Faculty Publications
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Item Supramolecular synthons in noncovalent synthesis of a class of gelators derived from simple organic salts: Instant gelation of organic fluids at room temperature via in situ synthesis of the gelators(2009) Das, U.K.; Trivedi, D.R.; Adarsh, N.N.; Dastidar, P.(Chemical Equation Presented) The supramolecular synthon approach has been employed to synthesize noncovalently a series of low molecular mass organic gelators (LMOGs) derived from benzylammonium salts of variously substituted benzoic acids. The majority of the salts (75%) prepared showed interesting gelation properties. Instant gelation of an organic fluid, namely methyl salicylate, was achieved at room temperature by using most of the gelator salts by in situ synthesis of the gelators. Table top rheology and scanning electron microscopy (SEM) were used to characterize the gels. Single crystal X-ray diffraction studies revealed the presence of both 1D and 2D supramolecular synthons. X-ray powder diffraction (XRPD) studies indicated the presence of various crystalline phases in the fibers of the xerogels. By using these data, a structure-property correlation has been attempted and the working hypothesis for designing the gelator has been reinforced. © 2009 American Chemical Society.Item Dual colorimetric receptor with logic gate operations: Anion induced solvatochromism(Royal Society of Chemistry, 2014) Kigga, M.; Swathi, N.; Manjunatha, J.R.; Das, U.K.; Nityananda Shetty, A.N.; Trivedi, D.R.A receptor R1 was designed and synthesised for colorimetric detection of F- ions as well as Cu2+ ions via intramolecular charge transfer mechanism. Upon addition of F- ions in dry DMSO, the color of the receptor R1 changed from pale yellow to blue. The receptor showed a unique property of solvatochromism by displaying different coloration with different solvents only in the presence of F- ions, which were applied to determine the percentage composition of binary solvent mixtures. The receptor R1 was able to detect Cu2+ ions colorimetrically where it exhibited a color change from pale yellow to orange-red. In addition, the receptor was subjected to molecular logic gate applications, wherein it showed 'ON-OFF' switching operations. © 2014 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.Item An Efficient Three-component, One-pot Synthesis of Quinazolines under Solvent-free and Catalyst-free Condition(HeteroCorporation support@jhetchem.com, 2015) Bhat, S.I.; Das, U.K.; Trivedi, D.R.An efficient green protocol for the synthesis of quinazolines in the absence of solvent and catalyst has been developed. 2,4-Disubstituted quinazolines have been synthesized from three-component one-pot reactions of 2-aminoaryl ketones, orthoesters, and ammonium acetate. The present method has advantages of operational simplicity, substrate generality, clean reaction, high yields (76-94%), and moderate reaction time. The plausible mechanism of the reaction has been proposed based on the spectral characterization and single crystal X-ray analysis of isolated intermediate. © 2014 HeteroCorporation.Item The hierarchies of hydrogen bonds in salts/cocrystals of isoniazid and its Schiff base - A case study(Royal Society of Chemistry, 2016) Oruganti, M.; Khade, P.; Das, U.K.; Trivedi, D.R.A series of two salts of isoniazid and two cocrystals of its Schiff base have been synthesised and characterized using FT-IR, 1H-NMR, DSC, XRPD and SCXRD. The crystal structures with 2,5-dihydroxybenzoic acid, 2,6-dihydroxy benzoic acid, 3-aminobenzoic acid and o-phthalic acid have been deduced. In all complexes the involvement of pyridine N (proton transfer/robust synthon) is noticed. The unit cell similarity index was calculated between two cocrystals (N-(propan-2-ylidene)isonicotinohydrazide)·(2,5-dihydroxybenzoic acid) and (3-aminobenozic acid)·(N-(propan-2-ylidene)isonicotinohydrazide). Furthermore, the index was compared with the reported complexes and it was found to be close to zero indicating isostructurality. The correlation between the NPyr-H?O (acid) hydrogen bond distance for the reported cocrystals and their corresponding pKa values has been deduced and validated. © The Royal Society of Chemistry 2016.