Faculty Publications
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Item Electrical and magnetic properties of chitosan-magnetite nanocomposites(2010) Bhatt, A.S.; Bhat, D.K.; Santosh, M.S.Magnetite powders in nanometer size have been synthesized by the hydrothermal process. Various magnetic films of chitosan and the synthesized magnetite nanopowders containing different concentrations of the latter were prepared by ultrasonication route. The X-ray diffraction (XRD) studies and the transmission electron microscopy (TEM) images showed that the synthesized magnetite particles had 80 nm dimensions. The band gap of the composites was evaluated using the UV-visible Spectroscopy. The influence of magnetite content on the magnetic properties of the composite showed a decrease in the saturation magnetization with the decrease in the magnetic content. The effect of magnetite content on the dielectric properties of the polymer film at different frequencies from 0.01 to 105 Hz was studied using an electrochemical impedance spectroscopy. The possible mechanism for the observed electrical properties of the composite films was discussed. © 2010 Elsevier B.V. All rights reserved.Item Crystallinity, magnetic and electrochemical studies of PVDF/Co 3O4 polymer electrolyte(Elsevier Ltd, 2012) Bhatt, A.S.; Bhat, D.K.Organic-inorganic nanocomposites are gaining importance in the recent times as polymer electrolyte membranes. In the present work, composites were prepared by combining nano sized Co3O4 and poly(vinyledene fluoride) (PVDF), using spin coating technique. The surface of the PVDF/Co 3O4 system characterized through field emission scanning electron microscopy (FESEM) revealed a porous structure of the films. The nanoparticles tend to aggregate on the surface and inside the pores, leading to a decrease in the porosity with an increase in Co3O4 content. Co3O4 nanoparticles prohibit crystallization of the polymer. Differential scanning calorimetry (DSC) studies revealed a decrease in crystallinity of PVDF/Co3O4 system with an increase in the oxide content. Magnetic property studies of the composite films revealed that with an increase in Co3O4 content, the saturation magnetization values of the nanocomposites increased linearly, showing successful incorporation of the nanoparticles in the polymer matrix. Further, ionic conductivity of the composite films was evaluated from electrochemical impedance spectroscopy. Addition of Co3O4 nanoparticles enhanced the conductivity of PVDF/Co3O4 system. © 2011 Elsevier B.V. All rights reserved.Item Photostability and electrical and magnetic properties of cobalt oxide nanoparticles through biological mechanism of endophytic fungus Aspergillus nidulans(Springer, 2020) Vijayanandan, A.S.; Mohan Balakrishnan, R.M.The study elaborates magnetic and electrical properties of greenly synthesized cobalt oxide (Co3O4) nanoparticles through endophytic fungus Aspergillus nidulans isolated from medicinal plant Nothapodytes foetida, which examines the ability of the nanoparticles to be magnetized and electrified, being one of the yardsticks for energy application. On increasing the precursor concentration from 2 to 10 mM, there is a shift in paramagnetic to weak ferromagnetic behavior of nanoparticles with the increase in saturation magnetization (Ms) from 0.161 to 7.75 emu/g. Frequency dependence of dielectric constant is found to increase with an increase in frequency, and the aforementioned nanoparticles can be used as a dielectric up to 1,50,000 Hz as dissipation factor is lesser than one. Besides, photostability study has indicated that the particles are stable for at least 45 days. Through liquid chromatography–mass spectrometry (LC–MS) analysis, phytochelatins are identified to be involved in the biosynthesis of nanoparticles. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.Item Influence of temperature on magnetorheological fluid properties and damping performance(IOP Publishing Ltd, 2022) Kumar Kariganaur, A.; Kumar, H.; Arun, M.The magnetorheological (MR) system's performance depends on the MR fluid's temperature in operation. This study aims to evaluate the temperature effect of MR fluid on performance while the damper is working. Before synthesizing MR fluid, scanning electron microscopy, x-ray diffraction, and particle size analysis verifies for the synthesis of MR fluid in-house. Characterization of the MR fluid at different temperatures and magnetic fields was carried out. The Herschel-Bulkley model is used to analyse the nonlinearity in the fluid by incorporating the temperature effect. The range of critical parameters used to fabricate the MR damper is selected using the Technique for Order of Preference by Similarity to Ideal Solution performance score. The temperature of the MR fluid is measured using an embedded thermocouple while the damper is operating at different loading parameters. The results reveal that the fluid temperature rises significantly from atmospheric to 125.39 °C with decrease in damping force by 66.32% at higher loading parameters. The theoretical model predicts the increase in temperature similar to that of the experimental values with an average error of 10.24% in the on-state condition. Particle characterization after dynamic testing reveals particle morphology has not changed but the saturation magnetization of the particles reduced by 57% at higher temperatures (127 °C). It is observed through thermogravimetric analysis that, the life of the fluid is reduced by 0.25%, which is negligible after dynamic testing of the fluid for approximately 85000 cycles. Finally, to imitate the temperature effect on the particle, particles were heat-Treated at 200 °C, 400 °C, and 600 °C, and through scanning electron microscope image it is confirmed that deterioration of the particle starts after 200°C, if the fluid is operated for a prolonged amount of time. © 2022 IOP Publishing Ltd.Item A study on solubility of bismuth cations in nickel cobalt ferrite nanoparticles and their influence on dielectric and magnetic properties(Elsevier Ltd, 2023) Patil, S.; Meti, S.; Kanavi, P.S.; Bhajantri, R.F.; Anandalli, M.; Mondal, R.; Karmakar, S.; Muhiuddin, M.; Rahman, M.R.; Kumar, B.C.; Hegde, B.G.In this work, a low temperature (∼600 °C) solution combustion technique is employed for the synthesis of Ni0.5Co0.5BixFe2-xO4 (NCBFO, where x = 0.0, 0.05, 0.1, 0.15, & 0.2) nanoparticles with crystallite size variation of 17–22 nm. The X-ray diffraction (XRD) technique is used to confirm the formation of cubic spinel phase of Bi3+ doped (for x ≤ 0.05 samples) nickel–cobalt ferrite (NCFO) nanoparticles. The increase in bismuth substitution (x > 0.05) results in the formation of the Bi2O3 along with the NCFO structure, which results in the reduction of binding energy and is confirmed by the XRD and X-ray photoelectron spectroscopy (XPS) techniques. From the Raman spectra, the change in the intensities of the peaks is observed due to the variation of Bi3+ in NCFO matrix. Due to increasing cation concentration and electronegativity, the FTIR absorption band shifts toward the lower wave numbers. Dielectric measurements were carried out to examine the charge transport behavior and electric conduction mechanism. The FESEM images shows the non-magnetic bismuth atoms are diffused into the NCFO nanoparticles. From the vibrating sample magnetometer (VSM) analysis, it is observed that saturation magnetization, remanent magnetization, coercivity and squareness ratio are found to be maximum for x = 0.15 NCBFO sample. The high coercivity (Hc = 916.8 Oe) for the x = 0.15 sample indicates the hard ferromagnetic behaviour of the samples. © 2023 Elsevier B.V.Item Amino acid functionalized metal oxide nanocomposite for the removal of fluoroquinolones(Elsevier Ltd, 2023) Ilango, I.; Mohan Balakrishnan, R.M.Antibiotic consumption has increased globally, and its discharge into water bodies at concentrations ranging from a few ng/L to mg/L has a detrimental effect on the ecosystems. Amino acid functionalized nickel ferrite nanoparticles were chosen to improve the stability of bare nanoparticles and prevent oxidation and leaching ions in nanoparticles thereby targeting the antibiotics in the contaminated water bodies. The removal of ciprofloxacin and lomefloxacin hydrochloride in the aqueous phase was investigated using a hydrothermally synthesized L-Leucine functionalized nickel ferrite nanocomposite (NFO@L). Various analytical techniques were used to analyze L-Leucine functionalized nickel ferrite, and the nanocomposite's average particle diameter was determined to be between 11 and 15 nm. The maximal measured zeta potential was −21.5 mV. Fourier transform infrared spectroscopy (FTIR), ninhydrin assay and X-ray diffraction (XRD) analysis confirmed the attachment of L-Leucine onto nickel ferrite. The nanocomposite's surface-to-volume ratio was calculated to be 92.916 m2/g. The S-shaped curve from the vibrating sample magnetometer analysis reflected the superparamagnetic behaviour of the nanocomposite with a saturation magnetization of 0.665 emu/g. Various parametric experiments were conducted, in which 93.549% ciprofloxacin was removed in 120 min at 303 K, pH 8 and NFO@L dosage of 100 mg in 100 mL whereas 75.192% lomefloxacin hydrochloride was removed in 140 min at 333 K, pH 9 and NFO@L dosage of 70 mg in 100 mL. The plot of experimental datum in kinetic and isotherm studies fitted well with the Pseudo second order kinetic model and Langmuir isotherm. There was no evidence of iron ions leaching from the final analyte. The recycle and regeneration studies showed good stability with a small reduction after four cycle runs. Based on these findings, the Leucine functionalized nickel ferrite nanocomposite could be a potent adsorbent for the removal of low-concentrated ciprofloxacin and lomefloxacin hydrochloride in the wastewater. © 2023Item Study on operational temperature of magneto-rheological fluid and design dimensions of magneto-rheological damper for optimization(Institute of Physics, 2024) Kumar Kariganaur, A.; Kumar, H.; Arun, M.This study aims to restrict the upper limit for flow gap and effective length in magnetorheological (MR) damper for optimal performance. Initially, the sedimentation study of in-house MR fluid (25%) shows that an 8% reduction in the sedimentation ratio with the addition of additive and nonlinear Herschel-Bulkley (HB) model fit reflects a 32.5% decrease in average yield stress with increasing currents when the parallel plate gap is increased from 1 mm to 2 mm. Owing to this decrease in yield stress, further study is extended to fabricate two MR dampers with limit values (LV) of flow gap and effective length with a common magnetic outer cylinder. Testing results of MR dampers revealed a 72% reduction in damping force at 0.8 A current when the LV’s is increased from LV-1 to LV-2. Selecting LV-1 over LV-2 as the upper limit for any design optimization will give the MR damper optimal performance. At higher input parameters, amplitude has a 135% greater impact on damping force than frequency and current. It is also demonstrated that saturation magnetization depends on the applied magnetic field and input loading parameters. Finally, gravimetric analysis shows that the effectiveness of the MR fluid and magnetic particle starts to decline after 322 °C and 400 °C. © 2024 IOP Publishing Ltd.Item Investigation of structural, thermal, magnetic, and dielectric properties of Yb+3 doped nickel cobalt ferrite nanomaterial for electro-magnetic applications(Springer, 2024) Patil, S.; Meti, S.; Anandalli, M.; Badiger, H.; Bhajantri, R.F.; Pratheek, L.; Muhiuddin, M.; Rahman, M.R.; Hegde, B.G.Herein, we report the synthesis of ytterbium (Yb) (with concentration x = 0.01, 0.015, 0.02, 0.025 and 0.03) doped in to nickel cobalt ferrite (NCYFO: YbxNi0.5Co0.5Fe2-xO4) nanoparticles at temperature 500 °C with phase pure spinel using solution combustion technique. The phase purity and effect of doping on NCYFO complex oxide on structural, thermal, magnetic and dielectric properties have been determined by various characterization techniques. The FTIR data reveal that strong metal oxide linkages can be observed in the tetrahedral and octahedral sites at wavenumbers 460 to 410 cm−1 and 595 to 540 cm−1. The X-ray diffraction (XRD) studies confirmed the spinel structure. The crystallite sizes and lattice parameters were estimated to be in the range of 31 to 22 nm and 8.32 to 8.35 Å, respectively. The X-ray photoelectron spectroscopy (XPS) study confirmed that the increase in Yb concentration results in accumulation of Yb in the grain boundaries of NCYFO in the form of Yb2O3. The thermal stability of nanoparticles were investigated using TGA/DSC method. Transmission Electron microscopy (TEM) studies and Field emission scanning electron microscopy (FESEM) used to study the particle size distribution and elemental composition within the nanomaterial. In addition, the dielectric properties, such as, dielectric constant and dielectric loss were investigated for all the NCYFO nanomaterial. The saturation magnetization of the NCYFO is determined using vibrating sample magnetometer (VSM) analysis and is maximum for x = 0.03 (Ms = 97.56 emu/g) sample. The high magnetic behaviour and better dielectric properties of the NCYFO nanomaterials are suitable for electro-magnetic applications. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024.Item Influence of Stator Structure on the Electromagnetic Performance of an In-Wheel Multi-teeth SRM(Springer, 2025) Bhaktha, S.; Ramnihor, G.R.; Pitchaimani, J.; Gangadharan, K.V.Compared to traditional switched reluctance motor (SRM) topologies, the multi-teeth (MT) SRM topology has been reported to be beneficial for in-wheel motor applications because of its superior torque density, efficiency, with minimized torque ripple. In this paper, a four-phase 8/18 IW-MTSRM with two different stator structures, namely the trapezoidal-shaped stator structure (TSSS) and the Y-shaped stator structure (YSSS) are designed and analyzed. Using two-dimensional (2D) electromagnetic static finite element analysis, the performance metrics including average torque, peak torque capacity, and torque ripple are compared under the condition of constant copper loss. Based on the results obtained, this study attempts to offer guidance and suggestions for choosing an appropriate stator structure among IW-MTSRMs according to the application requirement. To validate the FEA model employed in this study, an 8/18 IW-MTSRM with the TSSS is prototyped and tested experimentally. The experimental results are observed to agree with the FEA model. © The Institution of Engineers (India) 2024.