Faculty Publications

Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736

Publications by NITK Faculty

Browse

Filters

2006 - 200932020 - 20222

Settings

Author: search.filters.author.Shrihari, S.Subject: search.filters.subject.laterite

Search Results

Now showing 1 - 7 of 7
  • No Thumbnail Available
    Item
  • No Thumbnail Available
    Item
  • No Thumbnail Available
    Item
    Effect of pH on the geotechnical properties of laterite
    (2006) Sunil, B.M.; Nayak, S.; Shrihari, S.
    Environmental Geotechnology has emerged as an interdisciplinary science, aiming and forecasting, analyzing and solving the geotechnical problems involving the influence of environmental factors. Lateritic soil of west coast region of India was studied to investigate the effect of soaking on the engineering properties and chemical characteristics of soil, soaked in different pH solutions (pH = 5.0, pH = 7.0, pH = 8.0). 12 N hydrochloric acid and 15 M ammonia solution were used to monitor the pH of the solution for about ninety days. Results showed that the pH of the solution has strong influence on the chemical characteristics of lateritic soil. The engineering properties of soil are altered when compared with the initial characteristics of the soil. The reason for this observed behavior of the soil is addressed in this paper. © 2006 Elsevier B.V. All rights reserved.
  • No Thumbnail Available
    Item
    Hydraulic and compaction characteristics of leachate-contaminated lateritic soil
    (2007) Nayak, S.; Sunil, B.M.; Shrihari, S.
    Large quantities of leachate-contaminated lateritic soil results from dump yards in the southwest coast of India. These dump yards receive large quantities of municipal solid waste which includes chemical, industrial and biomedical wastes. Large areas of land are currently being used for this purpose. An extensive laboratory testing program was carried out to determine the compaction characteristics and hydraulic conductivity of clean and contaminated lateritic soil. Batch tests were used to study the immediate effect of leachate contamination on the properties of lateritic soil. Contaminated specimens were prepared by mixing the lateritic soil with leachate in the amount of 5%, 10% and 20% by weight to vary the degree of contamination. The results indicated a small reduction in maximum dry density and an increase in hydraulic conductivity due to leachate-contamination. The change induced by chemical reaction in the microstructure of the soil was studied by scanning electron microscope before and after contamination of soil with leachate. The structure of the leachate contaminated soil sample appeared to be aggregated in scanning electron microscope analysis. The aggregated structure increases the effective pore space and thus increases the hydraulic conductivity. Fifty percent increase in hydraulic conductivity was observed for specimens prepared at standard Proctor density and mixed with 20% leachate. Compaction characteristics did not change much with the presence of leachate up to 10%. With 20% leachate the maximum dry density decreased slightly indicating excess leachate in the soil. However the changes are not significant. © 2007 Elsevier B.V. All rights reserved.
  • No Thumbnail Available
    Item
    Shear strength characteristics and chemical characteristics of leachate-contaminated lateritic soil
    (2009) Sunil, B.M.; Shrihari, S.; Nayak, S.
    Leachate is a hazardous liquid and is a major cause of concern in landfills. Numerous environmental problems such as soil and groundwater contamination occur in unlined landfills due to free flow of leachate. Large quantities of leachate-contaminated soils result from open dumping in the study area. These dump yards receive large quantities of municipal solid waste which includes chemical and industrial wastes. Large areas of land are currently being used for this purpose. An extensive laboratory testing program was carried out to determine the properties of clean and contaminated lateritic soils. Laboratory prepared municipal solid waste leachate was used in this study. Contaminated specimens were prepared by mixing the soils with MSW leachate in the increments of 0%, 5%, 10% and 20% by weight to vary the degree of contamination. The results showed that the MSW leachate affects the Atterberg limits, shear strength and chemical characteristics of the lateritic soils. The liquid limit and the plasticity index of the lateritic soils increases with MSW leachate concentration. For specimens tested at the Proctor density, effective cohesion increases and effective friction angle decreases due to increase in leachate concentration. This is attributed due to the increase in clay content of lateritic soil after interaction with the leachate. This led to increase in cohesion parameter and the friction angle decreases. The pH measurements of lateritic soil contaminated with MSW leachate indicated an increase in pH values. This is also accompanied by slight increase in the cation exchange capacity of the soil. The change in chemical characteristics of lateritic soil contributed due to addition of leachate may be detrimental to foundation concrete in real field conditions. The present work deals with an attempt to study the effect of leachate on the Atterberg limits, shear strength properties and chemical characteristics of lateritic soil. © 2009 Elsevier B.V. All rights reserved.
  • No Thumbnail Available
    Item
    Predictive simulation of leachate transport in a coastal lateritic aquifer when remediated with reactive barrier of nano iron
    (Elsevier B.V., 2020) Divya, A.; Shrihari, S.; Ramesh, H.
    The current study focuses on determination of extent of groundwater contamination on a typical tropical coastal aquifer due to a landfill located at Vamnjoor in Dakshina Kannada district, India with the help of groundwater flow model, MODFLOW and MT3DMS when remediated with permanent reactive barrier of nano iron. The aquifer considered is a shallow, unconfined one with laterite soil which gets good rains during monsoon and will be dry during rest of the year. The adsorption by laterite soil has been considered. The specific yield and transmissivity were estimated to be 7.85% and 213m2/day respectively. After calibrating successfully with Nash–Sutcliffe efficiency 0.8, horizontal hydraulic conductivity was set as 7 m/day. Validation of model was then done with the field data and is applied for forecasting the spread of contaminant for anticipated future scenarios. The results show that in spite of retardation offered by lateritic soil, contaminant trail is expanding with a velocity of 0.15 m/day in downstream direction. When permeable reactive barrier of nano iron which can adsorb nearly 65% of chemical oxygen demand is installed, it is showing that the contaminant spread can be reduced to 400 mg/l at the observation well located at 1 km from landfill. Hence a comprehensive remedial alternative of permanent reactive barrier of nano iron can be recommended for preventing groundwater contamination from landfill leachate. © 2020 Elsevier B.V.
  • No Thumbnail Available
    Item
    Extraction of iron from laterite soil and green synthesis of laterite nano iron catalyst (GLaNICs) for its application as Fenton's catalyst in the degradation of triclosan
    (IWA Publishing, 2022) Rashmishree, K.N.; Bhaskar, S.; Shrihari, S.; Thalla, A.K.
    Laterite based nano iron particles were synthesized using natural laterite extract as a precursor and Psidium guajava plant extract for its application as Fenton's catalyst in the degradation of triclosan. Chemical digestion method was used for the extraction of iron from laterite soil. Synthesized nano iron catalyst was characterized using SEM-EDS, XRD and FTIR and evaluated for its catalytic application in the Fenton's oxidation of triclosan. Maximum triclosan degradation of 69.5% was observed with nano iron catalyst dosage of 0.1 g/L and hydrogen peroxide dosage of 200 mg/L at acidic pH of 3. Hydrogen peroxide influence on the process was observed with Fenton's oxidation. Role of iron in the process has been accessed by control experiment with no nano catalyst addition in which degradation is considerably low. Fenton's oxidation was compared with conventional Fenton's oxidation driven by a green nano iron catalyst. Study claims the usage of natural laterite iron as a replacement for commercial iron in Fenton's degradation of triclosan. Regeneration and reusability studies on catalyst were studied and synthesized catalyst was observed to be reusable in three consecutive cycles. Degradation of triclosan in Fenton's oxidation follows pseudo-second order reaction with linear fit. © 2022 The Authors.