Palladium-Schiff base-triphenylphosphine catalyzed oxidation of alcohols
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Date
2010
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Abstract
Novel palladium(II)-N-(2-pyridyl)-N'-(5-R-salicylidene) hydrazine triphenylphosphine complexes were synthesized and characterized by UV, IR, 1HNMR and31P NMR spectral analysis, C, H, N analysis andmagnetic susceptibilitymeasurements. The complexes were effective in the catalytic oxidation of primary and secondary alcohols in presence of N-methyl-morpholine-Noxide as oxidant. The oxidation reactions were carried out in dichloromethane. A mechanistic study of the above reactions has been proposed. Copyright© 2010 JohnWiley & Sons, Ltd.
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Keywords
Catalyzed oxidation, Mechanistic studies, N-methyl-morpholine, NMO, Oxidation reactions, Pd complexes, Pyridyl, Schiff-base, Secondary alcohols, Spectral analysis, Triphenyl phosphines, Dichloromethane, Functional groups, Palladium, Palladium compounds, Spectrum analysis, Spectrum analyzers, Catalytic oxidation
Citation
Applied Organometallic Chemistry, 2010, 24, 9, pp. 663-666