Faculty Publications
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Item Thermal property study of fatty acid mixture as bio-phase change material for solar thermal energy storage usage in domestic hot water application(Elsevier Ltd, 2019) B.V., R.M.; Gumtapure, V.For the correct design, simulation and specific application of the latent heat thermal energy storage (LHTES) system, detailed evaluation of phase change material (PCM) properties are essential. Present study aims to analyze the thermal and volume dependent behavior of available organic Bio-PCM OM55, using conventional thermal gravimetric analyzer (TGA), thermal constant analyzer (TCA), differential scanning calorimeter (DSC) and in-house T-history method (THM). Execution of the mentioned thermal analysis outcome with significant information of OM55. TGA shows that OM55 is thermally stable within the operating temperature 45–60 °C, because the maximum permissible degradation temperature 154.6 °C is much higher than operating temperature range. The OM55 has considerable thermal conductivity compared to the existing PCM, which is already used in domestic solar water heating (DSWH) applications. The evaluation of transition temperature, isothermal enthalpy, and specific heat by THM are well compared with the DSC analysis. Comparison of DSC and THM analysis showed that the behavior of OM55 is volume independent. The overall study concluded that OM55 is a potential Bio-PCM. However, for the optimum amount of energy storage and discharge in OM55, it is recommended to operate the LHTES unit over a temperature range between 46–59 °C for domestic hot water application. © 2019 Elsevier LtdItem Thermo-physical analysis of natural shellac wax as novel bio-phase change material for thermal energy storage applications(Elsevier Ltd, 2020) B.V., B.V.; Gumtapure, V.The high energy density of latent heat storage makes it more competent than other types of thermal energy storage (TES) systems. Studying thermophysical and rheological properties of phase change material (PCM) is required for effective storage design, simulation, and applications. Bio-based PCM (BPCM) is a renewable and eco-friendly option for commercial paraffin-based PCMs. This study intends to characterize the shellac wax using the conventional and non-conventional approach as novel BPCM. Analysis of Fourier transforms infrared spectrophotometer (FTIR) indicates that shellac wax has aliphatic hydrocarbons, carboxylic acid, alcohol, and esters functional group. Thermogravimetric analysis (TGA) shows shellac wax has no mass change for operating temperature range (50–85 °C). Differential scanning calorimetry (DSC) analysis reported enthalpy of melting and crystallization as 148 kJ/kg and 161 kJ/kg, respectively. The crystallization enthalpy measured in the T-history method (THM) is 210.5 kJ/kg. However, DSC analysis of sample undergone 0,100,200 and 300 thermal cycle shows no significant change in thermal properties. Other properties like thermal conductivity, density, specific heat and viscosity are comparable to the present PCM used in storage applications. The overall study outcome that shellac wax is thermally stable and is potential BPCM for the TES application like solar desalination, district heating, waste heat recovery and solar cooking. © 2020 Elsevier LtdItem A quantitative approach for thermal characterization of phase change materials(ASTM International, 2021) Agarwala, S.; Prabhu, K.N.A quantitative method for the calculation of phase change parameters of salt-based phase change materials (PCMs) has been proposed. This technique involves the estimation of mold-salt interfacial heat flux by solving Fourier's law of heat conduction within the salt and using it for the calculation of phase change enthalpy of salt PCMs. Radial heat transfer was ensured by keeping the length to diameter (L/D) ratio of the mold equal to 5. The proposed method eliminates any drawbacks involved with sample size, reference material, the baseline fitting calculations, and the errors introduced due to the selection of solidification points. Pure salt PCMs such as potassium nitrate (KNO3), sodium nitrate (NaNO3), and solar salt mixture (60 wt. % NaNO3 + 40 wt. % KNO3) were used for validation of this technique. The thermal behaviors of the salt and the mold during solidification of the salt sample were analyzed, and solidification characteristics such as cooling rate, solidification time, and phase change enthalpy of PCMs were determined. © © 2021 by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959Item Removal of methylene blue dye using nano zerovalent iron, nanoclay and iron impregnated nanoclay-a comparative study(Royal Society of Chemistry, 2021) Tarekegn, M.M.; Mohan Balakrishnan, R.M.; Hiruy, A.M.; Hussen, A.H.There has been an increasing challenge from the emission of methylene blue (MB) dye-containing wastewater and its management methods in industry. The sorption process is one conventionally used method. In this study, nanoclay, nano zero valent iron (nZVI), and iron impregnated nanoclay were prepared and studied for the removal of MB dye in batch mode. The effects of operating parameters like pH, dye concentration, sorbent dosage, and contact time were investigated and optimized. The nZVI, nanoclay, and iron impregnated nanoclay sorbents showed zeta potentials of -32.1, -53.4, and -40.7 mV, respectively. All the nano adsorbents were crystalline. The nanoclay was characterized by an average surface area, pore volume and pore diameter of 43.49 m2 g-1, 0.104 cm3 g-1 and 2.806 nm, respectively. nZVI showed a surface area of 47.125 m2 g-1, pore volume of 0.119 cm3 g-1, and pore diameter of 3.291 nm. And iron impregnated nanoclay showed a surface area of 73.110 m2 g-1 with a pore volume of 15 cm3 g-1 and a pore diameter size of 3.83 nm. A Langmuir EXT nitrogen gas adsorption isotherm (R2 ? 0.99) was the best fit. The thermodynamics parameters, such as ?G° (-12.64 to -0.63 kJ mol-1), ?H° (+0.1 to +62.15 kJ mol-1) and ?S° (+0.10 to +0.22 kJ mol-1), confirmed that a spontaneous and endothermic adsorption process took place at a high rate of disorder. Iron impregnated nanoclay showed higher negative Gibbs free energy (-12.64 kJ mol-1), higher enthalpy change (+62.5 kJ mol-1) and entropy (+0.22 kJ mol-1) and gave a better MB removal performance. In addition, the lower negative heat of enthalpy for all adsorptions proved the dominance of physisorption. The methylene blue adsorption isotherm on nZVI and nanoclay showed the best fit with the Freundlich isotherm model with correlation coefficients (R2) ?0.98 and 0.99, respectively. Whereas the Langmuir adsorption isotherm was the best fit for iron impregnated nanoclay (R2 ? 0.98). The adsorption activities of nZVI, nanoclay and iron impregnated nanoclay were fitted to a pseudo-second-order kinetic model with correlation coefficients (R2) of 0.999, 0.997 and 0.983, respectively. The optimal pH 7.0 (RE: 99.1 ± 0.73%), initial MB concentration 40 ppm (RE: 99.9 ± 0.03%), contact time 120 min (RE: 99.9 ± 0.9%), and adsorbent dose 80 (99.9 ± 0.03%) were obtained for iron impregnated nanoclay. The optimal operational parameters of nanoclay and nZVI, respectively, were pH 11.0 and 13.0, initial MB concentration 20 and 20 ppm, adsorbent dose 100 and 140 mg, and contact time 120 and 140 min. In general, iron impregnated nanoclay has shown promising cationic dye adsorbance for industrial applications; but a recyclability test is suggested before scale-up. © The Royal Society of Chemistry.Item Experimental analysis of low-temperature grain drying performance of vertical packed clay and clay-additives composite desiccant beds(Springer, 2021) Hiremath, C.R.; Kadoli, K.A laboratory model of a forced circulation desiccant based green pea drying system operating in an open-loop is constructed and tested. The green pea drying process is divided into two stages involving dehumidification by the desiccant bed and green peas drying by dehumidified process air. Removal of moisture from the process air has been achieved by vertical packed composite desiccant beds. The composite desiccant used are heat treated clay with CaCl2 being impregnated and clay with additives like horse dung and sawdust, again being heated, treated and later impregnated with CaCl2. The green peas were dried for a process time of one hour. The drying was quite sharp during the initial process time of 500 s and from then onwards proceeded at a constant rate. For the identical bed masses, The performance of heat treated clay-additives based beds in moisture reduction and enhancement in enthalpy of process air is higher. The experimental study reveals the average heat content of air entering the dryer is 1.46, 2.46 and 2.38 kJ for heat-treated clay-CaCl2, clay-horse dung-CaCl2 and clay-sawdust-CaCl2 composite desiccant beds of 700 g mass. © 2021, Indian Academy of Sciences.Item Experimental study on sorption–desorption characteristics of natural composite desiccant with metal embedment(Elsevier Ltd, 2023) Dasar, S.R.; Anish, S.; Kadoli, R.; Yadav, A.K.The present study investigates the effect on total moisture sorption, moisture sorption rate, moisture desorption rate, and reduction in the temperature of dehumidified air of metal-embedded natural composite desiccants (MENCDs), which can be used in dehumidification systems. A natural composite desiccant, in which the unutilized portion of the spherical desiccant material is replaced with a metallic ball, is proposed. Stainless steel balls with a diameter of 4.75 and 6.35 mm are used to make different thickness ratios (TR = 1, 0.525, and 0.365) of MENCDs. The natural composite desiccant is prepared from dried cow dung and polyvinyl pyrrolidone with a ratio of 3:1. Experiments are conducted to find the optimum thickness ratio of MENCDs. The total moisture sorption, moisture sorption rate, total heat load reduction, and exergy efficiency of these dehumidification systems are investigated under different relative humidities (RH = 65% to 85%), and at a constant temperature and velocity. Desorption characteristics are tested under 328 K and 5% RH. The total moisture sorption of MENCDs with a TR of 0.365 is found to be 11.84 g/100 g, which is 17% higher compared to natural composite desiccants (i.e., TR = 1) at 85% RH, whereas, the total moisture sorption rate is 0.4 g/100 g⋅min, which is 20.57% higher for TR of 0.365 compared to TR = 1. Moisture desorption rate for TR = 0.365 is 16.66% higher compared to TR = 1. The average exergy efficiency of these systems is 60%. The average exergy efficiency of these composite desiccants with a TR = 0.365 is 9.6% higher compared to TR = 1. The average total heat load reduction for composite desiccants with a TR = 0.365 is 24% higher compared to TR = 1. The experimental study shows that the MENCDs will help to increase total heat load reduction, sorption and desorption rate, and total moisture sorption of dehumidified air with optimum thickness ratio for enhanced utilization of a composite desiccant for dehumidification systems. © 2023 Elsevier LtdItem A Phase Transformation Enthalpy Parameter for Modeling Quench Hardening of Steels(Springer, 2024) Samuel, A.; Pranesh Rao, K.M.P.; Prabhu, K.N.The effect of phase transformations on the steel/quenchant interfacial heat flux during quench hardening heat treatment is investigated in the present work. Experimental and modeling approaches comprising the inverse heat conduction problem (IHCP) were employed to analyze the thermal behavior of different steel grades with varying section thicknesses. The results revealed that phase transformation led to a distinctive pattern of the interfacial heat flux, characterized by a dip and subsequent rise. We observed that increasing the section thickness increases the surface heat flux for stainless steel probes without phase transformation. In contrast, the surface heat flux decreased with thicker sections in phase transformation. The increased heat evolved due to the latent heat liberation during phase transformation, and a reduction in thermal diffusivity due to increased specific heat caused a fall in the heat flow rates. Furthermore, the study proposed a phase transformation enthalpy parameter (ΔQ) to access the enthalpy change during quenching. ΔQ was consistent for a specific steel grade and independent of section thickness but varied with the cooling rate or quench media. The incorporation of phase transformation in the quenching heat transfer model is complex due to the required material data, including TTT/CCT diagrams and thermophysical properties that vary with steel grade. The study suggests directly incorporating the ΔQ values into the heat conduction equation or the IHCP model with phase transformation, simplifying the simulation process and minimizing data inputs. A database on ΔQ as a function of temperature and cooling rate would facilitate heat transfer modeling during quench hardening. © 2023, The Minerals, Metals & Materials Society and ASM International.