Faculty Publications
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Item The measurement of electrical conductivity for the investigation of the number of water molecules present in the mixed crystals of barium copper oxalate and barium ammonium oxalate lattice have been carried out in the temperature range 30 to 450 °C. The dehydration temperature and the number of water molecules removed out of the structure at a particular temperature is estimated from the sharp increase in conductivity at these points. The almost steep increase of conductivity is attributed to the increase in the number of mobile charge carriers H+ and OH– ions generated from the escaping water molecules. The study of electrical conductivity in association with the thermal behaviour has been used to understand the mechanism of conduction. Copyright © 1995 WILEY?VCH Verlag GmbH & Co. KGaA(Electrical Conductivity and Thermal Dehydration Studies of Mixed Single Crystals of BaCu(C2O4)2 · 6 H2O, Ba1–xCuxC2O4 · 4 H2O and Ba1–2x(NH4)2xC2O4 · 4 H2O) Kasthuri, V.B.; Mohan Rao, P.1995Item For successful modelling of the solidification process, a reliable heat transfer boundary condition data is required. These boundary conditions are significantly influenced by the casting and mould parameters. In the present work, the effect of sodium modification melt treatment on casting/chill interfacial heat transfer during upward solidification of an Al-13% Si alloy against metallic chills is investigated using thermal analysis and inverse modelling techniques. In the presence of chills, modification melt treatment resulted in an increase in the cooling rate of the solidifying casting near the casting/chill interfacial region. The corresponding interfacial heat flux transients and electrical conductivities are also found to be higher. This is attributed to (i) improvement in the casting/chill interfacial thermal contact condition brought about by the decrease in the surface tension of the liquid metal on addition of sodium and (ii) increase in the electronic heat conduction in the initial solidified shell due to change in the morphology of silicon from a acicular type to a fine fibrous structure and increase in the ratio of the modification rating to the secondary dendrite arm spacing. © 2003 Elsevier B.V. All rights reserved.(Elsevier BV, Effect of modification melt treatment on casting/chill interfacial heat transfer and electrical conductivity of Al-13% Si alloy) Prabhu, K.; Ravishankar, B.N.2003Item Heat transfer during quenching of modified and unmodified gravity die-cast A357 cylindrical bars(2006) Prabhu, K.; Hemanna, P.Heat transfer during quenching of chill-cast modified and unmodified A357 Al-Si alloy was examined using a computer-aided cooling curve analysis. Water at 60°C and a vegetable oil (palm oil) were used as quench media. The measured temperatures inside cylindrical probes of the A357 alloy were used as inputs in an inverse heat-conduction model to estimate heat flux transients at the probe/quenchant interface and the surface temperature of the probe in contact with the quench medium. It was observed that modified alloy probes yielded higher cooling rates and heat flux transients. The investigation clearly showed that the heat transfer during quenching depends on the casting history. The increase in the cooling rate and peak heat flux was attributed to the increase in the thermal conductivity of the material on modification melt treatment owing to the change in silicon morphology. Fine and fibrous silicon particles in modified A357 probes increase the conductance of the probe resulting in higher heat transfer rates. This was confirmed by measuring the electrical conductivity of modified samples, which were found to be higher than those of unmodified samples. The ultrasound velocity in the probes decreased on modification. ©ASM International.Item The effect of substrate temperature on the structural, optical and electrical properties of vacuum deposited ZnTe thin films(2009) Rao, G.K.; Bangera, K.V.; Shivakumar, G.K.The present paper reports the effect of substrate temperature on the structural, optical and electrical properties of vacuum deposited zinc telluride (ZnTe) thin films. X-ray diffraction (XRD) analysis of the films, deposited on glass substrates, revealed that they have cubic structure with strong (111) texture. Room temperature deposits are tellurium rich and an increase in the substrate temperature up to 553 °K results in stoichiometric films. Electrical conductivity has been observed to increase with the increase in substrate temperature, accompanied by increase in the carrier concentration and the mobility of the carriers. The optical bandgap energy and the thermal activation energy of the films have also been evaluated. © 2009 Elsevier Ltd. All rights reserved.Item Tropical, Seasonal River Basin Development through a Series of Vented Dams(2011) Shetkar, R.V.; Mahesha, A.Tropical rivers are predominantly seasonal in nature, and managing water resources during the deficit period is becoming more difficult because of the rapidly increasing demand for water. The present investigation focuses on harvesting Netravathi River water in the southern Indian peninsula through a series of vented dams with an estimated storage capacity of 102 Mm3 for use during the deficit period. A brief hydraulic design of a vented dam at a specific location is presented. The spacing and capacity of these reservoirs were worked out on the basis of the dam height and the river characteristics. The proposed vented dams are seasonal dams, and the closure of the vents will be decided on the flow available (i.e., 95% dependable flow), the storage capacity, and the minimum water release required for the downstream ecosystem. The appropriate time to start storing water in the vented dams was estimated to be in the month of November, and the entire process of storing water in the vented dams may last for about 41 days. An operational protocol for the storing process is presented. The investigations of aquifer parameters were performed by using electrical resistivity, pumping, and soil tests. The results indicated that the aquifer is shallow, unconfined in nature, and had a depth ranging from 18 to 30 m and hydraulic conductivity ranging from 62.6 to 406 m/day. A multiple regression model developed to assess the groundwater recharge in the adjoining well fields indicated that water table fluctuations may be 30% of reservoir level fluctuations. Because the river is also tidal in nature, a saltwater exclusion dam is proposed at the lower reaches of the river to prevent the entry of saltwater along the river during the summer period. © 2011 American Society of Civil Engineers.Item A comprehensive assessment of increased iron ore production on the environment - A case study(2011) Thimmaiah, S.A.; Rao, Y.; Murthy, C.H.S.N.There has been a significant increase in iron ore production in the Bellary- Hospet-Sandur sector of Karnataka, India due to sudden increase in the demand of iron ore from other countries as well as by local steel plants set up in the region. An attempt has been made in this paper to study the effect of increase in the iron ore production on various environmental parameters like air, water, soil and noise. For this purpose a study area of 10 Km radius was taken and the various environmental parameters were monitored before and after increase in iron ore production in the region. Study shows that there is no significant change in the air quality in terms of SPM, RPM, SO2 and NOx in the region. In many locations, there is decrease in the concentrations of these parameters. This is mainly due to improvement of roads by asphalting, effective covering of iron ore trucks by tarpaulin, awareness among mine owners about the protection of environment by following various pollution control measures, dust suppression measures on the public road using water sprinklers and stringent monitoring of the environmental protective measures by various regulatory authorities. The concentration of SO2 and NOx was found to increase due to increase in traffic by movement of tippers in the public/village road. The deployment of heavy earth moving machinery at mine site also contributed for increase of SO2 and NOx. The surface water quality parameters were found to be within the acceptable limits in the study area. There is no possibility of disturbing/altering ground water table due to mining operations as the mining is being carried out on hill top which is above the general ground level. In agricultural soil, except that of potassium and electrical conductivity, variations in other parameters are insignificant as the agricultural lands are located 2 to 3 Kms away from the active mining area. Increase in noise level is found at most of the locations of the study area. Therefore, serious attempts should be made by mine owners as well as statutory bodies to reduce the sound level at various locations for increasing the quality of life in these locations in terms of sound level. © 2011 CAFET-INNOVA technical society. All right reserved.Item Influence of nanoscale NiO on magnetic and electrochemical behavior of PVDF-based polymer nanocomposites(2012) Bhatt, A.S.; Bhat, D.K.New poly(vinylidene fluoride) (PVDF)/NiO-based polymer nanocomposites were prepared by phase inversion method, using dimethyl formamide as solvent and deionized water as non-solvent. The structure and porous morphology of the membranes were studied by field emission scanning electron microscopy. The presence of NiO resulted in overall decrease in porosity and crystallinity of the nanocomposite membranes. Using electrochemical impedance spectroscopy, a maximum ionic conductivity of 1.08 × 10 -3 S cm -1 was obtained for PVDF membrane with 1 wt% content of NiO. The good efficiency of conductivity observed in the membrane was explained on the basis of decrease in crystallinity and movement of charge carriers in NiO structure. The magnetization of nanocomposite membranes gradually increased with increase in NiO content. © 2011 Springer-Verlag.Item Study of the aluminium oxide doped zinc oxide thin films prepared by thermal evaporation technique(2012) Palimar, S.; Banger, K.V.; Shivakumar, G.K.The present study reports the observations made on investigations carried out to study structural, optical and electrical properties of aluminium oxide doped ZnO thin films obtained by thermal evaporation technique. Films obtained are found to be amorphous in nature with smooth and continuous surface. Room temperature conductivity of the film is found to be 5x10 3 U -1 cm -1 with visible region transmittance of above 95%. The optical energy gap of the film is found to be 3.25 eV. From the calculations of activation energy, it is observed that the doped ZnO film has two donor levels, one at 142 meV and other at 43 meV. A detailed analysis of the result is reported. © 2012 Asian Network for Scientific Information.Item Quantifying aquifer properties and freshwater resource in coastal barriers: A hydrogeophysical approach applied at Sasihithlu (Karnataka state, India)(2012) Vouillamoz, J.-M.; Hoareau, J.; Grammare, M.; Caron, D.; Nandagiri, L.; Legchenko, A.Many human communities living in coastal areas in Africa and Asia rely on thin freshwater lenses for their domestic supply. Population growth together with change in rainfall patterns and sea level will probably impact these vulnerable groundwater resources. Spatial knowledge of the aquifer properties and creation of a groundwater model are required for achieving a sustainable management of the resource. This paper presents a ready-to-use methodology for estimating the key aquifer properties and the freshwater resource based on the joint use of two non-invasive geophysical tools together with common hydrological measurements.
We applied the proposed methodology in an unconfined aquifer of a coastal sandy barrier in South-Western India. We jointly used magnetic resonance and transient electromagnetic soundings and we monitored rainfall, groundwater level and groundwater electrical conductivity. The combined interpretation of geophysical and hydrological results allowed estimating the aquifer properties and mapping the freshwater lens. Depending on the location and season, we estimate the freshwater reserve to range between 400 and 700 L m??'2 of surface area (A± 50%). We also estimate the recharge using time lapse geophysical measurements with hydrological monitoring. After a rainy event close to 100% of the rain is reaching the water table, but the net recharge at the end of the monsoon is less than 10% of the rain. Thus, we conclude that a change in rainfall patterns will probably not impact the groundwater resource since most of the rain water recharging the aquifer is flowing towards the sea and the river. However, a change in sea level will impact both the groundwater reserve and net recharge. © Author(s) 2012.Item Parameter estimation and vulnerability assessment of coastal unconfined aquifer to saltwater intrusion(2012) Mahesha, A.; Vyshali; Lathashri, U.A.; Ramesh, H.The focus of the present work is to characterize a tropical, coastal aquifer and to carry out its vulnerability to saltwater intrusion using hydrogeological parameters. The characterization of the aquifer involves pumping tests, vertical electrical sounding, and water quality analysis carried out at 41 monitoring wells. The area under investigation lies between two tropical, seasonal, tidal rivers, i.e., Pavanje and Gurpur rivers, joining the Arabian on the west coast of India. The aquifer is predominantly shallow and unconfined, having moderate to good groundwater potential with transimissivity and specific yield ranging from 49.2 to 461:4 m2/day and 0.00058 to 0.2805, respectively. The electrical resistivity tests indicated that the thickness of the aquifer ranges from 18 to 30 m. The study also investigates the saltwater affected areas in the region the vertical electrical sounding and water quality analysis. The resistivity results revealed several probable isolated saltwater intruded pockets in the region with resistivity less than 70 Om. From the salinity analysis of water, the locations that are affected during February to May (summer) and throughout the year are identified. The wells that are located close to the coast (< 350 m) and at lower elevations (well bottom < +1 m) were found to be saline throughout the year. Also, wells along the banks of the river show considerable salinity (> 200 ppm) during the summer period from tidal inflow along the rivers. The water samples were also analyzed for chloride to bicarbonate ratios during December to May at all the monitoring wells and were found to be exceeding the allowable limit at several locations. The saltwater vulnerability maps are derived for the area by the index-based method using the hydrogeological parameters. The method was found to be effective while compared to the field observations. The results from the analysis indicate that the aquifer is medium to highly vulnerable to saltwater intrusion at majority of the locations. The impact of projected sea level rise by 0.25 and 0.50 m from the climate change is also assessed on the vulnerability of the region to saltwater intrusion. © 2012 American Society of Civil Engineers.