Faculty Publications

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    An Investigation into the Relative Efficacy of High-Velocity Air-Fuel-Sprayed Hydroxyapatite Implants Based on the Crystallinity Index, Residual Stress, Wear, and In-Flight Powder Particle Behavior
    (American Chemical Society, 2023) Jagadeeshanayaka, N.; Kele, S.N.; Jambagi, S.C.
    Due to its resemblance to the bone, hydroxyapatite (HA) has been widely used for bioactive surface modification of orthopedic implants. However, it undergoes significant thermal decomposition and phase transformations at a high operating temperature, leading to premature implant failure. This investigation uses high-velocity air-fuel (HVAF) spray, an emerging low-temperature thermal spray technique, to deposit HA over the Ti-6Al-4V substrate. Coating characteristics, such as the crystallinity index and phase analysis, were measured using X-ray diffraction, Raman analysis, and Fourier transform infrared spectroscopy, residual stress using the sin2ψ method, and tribological performance by a fretting wear test. The coating retained an over 90% crystallinity index, a crystallite size of 41.04 nm, a compressive residual stress of −229 ± 34.5 MPa, and a wear rate of 1.532 × 10-3 mm3 N-1 m-1. Computational in-flight particle traits of HA particles (5 to 60 μm) were analyzed using computational fluid dynamics; it showed that 90% of particles were deposited at a 700 to 1000 m/s velocity and a 900 to 1450 K temperature with a 2.1 ms mean residence time. In-flight particle oxidation was minimized, and particle impact deformation was maximized, which caused severe plastic deformation, forming crystalline, compressive residual stressed coatings. The thermal decomposition model of low-temperature HVAF-sprayed HA particles helped to understand the implants’ crystallinity index, residual stress, and tribological characteristics. Hence, this experimental and computational analysis shows that the HVAF process can be a promising candidate for biomedical applications for having strong and durable implants. © 2023 American Chemical Society.
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    An investigation of slurry erosion behaviour in plasma-sprayed carbon nanotube-reinforced fly ash/alumina coatings using experimental analysis and artificial neural computing for marine and offshore applications
    (Elsevier Ltd, 2024) Chavana, N.; Anil, A.; Jambagi, S.C.
    This study investigates carbon nanotube (CNT)-reinforced alumina fly ash (FA) coatings, namely AF (unreinforced), 1CAF (with 1 wt% CNT), and 2CAF (with 2 wt% CNT), on marine-grade steel. Microstructural analysis shows 1CAF coatings denser by ∼15.32% due to CNT reinforcement, while 2CAF coatings display ∼9.68% increased porosity from CNT agglomeration. Raman spectroscopy confirms CNT retention. 1CAF coatings exhibit ∼14.66% higher microhardness, ∼15.96% higher adhesion strength, and ∼15.66% improved fracture toughness compared to AF coatings, attributed to pore sealing through CNT reinforcement. Enhanced erosion resistance (∼14.59%) in 1CAF coatings was observed due to improved mechanical properties and CNTs mitigating crack propagation. Validation through an artificial neural network (ANN) modeling and regression analysis supports 1CAF coatings’ promise for harsh marine environments, offering enhanced durability. © 2024 Elsevier Ltd
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    Comparative analysis of flipped and overlapped microwave sintered plus friction stir processed in-situ Al-Cu composites
    (Springer Nature, 2024) Vinayak, V.R.; Bajakke, P.A.; Jambagi, S.C.; Bhajantri, V.; Deshpande, A.S.
    The in-situ Al-Cu composites were fabricated with Cu content more than the solubility limit (5.65%) and the critical composition of an Al-Cu alloy (4.6%). A powder metallurgy route with state-of-the-art microwave sintering and friction stir process with overlapped and flipped conditions was attempted. The overlapped friction stir resulted in a minimum area of nugget region, unidirectional material mixing, high heat input in successive passes, and brittleness in the material. This accounted for the material to exhibit high strength with low ductility. Whereas flipped friction stir leads to a maximum area of stir zone, bidirectional material mixing, and similar thermal cycles in individual passes and avoids excessive heating. This facilitated the material to possess maximum strength by retaining ductility. The newly developed in-situ Al-Cu composite material (with Cu wt% in ranges of 8–12) possesses equivalent strength, ductility, electrical conductivity, and rate of corrosion compared to copper. Notably, these attributes, combined with its cost-effectiveness, position this material as a promising alternative to copper conductors in electrical applications. From the present investigation, it is strongly recommended to choose a flipped friction stir for better properties. © Qatar University and Springer Nature Switzerland AG 2024.