Faculty Publications
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Item Role of thermally grown oxide and oxidation resistance of samarium strontium aluminate based air plasma sprayed ceramic thermal barrier coatings(Elsevier B.V., 2017) Baskaran, T.; Arya, S.B.Samarium Strontium Aluminate (SSA) based ceramic oxide was synthesized and coated on a bond coated (NiCrAlY) Inconel 718 superalloy by air plasma spray (APS) process. Thermally grown oxide (TGO) thicknesses were controlled at different pre-oxidation times of 10, 20 and 30 h at 1050 °C in the argon atmosphere, the highest TGO thickness being found for 30 h pre-oxidized samples. The percentage elastic recovery of pre-oxidized samples increased (45, 48, and 50%) with an increasing pre-oxidation time at 1050 °C. The isothermal oxidation test was performed on pre-oxidized samples at 1100 °C for 15 h in air. The parabolic oxidation rate constant decreased from 6.08 × 10? 5 to 3.90 × 10? 5 mg2 cm? 4 s? 1 (from 10 to 20 h) and then increased up to 4.55 × 10? 5 mg2 cm? 4 s? 1 for 30 h pre-oxidized SSA samples at 1100 °C. SSA based TBCs showed 65% lower weight gain as compared to conventional YSZ TBCs after oxidation at 1100 °C in air. Cross-sectional SEM results revealed that the threshold TGO thickness of SSA TBCs is about 5.3 to 5.8 ?m. Failure of SSA TBCs was observed at the interface of TGO and ceramic top coat due to the formation of SmAlO3 along with spinel oxides. © 2017Item Ceria-samarium binary metal oxides: A comparative approach towards structural properties and soot oxidation activity(Elsevier B.V., 2018) Anjana, A.P.; Geethu, J.; P, M.R.; Prasad Dasari, H.P.; Lee, J.-H.; Harshini, H.; Bhaskar Babu, G.U.Binary metal oxides of CeO2-Sm2O3 (CSx, x varies from 10 to 90 mol%) along with pure CeO2 and Sm2O3 were synthesised successfully by the EDTA-Citrate method. From XRD, Raman spectroscopy and UV–vis DRS results, the whole composition of metal oxides exist in three phases: (fluorite phase (F) (CS10-CS30), bi-phase (fluorite (F) + cubic (C)) (CS30-CS90) and cubic phase (C) (Sm2O3)). For CSx samples, the calculated band gap energy values obtained from the UV–vis DRS results were in between 3.0–5.1 eV and fluorite phase samples (CS10–CS30) displayed lower band gap energy values (3.04–3.07 eV) than compared to the samples in other phases. Similarly, from XPS analysis, fluorite phase samples (CS10–CS30) showed higher surface oxygen vacancy concentration than compared to samples in other phases. Catalytic activity for soot oxidation is carried out on CSx samples, and the T50 temperature is in between 480–540 °C. Fluorite phase samples (CS10 CS30) showed higher surface area, lower degree of agglomeration, lower band gap energy, higher oxygen vacancy concentration and better catalytic activity for soot oxidation. Among all the CSx samples, CS10 sample displayed highest surface area (38 m2/g), lowest degree of agglomeration (0.36), lowest band gap energy (3.04 eV), highest oxygen vacancy concentration (64%) and highest soot oxidation activity (T50 = 480 °C). The order of the soot oxidation activity of CSx samples followed the same trend of band gap energy values. © 2018 Elsevier B.V.Item Influence of ceramic top coat and thermally grown oxide microstructures of air plasma sprayed Sm2SrAl2O7 thermal barrier coatings on the electrochemical impedance behavior(Elsevier B.V., 2018) Baskaran, T.; Arya, S.B.Electrochemical impedance spectroscopy (EIS) technique is used to examine the top coat and thermally grown oxide (TGO) microstructures of Samarium Strontium Aluminate (SSA) thermal barrier coatings (TBCs) after exposed to pre-oxidation and oxidation at 1050 and 1100 °C, respectively. EIS spectra showed that the three relaxations frequencies in Bode plot corresponded to SSA top coat, TGO, and TGO-bond coat interface. A significant reduction in polarization resistance of SSA top coat and increase in capacitance for different pre-oxidation times of 10, 20 and 30 h are being found due to increasing the defects (pores and cracks) of about 13, 29 and 45%, respectively at 1050 °C. The reduction in bi-axial residual stresses was calculated to be about 57% as a consequence of decrement in top coat resistance. The growth of SSA TGO was found from 10 to 20 h of pre-oxidation treatment caused to decrease the capacitance which indicates the presence of highly enriched ?-Al2O3 at the bond coat-top coat interface. The highest charge transfer resistance and lowest capacitance were found to be about 0.48 × 106 ? cm2 and 1.1 nF cm?2 respectively for 20 h of pre-oxidation which could reflect the overall impedance kinetics of TBC system (SSA top coat and TGO) at the TGO-bond coat interface. The impedance responses of SSA top coat, TGO, and TGO-bond coat interface were reduced drastically after oxidation at 1100 °C for 10 h pre-oxidized specimen as compared to 20 and 30 h due to the compositional change of pure ?-Al2O3 based TGO into more conductive NiCr2O4. The lowest diffusion coefficient, DCr3+ in the NiO lattice which reduced the formation of metal ion vacancies at the TGO-top coat interface caused to exhibit higher TGO resistance for 20 h pre-oxidized specimens over 10 and 30 h after oxidation at 1100 °C. © 2018 Elsevier B.V.Item Hot corrosion resistance of air plasma sprayed ceramic Sm2SrAl2O7 (SSA) thermal barrier coatings in simulated gas turbine environments(Elsevier Ltd, 2018) Baskaran, T.; Arya, S.Samarium strontium aluminate (Sm2SrAl2O7-SSA) and Yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) were developed on NiCrAlY bond coated Inconel 718 superalloy substrate using air plasma spray process. The hot corrosion study was conducted in simulated gas turbine environments (molten mixtures of 50 wt% Na2SO4 + 50 wt% V2O5 and 90 wt% Na2SO4 + 5 wt% V2O5 + 5 wt% NaCl) for two different temperatures of 700 and 900 °C. A developed SSA TBCs showed about 8% and 22% lower lifetime at 700 and 900 °C, respectively than YSZ TBCs in 50 wt% Na2SO4 + 50 wt% V2O5 (vanadate). The hot corrosion life of SSA TBCs being found about 13% and 39% lower than YSZ TBCs in 90 wt% Na2SO4 + 5 wt% V2O5 + 5 wt% NaCl (chloride) at 700 and 900 °C, respectively. X-ray diffraction results showed the formation of SmVO4, SrV2O6, and SrSO4 as a major hot corrosion product in 50 wt% Na2SO4 + 50 wt% V2O5 and 90 wt% Na2SO4 + 5 wt% V2O5 + 5 wt% NaCl environments respectively for SSA TBCs. Similarly, YSZ TBCs also showed YVO4 as hot corrosion product in vanadate and chloride environments. Both the TBCs suffer a more severe hot corrosion attack in chloride environment at 900 °C. The leaching of Sr2+ and Y3+ ions from SSA and YSZ respectively play a vital role in the destabilization of coating in vanadate and chloride environments at 700 and 900 °C. In both SSA and YSZ TBCs, the leaching of ion has significantly low influence as compared to attack by chloride ions at the bond coat-top coat interface in the presence of chloride environment. The hot corrosion resistance of SSA TBCs was improved three times higher in the presence of MgO and NiO inhibitor in vanadate environment at 900 °C mainly due to the formation of a stable Ni3V2O8 phase at the surface. © 2018 Elsevier Ltd and Techna Group S.r.l.Item Isothermal oxidation characteristics of laser-treated Al2O3 + Sm2SrAl2O7 composite thermal barrier coatings(John Wiley and Sons Inc, 2023) James J, F.; Arya, S.B.; Satish Kumar, D.A thermal barrier coating system with Al2O3 + Sm2SrAl2O7 composite top coat was developed on an Inconel 718 superalloy substrate by using an atmospheric plasma spray technique, and the coated samples are treated with an Nd:YAG fiber laser to improve the surface properties. The as-coated and laser-treated samples were subjected to high temperature isothermal oxidation test at 1100°C for 150 h duration. The surface of the oxidized samples showed the presence of dissociated SmAlO3, SrAl2O4, and Sm2O3. Thermally grown oxides (TGO) are found at the bond coat top coat interface of the samples. The oxidation kinetics is examined by monitoring weight gain at regular intervals. The electrochemical impedance behavior, oxidation mechanism, and TGO formation in the developed composite coatings are discussed in detail. © 2023 Wiley-VCH GmbH.Item Phase stabilized solution combustion processed (Ce0.2La0.2Pr0.2Sm0.2Y0.2)O1.6-δ: An exploration of the dielectric properties(Elsevier Ltd, 2023) Salian, A.; K, A.P.; Mandal, S.High entropy oxide (HEO) (Ce0.2La0.2Pr0.2Sm0.2Y0.2)O1.6-δ with a phase pure fluorite was synthesized using low-temperature solution combustion. A low-temperature formation of HEO was evidenced at 500 ºC. The HEO formation at 500 ºC was due to the exothermicity of the combustion redox reaction, where the internal temperature might have reached a much higher temperature for a limited amount of time. The presence of Sm2O3 and Y2O3 was visible upto 500 ºC, while La2O3 was detected up to 900 ºC and the HEO fully got stabilized at 1000 ºC with a single-phase, fcc fluorite structure with an Fm-3 m space group. The HEO displays one of its parent oxide Ce-O structural properties as both belong to the fluorite family and had lattice parameters very close to each other. The presence of a secondary phase in the 2 and 3-cation systems and the display of a single phase in the 4 and 5-cation systems indicated the role of configurational entropy in phase stabilization. Raman of HEO also affirmed the formation of HEO at 500 °C, the complete elimination of secondary phases at 1000 °C, and a fully disordered occupancy of various metal cations with severe lattice distortion. A Flake morphology with a nanogranular cluster on the surface was displayed. Dielectric measurements at room temperature showed permittivity (κ) ≈ 29 – 5.7 from 100 Hz to 1 MHz. © 2023 Elsevier B.V.Item Enhancement of Corrosion Resistance of Al2O3 + Sm2SrAl2O7 Composite Thermal Barrier Coatings by Laser Treatment(Springer, 2024) James J, F.; Arya, S.B.The rare earth aluminate Sm2SrAl2O7 was synthesized in the laboratory through a molten salt synthesis technique at 1100 °C. A composite thermal barrier coating system on Inconel 718 substrate was developed with Al2O3–Sm2SrAl2O7 composite as the top coat and NiCrAlY as the bond coat using atmospheric plasma spraying. The surface of the plasma-sprayed coatings was treated using an Nd: YAG fiber laser to seal off the open porosities and reduce surface roughness. Hot corrosion tests on the laser-modified samples were performed at 700 °C and 900 °C, in aviation and marine corrosive conditions using 50 wt.% Na2SO4 + 50 wt.% V2O5 and 90 wt.% Na2SO4 + 5 wt.% V2O5 + 5 wt.% NaCl, respectively. The laser-treated samples showed higher resistance to failure than the as-coated samples under similar conditions. The corrosion products are identified, and the mechanisms involved are discussed in detail. The effect of surface modifications on the hot corrosion resistance of the coatings is investigated. © The Indian Institute of Metals - IIM 2023.Item Effect of Surface Modification on Erosion Behavior of Alumina-Samarium Strontium Aluminate Composite Thermal Barrier Coatings(Springer, 2025) James J, F.; Arya, S.B.; Yadav, S.; Paul, C.P.The mechanical and tribological characteristics of a thermal barrier coating are highly critical in gas turbine applications to resist high-temperature oxidation, corrosion, and solid particle erosion. In the present investigation, a composite coating with alumina and samarium strontium aluminate has been developed through a plasma spraying process. The as-coated composite top coat consisted of three phases ?-alumina, ?-alumina, and Sm2SrAl2O7. The as-coated surface is re-engineered with an Nd: YAG fiber laser to improve the mechanical and microstructural properties. The laser-treated samples showed a better erosion resistance than the as-coated samples. Despite the surface treatment, both the as-coated and the laser-treated samples showed a higher ‘average erosion value’ at an impact angle of 90° for the test temperatures of 200 and 800 °C. In addition, the as-coated and the laser-treated samples have a higher erosion rate at 800 than at 200 °C for the selected impact angles, with a mixed mode of material removal presenting both ductile and brittle failure mechanisms. © ASM International 2024.