Faculty Publications
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Item Carbon spheres assisted synthesis of porous bioactive glass containing hydroxycarbonate apatite nanocrystals: A material with high in vitro bioactivity(2008) Jagadeesan, D.; Deepak, C.; Siva, K.; Inamdar, M.S.; Eswaramoorthy, M.A hierarchically porous bioactive glass of composition 80 mol % SiO 2 and 15 mol % CaO (MBGH) was synthesized using pluoronic P123 and glucose-derived amorphous carbon spheres as templates. While the carbon spheres leave behind pores of 300 nm to a few micrometers after calcination, the walls of these pores contain orderly arranged mesopores of 3-5 nm orchestrated by the pluoronic polymer. The role of carbon spheres is not only to create pores but also to aid in increased growth rate of hydroxycarbonate apatite in simulated body fluid (SBF). The negatively charged carbon spheres favor the local enrichment of calcium ions and facilitate the formation of amorphous calcium phosphate around the surface. On calcination, the walls of the macropores contain crystalline hydroxycarbonate apatite nuclei. MBGH also exhibits an accelerated growth of monoclinic-like apatite in SBF. The in vitro activity has been studied by XRD, FT-IR, FESEM, and TEM. © 2008 American Chemical Society.Item Electrical switching behavior of bulk Si15Te85-xSbx chalcogenide glasses - A study of compositional dependence(2010) Lokesh, R.; Udayashankar, N.K.; Asokan, S.Studies on the electrical switching behavior of melt quenched bulk Si15Te85-xSbx glasses have been undertaken in the composition range (1 ? x ? 10), in order to understand the effect of Sb addition on the electrical switching behavior of Si15Te85-x base glass. It has been observed that all the Si15Te85-xSbx glasses studied exhibit a smooth memory type switching. Further, the switching voltages are found to decrease almost linearly with Sb content, which indicates that the metallicity of the dopant plays a dominant role in this system compared to network connectivity/rigidity. The thickness dependence of switching voltage (Vth) indicates a clear thermal origin for the switching mechanism. The temperature variation of switching voltages reveals that the Si15Te85-xSbx glasses studied have a moderate thermal stability. © 2009 Elsevier B.V. All rights reserved.Item Abrasive wear behavior of granite-filled glass-epoxy composites by SiC particles using statistical analysis(2011) Basavarajappa, .S.; Manjunath Yadav, S.M.; Kumar, S.; Arun, K.V.; Narendranath, S.This experimental investigation deals with the evaluation of abrasive wear behavior of Glass Epoxy (G-E) composites on pin-ondisc test rig. A plan of experiments, based on the Taguchi Design of Experiments, was performed to acquire data in controlled way. An orthogonal array and the analysis of variance were employed to investigate the percentage of contribution of various process parameters like sliding speed, applied load, sliding distance and their interactions affecting the abrasive wear volume loss of composites. The correlations between the various factors affecting the abrasive wear behavior of composites were obtained by using multiple linear regression equations. The obtained results indicate that applied load and sliding distance were the wear factors that have the highest physical as well as statistical influence on the abrasive wear behavior of both filled and unfilled G-E composites. A good agreement between the predicted and actual wear resistance was observed within±12%. © Taylor & Francis Group, LLC.Item Experimental investigation and artificial neural network-based modeling of batch reduction of hexavalent chromium by immobilized cells of newly isolated strain of chromium-resistant bacteria(2012) Shetty K, K.V.; Namitha, L.; Rao, S.N.; Narayani, M.The batch bioreduction of Cr(VI) by the cells of newly isolated chromium-resistant Acinetobacter sp. bacteria, immobilized on glass beads and Ca-alginate beads, was investigated. The rate of reduction and percentage reduction of Cr(VI) decrease with the increase in initial Cr(VI) concentration, indicating the inhibitory effect of Cr(VI). Efficiency of bioreduction can be improved by increasing the bioparticle loading or the initial biomass loading. Glass bioparticles have shown better performance as compared to Ca-alginate bioparticles in terms of batch Cr(VI) reduction achieved and the rate of reduction. Glass beads may be considered as better cell carrier particles for immobilization as compared to Ca-alginate beads. Around 90% reduction of 80 ppm Cr(VI) could be achieved after 24 h with initial biomass loading of 14.6 mg on glass beads. Artificial neural networkbased models are developed for prediction of batch Cr(VI) bioreduction using the cells immobilized on glass and Ca-alginate beads. © Springer Science+Business Media B.V. 2011.Item Mechanical and sliding wear properties of multi-layered laminates from glass fabric/graphite/epoxy composites(Elsevier Ltd, 2013) Shivamurty, B.; Bhat, K.; Anandhan, S.Multi-layered laminates of bi-directionally woven E-glass fabric/epoxy with different loading of graphite particles were made by hand layup followed by compression molding. Tensile and flexural behaviors, impact strength, hardness and density of these laminates were determined. Wear behaviors of these composites were investigated by a pin-on-disc wear test apparatus. Specific wear rates of these composites strongly depend on their filler content and applied normal loads. The hybrid composite containing 3 wt% of graphite exhibits the optimum mechanical and wear performances. A further increase in the graphite content increases the specific wear rate and deteriorates the mechanical behavior. The lowest (? e)-1 factor (the reciprocal of the product of tensile strength and elongation at break) signifies the lowest specific wear rate. The results of the morphology study of the wear test specimens support the results of the wear test. © 2012 Elsevier Ltd.Item Optical and mechanical properties of calcium phosphate glasses(Maik Nauka Publishing / Springer SBM compmg@maik.ru, 2014) Venkateswara Rao, G.V.; Shashikala, H.D.Binary calcium phosphate glasses in the system, xCaO-(100 - x) P 2O5 with x = 30, 35, 40, 45, and 50 mol % were prepared by conventional melt quenching technique. The density, molar volume and refractive index of the glasses were found to increase with the increase in CaO content. Structural investigation by FTIR spectroscopy revealed that the substitution of P2O5 by CaO depolymerizes the phosphate glass network by systematic conversion of Q3 structural units to Q2 structural units by breaking the P-O-P links. From the optical absorption studies, the optical band gap values were found to decrease with increasing CaO content which can be due to increase in the concentration of non-bridging oxygens in the glass network. Vickers hardness increased with the calcium oxide content due to densification. The fracture toughness decreases with the increase in CaO content due to the increase in the bond density between the modifying cations and the non-bridging oxygens in the glass network. It was observed that brittleness increases with the addition of CaO content which can be mainly attributed to the decrease in the molar volume. © 2014 Pleiades Publishing, Ltd.Item Influence of nano-aluminum-hydroxide on tribological, mechanical and flammability properties of E-glass fabric/epoxy multi-layered laminates(Huthig GmbH, 2014) Shivamurty, B.; George, G.; Bhat, K.U.; Anandhan, S.E-glass fabric/nano aluminum hydroxide (ATH)/epoxy composites were prepared by manual lay-up and compression molding. An image processing tool was used to quantify fineness of dispersion of nano-ATH particles in epoxy. Fourier transform infrared (FTIR) spectroscopy was used to understand the interaction between nano-ATH and epoxy. Mechanical properties, sliding wear resistance and fire retardance of these composites improved upon addition of nano-ATH. The composite containing 0.125 wt% of nano-ATH exhibited optimum mechanical properties and low specific wear rate.Item Structural, optical and mechanical properties of ternary CaO-CaF2-P2O5 glasses(Tsinghua University, 2014) Venkateswara Rao, G.V.; Shashikala, H.D.The ternary phosphate glass series (50?x)CaO-xCaF2-50P2O5 (x = 0–20 mol%) were synthesized using melt quench technique. Structural, optical and mechanical properties were investigated with increase in CaF2 content. Using X-ray diffraction (XRD), synthesized glasses were confirmed to be amorphous in nature. Replacement of oxygen ions by fluorine ions increased the values of density. Decrease in refractive index due to the low polarizability of fluorine ions in the glass matrix was observed. In Fourier transform infrared (FTIR) spectra, the slight variation in ?as (PO2) band position and intensity could be attributed to replacement of fluorine ions for oxygen ions in phosphate glass structure. These data were well supported by Raman spectra. Optical band gap energy increased from 3.44 eV to 3.64 eV with increase in CaF2 content, and Urbach energy decreased suggesting that the fluorine ions reduced the tail energy states in the band gap compared to the oxygen ions. Mechanical parameters such as Vickers hardness, fracture toughness and brittleness were evaluated from the Vickers micro indentation measurements. Increase in Vickers hardness, decrease in fracture toughness and increase in brittleness were observed with increase in CaF2 content. © 2014, The Author(s).Item Optical, dielectric and mechanical properties of silver nanoparticle embedded calcium phosphate glass(Elsevier, 2014) Venkateswara Rao, G.V.; Shashikala, H.D.Silver nanoparticles have been embedded in 50 mol% CaO-50 mol% P 2O5 glass using melt quenching technique. The quenched glasses were heat treated at 550 °C for different durations between 10 and 50 h. The growth of silver nanoparticles in glass matrix appeared to be time dependent. FTIR spectra revealed that silver nanocluster formation had not affected the position of vibration bands of basic phosphate tetrahedral network. The Ag nanoparticle embedded glass matrix showed the red shift and broadening of the surface plasmon resonance (SPR) peak in the visible region with the increase in the duration of the heat treatment. Results showed the increase in size of the nanoparticles in glass matrix with heat treatment which was further confirmed using transmission electron microscopy and XRD. X-ray diffraction studies indicated the presence of Ag crystalline peaks along with amorphous structure on heat treatment at 550 °C for 50 h. The dielectric constant of these glasses increased as the duration of the heat treatment increased. Increase in both Vickers hardness and fracture toughness, and decrease in brittleness were observed which can be attributed to the increase in size of the nanoparticles in glass matrix. © 2014 Elsevier B.V.Item Statistical optimization of melt-quenching process parameters for multiple properties of ternary barium phosphate glasses(Elsevier Ltd, 2015) Narayanan, M.K.; Shashikala, H.D.; Manjaiah, M.In the present work simultaneous optimization of density, refractive index and hardness (multiple performance characteristics) of ternary barium phosphate glasses has been carried out using Taguchi based grey relational analysis. Effect of the parameters such as CaF2 content, melting temperature and melting time on the response parameters of (50 - X)BaO-XCaF2-50P2O5 (X = 0, 10, 20 mol%) glasses prepared according to the experimental layout of Taguchi's standard orthogonal array has been studied. Highest grey relational grade is the performance criteria used in this study to indicate the optimum level of process parameters needed for the best multiple performance characteristics. Analysis of variance (ANOVA) conducted on grey relational grade shows that under 95% confidence level, CaF2 content is the only parameter significantly affecting multiple performance characteristics. Experimental values of response parameters obtained by conducting the confirmatory experiment at optimum level of process parameters are closer to the optimal set of predicted values. © 2014 Elsevier B.V. All rights reserved.