Faculty Publications
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Item A continuous flow microreactor as a practical tool for the synthesis of active pharmaceutical ingredients(Institution of Chemical Engineers, 2024) Bhaskar, K.; Rashed, M.; Bhat, K.; Lee, J.; Kim, K.-H.; Buruga, K.Continuous flow processing has become a key technology to maximize the capabilities of chemical syntheses. Numerous new tactics have been devised to synthesize various chemicals including active pharmaceutical ingredients (APIs) via a continuous flow system using microreactors. This review aims to illustrate the holistic system approach and diverse applications of continuous flow microreactors for the synthesis of APIs (with respect to type, design, and fabrication). This review also highlights the applicability of continuous flow microreactors in the synthesis of APIs in contrast to conventional batch-type methods along with a discussion of their merits and demerits. Overall, this review is expected to offer valuable insights into the utility of continuous flow microreactor technology for the upscaled production of commercially feasible APIs. © 2024 The Institution of Chemical EngineersItem Polystyrene-halloysite nano tube membranes for water purification(Korean Society of Industrial Engineering Chemistry A-803 Twin Bldg 275-3 Yangjae-Dong Seocho-Kul Seoul 137-130, 2018) Buruga, K.; Kalathi, J.T.; Kim, K.-H.; Ok, Y.S.; Boukhvalov, B.Membrane technologies are a sustainable solution for treatment of water and wastewater. Here, the technical feasibility of polystyrene-halloysite nanotube (PS-HNT) membranes, fabricated by an ultrasound-assisted solution casting method, was explored for water purification. To this end, the effects of various solvents on the structure, morphology, thermal, and mechanical properties of PS-HNT membranes were investigated. Introduction of HNTs (5 wt%) into the polystyrene matrix demonstrated excellent thermal and mechanical properties along with good water flux, rejection of unwanted components, recovery, and regeneration cycles. These membranes were overall useful enough to purify real wastewater collected from pulp and paper mill. © 2017 The Korean Society of Industrial and Engineering ChemistryItem Experimental and theoretical studies of various solar control window glasses for the reduction of cooling and heating loads in buildings across different climatic regions(Elsevier Ltd, 2018) G, K.K.; Saboor, S.; Kumar, V.; Kim, K.-H.; Babu, A.The glass material and position/orientation of windows are very important to control the heat gain in buildings. In this article, we studied the effect of different window glazing materials (such as bronze, green, grey, bronze-reflective, green-reflective, grey-reflective, gold-reflective, opal blue-reflective, and sapphire blue-reflective glass) in controlling the heat gain by the buildings. The spectral data of diverse window glasses have thus been measured in solar spectrum range of 300–2500 nm. Moreover, the MATLAB codes have been developed to compute solar optical properties (including transmittance, reflectance, and absorbance), solar heat gain coefficient (SHGC), and heat transfer through the glazing material. Thermal analysis was carried out using a total of nine window glasses in eight coordinal directions (E, W, N, S, SE, SW, NE, and NW) against three climatic conditions (hot and dry, warm and humid and composite) in India. In terms of net annual cooling and heating cost savings per window, the grey reflective glass was found to be the most energy saving glass among all glasses tested in this study. The grey reflective glass exhibited the highest cost saving in net annual cooling and heating in all eight orientations across three climatic regions. The grey reflective glass saved the net cost of heating and cooling by $ 61.24 per annum in the south orientation of Jodhpur climatic conditions. © 2018 Elsevier B.V.Item A review on functional polymer-clay based nanocomposite membranes for treatment of water(Elsevier B.V., 2019) Buruga, K.; Song, H.; Shang, J.; Bolan, N.; Kalathi, J.T.; Kim, K.-H.Water is essential for every living being. Increasing population, mismanagement of water sources, urbanization, industrialization, globalization, and global warming have all contributed to the scarcity of fresh water sources and the growing demand of such resources. Securing and allocating sufficient water resources has thus become one of the current major global challenges. Membrane technology has dominated the field of water purification due to its ease of usage and fabrication with high efficiency. The development of novel membrane materials can hence play a central role in advancing the field of membrane technology. It is noted that polymer-clay nanocomposites have been used widely for treatment of waste water. Nonetheless, not much efforts have been put to functionalize their membranes to be selective for specific targets. This review was organized to offer better insights into various types of functional polymer and clays composite membranes developed for efficient treatment and purification of water/wastewater. Our discussion was extended further to evaluate the efficacy of membrane techniques employed in the water industry against major chemical (e.g., heavy metal, dye, and phenol) and biological contaminants (e.g., biofouling). © 2019 Elsevier B.V.Item Thermal and cost analysis of various air filled double glazed reflective windows for energy efficient buildings(Elsevier Ltd, 2020) Gorantla, G.; Saboor, S.; Vali, S.S.; Mahapatra, D.; Talanki Puttaranga Setty, A.B.; Kim, K.-H.The enormous amount of energy is being consumed by buildings in an attempt to deliver thermal comfort in buildings. This paper aims at reducing/increasing the total solar heat gain through various combinations of double glazed reflective windows of buildings. The spectral characteristics of six reflective glasses namely bronze, green, grey, opal blue, sapphire blue and gold-reflective glasses at a normal angle of incidence by using UV-3600 Shimadzu spectrophotometer according to ASTM E 424 standards were experimentally measured. The solar optical properties of the glasses were deduced by developing a MATLAB code using spectral data which was obtained from experiments in the solar spectrum wavelength range of 300 nm–2500 nm. Thirty air-filled double-glazed reflective windows have been studied for both thermal and cost analysis in the Indian composite climatic zone (New Delhi 28.580 N, 77.200 E). The configuration C13 (Grey reflective glass-Air gap 10 mm-Gold reflective glass) is observed to be the best air-filled double glazed window from the highest annual cost savings ($ 79.29 per annum in SE direction) and lower payback period (1.42 years) point of views among thirty double-glazed reflective glasses studied. The results of this paper are useful in the design of sustainable passive solar buildings. © 2019 Elsevier LtdItem An efficient system for electro-Fenton oxidation of pesticide by a reduced graphene oxide-aminopyrazine@3DNi foam gas diffusion electrode(Elsevier B.V., 2020) Senthilnathan, J.; Younis, S.A.; Kwon, E.E.; Surenjan, A.; Kim, K.-H.; Yoshimura, M.A stable rGO-AmPyraz@3DNiF gas diffusion electrode was prepared via modification of 3D nickel foam (3D-NiF) with aminopyrazine functionalized reduced graphene oxide (rGO-AmPyraz) for the electro Fenton (EF) process. The generation capacity of H2O2 and OH radicals by this electrode was assessed relative to 3DNiF and rGO-AmPyraz@indium tin oxide (ITO) electrodes and with/without a coated Fe3O4 plate. The rGO-AmPyraz@3DNiF electrode showed the maximum production of these radicals at 2.2 mmol h?1 and 410 ?mol h?1, respectively (pH 3) with the least leaching of Ni2+ such as < 0.5 mg L?1 even after 5 cycles (e.g., relative to 3DNiF (24 mg L?1). Such control on Ni ion leaching was effective all across the tested pH from 3 to 8.5. Its H2O2 generation capacity was far higher than that of the nanocarbon supported on commercially available ITO conductive glass. The mineralization of dichlorvos (at initial concentration: 50 mg L?1) was confirmed with its complete degradation as the concentrations of the end products (e.g., free Cl?1 (5.36 mg L?1) and phosphate (12.89 mg L?1)) were in good agreement with their stoichiometric concentration in dichlorvos. As such, the proposed system can be recommended as an effective electrode to replace nanocarbon-based product commonly employed for EF processes. © 2020 Elsevier B.V.