Faculty Publications
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Item Preparation of vacuum deposited cadmium selenide thin films for optoelectronic applications(Elsevier Ltd, 2016) Santhosh, T.C.M.; Bangera, K.V.; Shivakumar, G.K.Cadmium selenide is a direct band gap material which finds applications in optoelectronic devices. Preparation of the compound semiconductor in thin film form with stable electrical characterization has been investigated in the present study. As deposited films at room temperature (25°C) are non-stoichiometric with excess cadmium and films grown at 180°C substrate temperature are stoichiometric and homogeneous. The crystallinity increases with increase in substrate temperature. The optical band gap determined from absorption measurements lie in the range 1.89 eV - 2.02 eV. Electrical conductivity measurements made in a temperature range from 25°C to 200°C yield thermal activation energy of 0.52eV for stoichiometric films. Films deposited at 180° C and annealed at 200° C for two hours are found to be stabilized in its electrical and structural properties. © 2016 Elsevier Ltd.Item Thermal stability and crystallization kinetics of Bi doped Si15Te85-xBix (0 ≤ x ≤ 2) chalcogenide glassy alloys(Elsevier Ltd, 2018) Fernandes, B.; Munga, P.; Ramesh, K.; Udayashankar, N.K.Bulk Si15Te85-xBix (0 ≤ x ≤ 2) chalcogenide glassy alloys were prepared by well-established melt quenching technique. Thermal stability and crystallization kinetics of these alloys were investigated by employing differential scanning calorimetry (DSC) technique at different heating rates, namely, 10, 15, 20 and 25 K/min under non-isothermal condition. Thermal parameters such as glass transition (Tg), onset crystallization (Tc) and peak crystallization (Tp) temperatures were observed. Double crystallization peaks observed in the DSC thermogram refer to the instability and phase separated network in the glasses. Various kinetic parameters such as thermal stability (ΔT), enthalpy (ΔHc), entropy (ΔS), specific heat (ΔCp) and fragility index are deduced. The calculated kinetic parameters suggest that the stability of glassy samples decreases with the increase in Bi addition. The activation energies of glass transition (Eg), and crystallization (Ec) are calculated using relevant kinetic formulae. We further discuss on the kinetics of the synthesized materials relevant for their applications in phase change memory (PCM) material. © 2017 Elsevier Ltd.Item Structural and electrical behaviour of glass ceramic 00B under sandwiched condition between two Crofer22APU substrates(Elsevier Ltd, 2020) Bhattacharya, S.; Shashikala, H.D.Obtaining high temperature glass and glass ceramic based seals is one of the biggest challenges in the present day fabrication of Solid Oxide Fuel Cell (SOFC) stacks. Formation of BaCrO4phase in BCAS glasses leads to degradation of cell performance. This work focusses on one glass composition derived from a BCAS species named 00B which is free of BaO and Al2O3contents. 00B was sandwiched between two Crofer22APU plates forming CGC sandwiches and heated for repeated thermal cycles from RT to 800 °C to check their compatibility with the metallic substrate. Microscopic images of the CGC interface and XRD data of the internal glass surface of the broken sandwich were recorded to observe the structural properties of the prepared sandwich. DC resistivity measurements of the glass under sandwiched conditions between two Crofer22APU plates, at RT and at elevated temperatures were carried out, to determine its resistivity at high temperatures, under SOFC operating conditions. The CGC sandwiches prepared using sample 00B showed good structural properties after repeated thermal cycles and sufficiently high specific resistance at room and elevated temperatures. The 00B glass without BaO and Al2O3content, but having structural and electrical behaviour suitable for coating on Crofer22APU, is suggested to be a potentially promising candidate for SOFC sealant applications. © 2020 Elsevier Ltd. All rights reserved.Item An alloy containing 49 at.% aluminium was heat treated at different temperatures within the ? + ? two-phase field to get five different volume fractions of lamellar constituent. Creep studies were carried out on these samples at five different temperatures in the interval between 1023 and 1223 K, by impression creep technique using four levels of stresses at each temperature. For a given temperature and stress, steady state impression velocity decreased with increasing volume fraction of lamellar constituent. Activation energy for steady state creep increased linearly with lamellar content from 185 kJ/mol at 22 vol.% to 362 kJ/mol at 100 vol.%. The stress exponent was found to be around 1.2 in all the cases. The results show that a fully lamellar structure has a superior behaviour where creep is an important factor.(Carl Hanser Verlag, Effect of microstructure on the impression creep of two-phase titanium aluminide) Prasad Rao, P.; Swamy, K.Shivananda1995Item Semiconducting thin films of cadmium telluride, both p-type and n-type, have been prepared by conventional thermal evaporation technique. The influence of various growth parameters such as the rate of deposition, deposition temperature, post-deposition heat treatment, and source material composition has been investigated. The films deposited at high deposition rates and low substrate temperatures exhibited an excess of tellurium and showed a p-type conductivity, whereas those deposited at high substrate temperature and low deposition rates contained excess cadmium and are n-type in nature. An intrinsic bandgap of 1.49 eV for stoichiometric films obtained by both electrical and optical characterization is reported.(Growth and characterization of vacuum deposited cadmium telluride thin films) Shreekanthan, K.N.; Kasturi, V.B.; Shivakumar, G.K.2003Item The inhibiting effect of N - cyclohexyl - N?- phcnyl thiourea (CPTU) and N-naphthyl-N?- phenyl thiourea (NPTU) on the corrosion of mild steel in aqueous solution of 0.1 N H2SO4 have been demonstrated using potentiodynamic polarization technique. The polarization data have shown that these compounds act as efficient anodic inhibitors for mild steel. Adsorption of these compounds on the mild steel surface was found to obey Temkin's adsorption isotherm. Good inhibition efficiency (IE) was evidenced in both the compounds and it was found to vary with concentration of the inhibitors. The kinetic parameters of adsorption obtained reveal spontaneous adsorption and a strong interaction of the compounds on the mild steel surface. © 2006 SAEST.(Inhibition of mild steel corrosion in sulphuric acid solution) Divakara Shetty, S.; Shetty, P.; Sudhaker Nayak, H.V.2006Item Trifluoromethyl-quinolin-yl-thio-propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution(2006) Ramesh Saliyan, V.; Vasudeva Adhikari, A.V.3-{[8-(trifluoromethyl)quinolin-4-yl]thio}propanohydrazide(TFQTPH) was synthesized, characterized and tested as a corrosion inhibitor for mild steel in 1 M HCl and 2 M HCl solution using different techniques: potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed that TFQTPH is an excellent inhibitor for mild steel in acid medium. The inhibition was assumed to occur via adsorption of the inhibitor molecule on the metal surface. In the temperature range 20° to 60° C, the TFQTPH adsorption follows Langmuir isotherm model. The protection efficiency increased with increasing inhibitor concentration (10 to 500 ppm), even at higher temperature also, it recorded good inhibition efficiency. © 2006 SAEST.Item Quinolin-5-ylmethylene-3-{[8-(trifluoromethyl)quinolin-4-yl]thio}propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution(2008) Saliyan, V.R.; Vasudeva Adhikari, A.V.Quinolin-5-ylmethylene-3-{[8-(trifluoromethyl)quinolin-4-yl]thio}propanohydrazide (QMQTPH) was synthesized, characterized and tested as a corrosion inhibitor for mild steel in 1 M and 2 M HCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Polarization resistances calculated from the EIS measurements were in good agreement with those obtained from direct current (DC) polarization measurements. The mild steel samples were also analyzed by scanning electron microscopy (SEM). The results showed that QMQTPH is an excellent inhibitor for mild steel in acid medium. The inhibition was assumed to occur via adsorption of the inhibitor molecule on the metal surface. It acts as an anodic inhibitor. In the 30° to 60 °C temperature range, the QMQTPH adsorption follows Langmuir isotherm model. The protection efficiency increased with increasing inhibitor concentration in the range 10-5 - 10-3 M, but slightly decreased with increasing temperature. © 2007 Elsevier Ltd. All rights reserved.Item Characterization of thin film Al/p-CdTe schottky diode(2008) Mahesha, M.G.; Kasturi, V.B.; Shivakumar, G.K.A study has been made on the behavior of Al/p-CdTe thin film junction grown by thermal evaporation method. I-V characteristics show that the Al makes Schottky contact with p-CdTe. The variation of junction capacitance with frequency and voltage has been studied to evaluate the barrier height. The activation energy and band gap have been estimated by studying variation of resistivity with temperature. Using all these data, band diagram of Al/p-CdTe has been proposed. © TÜB?TAK.Item Inhibition of corrosion of mild steel in acid media by N'-benzylidene-3- (quinolin-4-ylthio)propanohydrazide(2008) Ramesh Saliyan, V.; Vasudeva Adhikari, A.V.In the present investigation a new corrosion inhibitor, N'-(3,4-dihydroxybenzylidene)-3-{[8-(trifluoromethyl)quinolin-4-yl]thio} propanohydrazide(DHBTPH) was synthesized, characterized and tested as a corrosion inhibitor for mild steel in HCl (1 M, 2 M) and H2SO 4 (0.5 M, 1 M) solutions using weight-loss method, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization methods. The corrosion inhibition efficiency measured by all the above three techniques were in good agreement with each other. The results showed that DHBTPH is a very good inhibitor for mild steel in acidic media. The inhibition efficiency in different acid media was found to be in the decreasing order 0.5 M H 2SO4 > 1 M HCl > 1M H2SO4 > 2 M HCL The inhibition efficiency increases with increasing inhibitor concentration and with increasing temperature. It acts as an anodic inhibitor. Thermodynamic and activation parameters are discussed. Adsorption of DHBTPH was found to follow the Langmuir's adsorption isotherm. Chemisorption mechanism is proposed. The mild steel samples were also analysed by scanning electron microscopy (SEM). © Indian Academy of Sciences.