Faculty Publications
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Item Enhancing the Dewatering Ability of Sludge by Locally Available Biomass(Springer Nature, 2023) Chopade, G.; Devatha, C.P.In this study, the effect of modified coconut shell biochar is analyzed for its efficacy achievable in sludge dewatering properties. Initially the coconut shell biochar is modified at different molar concentrations of FeCl3, i.e., 1, 2, and up to 5 mol/L, and it is analyzed with different dosages at 0.1, 0.2, and up to 0.4 (g/g of dry solids (DS)) for the improvement in capillary suction time (CST) (s), moisture content reduction (%), filterability (min), and settleability (SV30%) of the sludge. It is found that there is significant decrease in each of these parameters. The optimization study is carried out to optimize the process of sludge conditioning, considering independent regression parameters as dosage (g/g of DS), molarity (M), mixing time (min), and response taken as moisture content (%), the optimum values for the dosage, molarity, mixing time is found to be 0.4 (g/g of DS), 2.5 M and 24.72 min, respectively, with optimized moisture content value of 78% was achieved. Hence, the modified coconut shell biochar can be used as a potential candidate to increase the dewatering ability of the sludge. © The Author(s), under exclusive license to Springer Nature Switzerland AG 2023.Item Modelling for organics and nutrients release during Benthal sludge stabilisation : Part I -organics(2008) Bhargava, D.S.; Shrihari, S.Settleable solids in the untreated and partially treated domestic and industrial effluents discharged into a river system undergoes settling and decomposition in the form of benthal sludge deposits, Early models of biochemical oxygen demand (BOD) assimilation in rivers do not account for the BOD contribution by these benthal sludge deposits. In this paper, a model for computations of the BOD contribution by benthos (both from the top aerobic layers and the leached portion of BOD from the bottom anaerobic layers) was presented. Observations from three sets of experiments at the chosen overlying water flow rates (500 ml/min, 1000ml/ min and 1500 ml/min) show a higher BOD contribution by benthos at higher overlying water flow rates. The ratio of the BOD contributions by benthos to the volatile solids in the top aerobic layers was lower when compared to the similar ratio in respect of the bottom layer volatile solids showing that a higher contribution was made by the top layers.Item Modelling for organics and nutrients release during benthal sludge stabilisation part il - Nutrients(2009) Bhargava, D.S.; Shrihari, S.Settleable solids from untreated or partially treated domestic and industrial effluents undergoing stabilisation in stream beds contain significant amount or nutrients such as ammonia and phosphates apart from carbonaceous organic material. An experimental investigation was carried out to study the contribution of biochemical oxygen demand (BOD) and nutrients by this benthal-sludge undergoing stabillisation in steam beds. Sludge was collected from a sewage channel and placed at the bottom of an experimental reactor, and a continuous flow of clean tap water was maintained, in such a manner that the sludge was not disturbed. The first part of this work contained a discussion on degreadation of carbonaceous matter. The degradation of the nutrients, such as ammonia and phosphates being released from the sediments into the overlying waters at different flow rates of over laying waters is evaluated. It was noticed that the ammonia and phosphates released from the sediments into the overlying waters become more or less uniform after some days. The ammonia release and phosphate release were found to be affected by changes in the flowrates of overlying waters. The ammonia and phosphates remaining in the top and bottom layers of the sediments also showed similar trends. Predictive models have been presented for the variation of ammonia and phophate release into the overlying water, ammonia and phosphates remaining in the sediment layers at different times and different flow rates.Item Separation of dimethyl phenol using a spiral-wound RO membrane - Experimental and parameter estimation studies(2009) Srinivasan, G.; Sundaramoorthy, S.; Murthy, D.V.R.Reverse osmosis (RO) is increasingly used as a separation technique in chemical and environmental engineering for the removal of organics and organic pollutants present in waste water. Treatment of organics by RO is dependent on many factors and hence developing a viable RO system involves extensive pilot-plant studies. The removal of an organic compound, namely dimethyl phenol, using a polyamide membrane was investigated in this study. Experiments were conducted on a laboratory-scale spiral-wound RO module. The permeate concentrations and rejection coefficient values were measured for various transmembrane pressures and feed concentrations. A maximum rejection of 97% was observed. A mathematical model was developed for the RO module assuming a solution-diffusion mechanism for solute and solvent transport through the membrane and considering the concentration and pressure to be uniform on both permeate and retentate sides. The model has four parameters. A graphical method for estimating the model parameters was proposed. The model and the estimated parameter values were validated with the experimental data. The model was able to predict the permeate concentration within an error of 19% and rejection within 2% error. © 2009.Item An optimization study on microwave irradiated, decomposition of phenol in the presence of H2O2(2009) Prasannakumar, B.R.; Iyyaswami, I.; Murugesan, T.Background: Removal of phenol from industrial waste waters involves basic techniques namely extraction, biodegradation, photocatalytic degradation, etc. Among the available processes, the oxidation of phenols using H2O2 is a suitable alternative because of low cost and high oxidizing power. The application of an oxidation process for the decomposition of stable organic compounds in waste water leads to the total degradation of the compounds rather than transferring from one form to another. Since oxidation using Fenton's reagent ismore dependent on pH, in this present work it was proposed to use H2O2 coupled with microwave irradiation. The effects of initial phenol concentration, microwave power and the irradiation time on the amount of decomposition were studied. Results: In the present work experiments were conducted to estimate the percentage degradation of phenol for different initial concentrations of phenol (100, 200, 300, 400 and 500 mg L-1), microwave power input (180, 360, 540, 720 and 900 W) for different irradiation times. The kinetics of the degradation process were examined through experimental data and the decomposition rate follows first-order kinetics. Response surface methodology (RSM) was employed to optimize the design parameters for the present process. The interaction effect between the variables and the effect of interaction on to the responses (percentage decomposition of phenol) of the process was analysed and discussed in detail. The optimum values for the design parameters of the process were evaluated (initial phenol concentration 300 mg L-1, microwave power output 668 W, and microwave irradiation time 60 s, giving phenol degradation 82.39%) through RSM by differential approximation, and were confirmed by experiment. Conclusion: The decomposition of phenol was carried out using H2O2 coupled with microwave irradiation for different initial phenol concentrations, microwave power input and irradiation times. The phenol degradation process follows first-order kinetics. Optimization of the process was carried out through RSM by forming a design matrix using CCD. The optimized conditions were validated using experiments. The information is of value for the scale up of the oxidation process for the removal of phenol from wastewater. © 2008 Society of Chemical Industry.Item Nutrient contributions by benthal sludge deposits(2009) Bhargava, D.S.; Shrihari, S.Settled solids from effluents discharged into a river system, undergoing decomposition at the river bottom, form an appreciable internal nutrient source for the biological activities in the river system. During the stabilization of benthal deposits, a variety of nutrients are released into the overlying waters. The exchange between sediment and overlying waters is a major component of the nitrogen and phosphorous cycles in the natural waters. The releases of such nutrients is a surface phenomenon, regulated by the conditions of benthal sludge layers, flow rate of overlying waters, etc. The rate of ammonia nitrogen release manifested an optimum low value when benthal sludge depth was 0.2 m, but was not influenced by the flow rate of overlying water and h/d ratios. The rate of phosphate release from benthal sludge was independent of depth of benthal sludge, flow rate and h/d ratios. The nutrients in the benthal sludge layers were increasing with time, and were concentrated at a layer 10 cm below the top surface. The nutrients release (percent of nutrient remaining in top benthal sludge layers) decreased with time and became almost constant after about 40 days. The nutrients release under continuously accumulating conditions of benthal sludge and me effects of frequency of addition have been discussed in this paper. The nutrients release was less when the frequency of addition was less.Item Assessment of water quality of river Ganga along ghats in Varanasi city, U. P., India(2011) Thomas, T.; Mishra, M.; Thomas, H.; David, A.A.; Bharose, R.; Venkat Reddy, D.Assessment of water quality was done in holy River Ganga district of Varanasi, (U.P.) India in 2009. Water samples were collected from fives different sites namely (S 1)- Samne Ghat, (S 2)- Assi Ghat, (S 3)- Harishchandra Ghat, (S 4)- Dasaswamedh Ghat, (S 5)- Dr. Rajendra Prashad Ghat. The Ganga, one of the world's major rivers, has been venerated as the holiest and is bound with countless beliefs and faiths especially in India and adjacent countries. Its water has traditionally been regarded as pure and holy in nature gift to human. Recent experiences however do not warrant such complacency. The water resources are strained to a non-sustainable level due to rapid population growth, urban development, industrialization; livestock and power production on the Ganga Ghats at Varanasi city. The severe pollution stress and causes to which its water is subjected to the contents and quality of water and possible remedial measures. According to the result obtained by analyzing various Physico-chemical parameters of Ganga river in Varanasi City, maximum BOD recoded in (S 2)- Assi Ghat and minimum in (S 1)- Samne ghat whereas maximum DO was observed in Samne Ghat and minimum in (S 2)- Assi Ghat during Jan to March 2009 period respectively. On the basis of our experimental results it can be concluded that (S 2)- Assi Ghat exhibited higher pollution index than other ghats due to higher values of Turbidity, pH, BOD, Hardness, Alkalinity and Nitrate disposal occurring at (S 2)- Assi Ghat as well as disposal of industrial sewage in the (S 2)- Assi Ghat. Regular monitoring of Ganga river water quality is necessary to have a check on surface water quality for the sake of human life & to maintain a balanced aesthetical value of religious. We have to restore the environmental quality of Ganga which is amended by policy makers of Indian constitution. © 2011 CAFET-INNOVA TECHNICAL SOCIETY. All rights reserved.Item Characteristics of a novel Acinetobacter sp. and its kinetics in hexavalent chromium bioreduction(2012) Narayani, M.; Shetty K, K.V.Cr-B2, a Gram-uegadve hexavalent chromium [Cr(VI)] reducing bacteria, was isolated from the aerator water of an activated sludge process in the wastewater treatment facility of a dye and pigment based chemical industry. Cr-B2 exhibited a resistance for 1,100mg/l Cr(VI) and, similarly, resistance against other heavy metal ions such as Ni2+ (800 mg/l), Cu2+ (600 mg/l), Pb2+ (1,100 mg/l), Cd2+ (350 mg/l), Zn2+ (700 mg/l), and Fe3+ (1,000 mg/l), and against selected antibiotics. Cr-B2 was observed to efficiently reduce 200mg/l Cr(VI) completely in both nutrient and LB media, and could convert Cr(VI) to Cr(III) aerobically. Cr(VI) reduction kinetics followed allosteric enzyme kinetics. The Km values were found to be 43.11 mg/l for nutrient media and 38.05 mg/l for LB media. Vmax values of 13.17 mg/l/h and 12.53 mg/l/h were obtained for nutrient media and LB media, respectively, and the cooperativity coefficients (n) were found to be 8.47 and 3.49, respectively, indicating positive cooperativity in both cases. SEM analysis showed the formation of wrinkles and depressions in the cells when exposed to 800 mg/l Cr(VI) concentration. The organism was seen to exhibit pleomorphic behavior. Cr-B2 was identified on the basis of morphological, biochemical, and partial 16S rRNA gene sequencing chracterizations and found to be Acinetobacter sp. © The Korean Society for Microbiology and Biotechnology.Item Reduction of hexavalent chromium by a novel Ochrobactrum sp. - microbial characteristics and reduction kinetics(Wiley-VCH Verlag, 2014) Narayani, M.; Shetty K, K.A Gram negative hexavalent chromium (Cr(VI)) reducing bacteria, Ochrobactrum sp. Cr-B4 (genbank accession number: JF824998) was isolated from the aerator water of an activated sludge process of a wastewater treatment facility of a dye and pigment based specialty chemical industry. It showed a resistance for 1000mgL-1 Cr(VI). It exhibited resistance against other heavy metal ions like Ni2+ (900mgL-1), Cu2+ (500mgL-1), Pb2+ (800mgL-1), and Cd2+(250mgL-1), Zn2+ (700mgL-1), Fe3+ (800mgL-1), and against selected antibiotics. Cr-B4 could efficiently reduce 200mgL-1 Cr(VI) completely in nutrient and LB media and could convert Cr(VI) to Cr(III) efficiently. Cr(VI) reduction in nutrient media followed allosteric enzyme kinetics with Km values of 59.39mgL-1 and Vmax values of 47.03mgL-1h-1. The reduction in LB media followed Michaelis-Menten kinetics with Km values of 99.52mgL-1 and Vmax of 77.63mgL-1h-1. Scanning electron micrograms revealed the presence of extracellular polymeric secretions. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Item Aqueous two phase partitioning of fish proteins: partitioning studies and ATPS evaluation(Springer India sanjiv.goswami@springer.co.in, 2015) Nagaraja, V.H.; Iyyaswami, R.A suitable Aqueous Two Phase System (ATPS) has been identified for the partitioning of crude fish proteins from fish processing industrial effluent. A detailed study has been performed to analyze the influence of various parameters on protein partitioning such as molecular weight of PEG, effect of different salts (MgSO4, K2HPO4, Na3C6H5O7, Na2SO4, (NH4) 2PO4, K3C6H5O7) and their concentrations, pH, temperature, Tie Line Length (TLL), effluent loading and volume ratio. PEG 2000 - sodium sulphate ATPS was found to be a most favourable system among the selected ATPS for higher partition coefficient of proteins. The binodal curve and equilibrium characteristics of PEG 2000 - sodium sulphate were established and fitted to empirical equations. The equilibrium compositions (tie line) were correlated using Othmer–Tobias and Bancroft equations. © 2014, Association of Food Scientists & Technologists (India).
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