Faculty Publications
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Item Microstructural study of steel-concrete interface and its influence on bond strength of reinforced concrete(ASTM International, 2019) Goudar, S.K.; Das, B.B.; Arya, S.B.In this investigation, the variations in steel-concrete interface (SCI) properties, such as porous zone thickness and calcium hydroxide content around the reinforcing steel, were studied with respect to curing time. Three kinds of commercially used cements, ordinary portland cement (OPC), portland pozzolana cement (PPC), and portland slag cement (PSC), were used, and their significance regarding SCI properties was investigated. A reliable thresholding grayscale-based technique was used to determine the porous zone thickness at the SCI. The properties of SCI were found to be quite influenced by the curing period. The PSC concrete showed significant reduction in mean porous zone thickness at SCI compared with OPC and PPC concrete after 90 days of curing. The reduction in mean porous zone thickness can be considered one of the many influencing factors that resulted in increased ultimate bond strength at 90 days of curing. Also, the variation in calcium hydroxide content from the SCI toward the bulk concrete was examined with a scanning electron microscope empowered with energy-dispersive spectroscopy. The findings indicate a gradual decrease in calcium hydroxide content away from the steel surface toward the bulk concrete. The prolonged curing resulted in a slightly higher reduction of calcium hydroxide content around the SCI for PPC and PSC concrete because of the pozzolanic reactions. Higher reduction of calcium hydroxide content around the SCI for PPC and PSC concrete is predicted to be the reason for improved ultimate bond strength after prolonged curing. © 2019 by ASTM International.Item Ferrochrome ash – Its usage potential in alkali activated slag mortars(Elsevier Ltd, 2020) Kumar, K.B.; Yaragal, S.C.; Das, B.B.This study is an attempt to develop a sustainable construction material, i.e., alkali activated slag (AAS) in combination with ferrochrome ash (FCA) as a replacement to ordinary Portland cement (OPC). The effect of the various levels of FCA (0, 25, and 50%) replacing ground granulated blast furnace slag (GGBS) in AAS mortars with 4% of Na2O dosage is studied. Further, five levels of the modulus of silica (Ms = 0.75, 1.00, 1.25, 1.5, and 1.75) are chosen to achieve targeted compressive strength at 28 days under ambient temperature curing conditions. The compressive strength decreases with the increase in level of the FCA replacement. The targeted design compressive strength is achieved with 25% FCA replacement to GGBS in the AAS mortar system with Ms = 1.25. In addition, microstructure and mineralogical studies are undertaken to ascertain the formation of different hydration products with the aid of the scanning electron microscope (SEM) and the X-ray diffractometer (XRD). Gismondine and calcium aluminate silicate hydrate (C-A-S-H) are the major hydration products in the AAS mortar mixes. Sodium aluminate silicate hydrate phases (N-A-S-H) are also observed prominently as the FCA replacement level increases in the AAS mortar mixes. The Fourier-transform infrared spectroscopy (FTIR) confirms the presence of the Si–O-(Si or Al) functional group. The addition of FCA in the AAS system is of vital significance in the reduction of the embodied carbon dioxide (ECO2eq), embodied energy (EEeq) and cost. © 2020 Elsevier LtdItem Influence of Geopolymerization Factors on Sustainable Production of Pelletized Fly Ash-Based Aggregates Admixed with Bentonite, Lime, and GGBS(American Society of Civil Engineers (ASCE), 2023) Sharath, B.P.; Snehal, K.; Das, B.B.; Barbhuiya, S.This experimental research investigates the influence of geopolymerization factors such as Na2O dosages, water and mineral admixture [bentonite (BT), burnt lime (BL), and ground granulated blast furnace slag (GGBS)] on physiomechanical properties of the pelletized fly ash (FA)-based aggregates. Taguchi's L9 orthogonal array was adopted to design the mixing ratios for three kinds of fly ash-based aggregates (in the combinations of FA-BT, FA-BL, and FA-GGBS). The degree of geopolymerization of the produced aggregates was characterized using thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and a scanning electron microscope (SEM). Most influential response indices in the production of pelletized aggregates were identified using gray relational analysis. The physiomechanical characteristics of the fly-ash aggregates were significantly improved by admixing BL than that of GGBS and BT. However, pelletization efficiency was seen to be superior for GGBS-substituted fly-ash aggregates. The quantified amount of hydration products, i.e., sodium alumino-silicate hydrate (N-A-S-H)/calcium alumino-silicate hydrate (C-A-S-H) for fly ash-based aggregates intensified on increasing Na2O and mineral admixture dosages. The results strongly suggest the existence of a linear relationship between the quantified amount of N-A-S-H/C-A-S-H and individual pellet strength of produced aggregate. The FTIR spectrum showed strong and broadened bands of Si-O terminal for all types of aggregates, representing the conversion of unreacted minerals to chains of aluminosilicate gel (geopolymerized hydration product). Further, it can also be inferred from gray relational analysis that among all other factors, Na2O content significantly impacted the engineering properties of produced fly ash-based aggregates. © 2023 American Society of Civil Engineers.Item IMPLICATION OF HIGH-VOLUME MINERAL ADMIXTURE ON MECHANICAL PROPERTIES AND MICROSTRUCTURE AT STEEL-CONCRETE INTERFACE(Associated Cement Companies Ltd., 2023) Goudar, S.K.; Sumukh, E.P.; Das, B.B.The existence of a non-homogeneous unique zone in concrete along the periphery of steel surface is being referred as steel-concrete interface (SCI). The interface between steel and concrete exhibits a porous zone, with a thickness measuring several micrometers. This porous zone thickness around SCI plays a crucial role in influencing bond strength, durability, and is a significant parameter used in service life prediction models for reinforced concrete structures. The value of porous zone thickness around SCI is being assumed and adopted without any practical studies in service life prediction models as well as in reinforced concrete mesoscale structure modelling. In the present study, porous zone thickness was experimentally measured through obtaining backscattered electron images around SCI. Gray scale-based thresholding technique was employed to ascertain the porous zone thickness (PZT) around SCI. Furthermore, the influence of incorporating ground granulated blast furnace slag (GGBS) in high-volume on the interfacial transition zone (ITZ) between steel reinforcement bars and the surrounding concrete was investigated. It was observed that porous zone thickness around SCI varies in every other point along the periphery of reinforcement bar. The pozzolanic reaction in high volume GGBS concrete resulted in a substantial decrease of porous zone thickness (PZT) and reduced the accumulation of Portlandite around SCI with the progress in curing age. The factors contributing to the enhanced ultimate bond strength of high volume GGBS concrete compared to control concrete are the decrease in the Porous Zone Thickness (PZT) along with the reduced Ca/Si ratio around the SCI. © 2023, Associated Cement Companies Ltd.. All rights reserved.Item Influence of multi-stage processing and mechano-chemical treatments on the hydration and microstructure properties of recycled aggregate concrete(Elsevier Ltd, 2023) Trivedi, S.S.; Sarangi, D.; Das, B.B.; Barbhuiya, S.On account of the shortage of naturally occurring coarse aggregate, recycled aggregate (RA) made from crushed concrete debris is now used in the construction industry. With this rise in the utilisation of recycled aggregate in the construction sector, there has been extensive research into ways to improve its quality. The significant fraction of mortar remains that are left on the RA surface is the primary factor that affects its quality. Concrete made from RA loses strength and mechanical performance due to the attached mortar's increased porosity and water absorption values and the frailer transition region between the new mortar and aggregates. In order to minimise the old cement fractions and increase the quality, this paper studies the effect of concrete incorporating multi-stage processed RA from demolished concrete waste, followed by treatment with mechanical abrasion and sodium silicate immersion. The recycled aggregates were produced through multi-stage jaw crushing, followed by utilising natural aggregate, recycled aggregate, and recycled aggregate obtained after mechanical abrasion, followed by sodium silicate treatment for concrete mix design at various substitution percentages as coarse aggregates. The experimental investigation further progresses with the evaluation of mechanical and durability properties of concrete mixes, which is additionally followed by microstructural studies such as scanning electron microscopy (SEM), Energy dispersive X-ray spectroscopy (EDAX), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Thermogravimetry-differential thermal analysis (TG-DTA). The outcomes demonstrate that two-stage treatment, such as mechanical abrasion followed by sodium silicate immersion, yields superior-quality RA. Recycled aggregate concrete (RAC) made with these treated aggregates illustrated an increase in workability and density with respect to an untreated RAC mix. Furthermore, comparable strengths in compression, flexure, and tension are found in treated RAC mixes, particularly at 35% replacement levels, with respect to concrete mixes comprised of natural aggregates. A similar trend is detected in the chloride penetration tests and water sorptivity tests. In addition, the microstructural investigation confirmed the formation of additional calcium silicate hydrate for treated RAC mixes, particularly for the 35% substituted RA mix. On the basis of the results, it is suggested that multi-stage jaw crushing followed by treatment through mechanical abrasion and sodium silicate can potentially enhance the mechanical, microstructural, and durability performance of RAC. © 2023 Elsevier LtdItem Synergy of Hydration and Microstructural Properties of Sustainable Cement Mortar Supplemented with Industrial By-Products(Springer Science and Business Media Deutschland GmbH, 2024) Sumukh, E.P.; Das, B.B.; Barbhuiya, S.The present research assists in resolving the issues allied with the disposal of industrial solid wastes/industrial by-products (IBPs) by developing sustainable IBPs based cement mortars. The applicability of IBPs as a feasible alternative to river sand in cement mortar has been evaluated by investigating the synergy among the ingredients, resulting engineering properties and microstructural developments at early and late curing ages. The study could effectively substitute 30% volume of river sand with bottom ash and 50% in the case of slag sand mortars. The experimental outcomes disclose that the practice of IBPs as fine aggregate enhances the engineering properties of mortar and the optimum replacement level lies at 10% and 40% usage of bottom ash and slag sand, respectively. The advanced characterization studies and particle packing density illustrate the refinement of pores by void filing action and accumulation of additional hydration products through secondary hydration reactions. The consumption of portlandite followed by increased hydration products formation observed through thermogravimetric analysis, X-ray diffraction analysis and energy dispersive X-ray spectroscopy that confirmed the contribution of finer fractions of IBPs to secondary hydration reactions. This constructive development was also observed from the lowering of wavenumber corresponding to Si–O–Si/Al vibration bands in Fourier transform infrared spectroscopy spectra. The improved microstructure resulted in enhancing the compressive strength by 9.01% and 18.18% in optimized bottom ash and slag sand mortars, respectively at the curing age of 120 days. Similarly, the water absorption reduced by 1.03% and 1.24% in bottom ash and slag sand mortars, respectively. © The Author(s), under exclusive licence to the Iran University of Science and Technology 2024.Item Combined Effect of Multistage Processing and Treatment Methods on the Physical, Chemical, and Microstructure Properties of Recycled Concrete Aggregates(ASTM International, 2024) Trivedi, S.S.; Dixit, K.; Das, B.B.; Barbhuiya, S.This research aims to examine the effects of multistage processing on reducing the old cement fractions and enhancing the quality of concrete recycled aggregate (CRA). The investigation involves the use of demolished concrete debris and subsequent treatments in both single and multistage processes. The recycled aggregates (RAs) were obtained using a multistage jaw crushing process followed by utilizing natural aggregate, untreated RA, RA treated with hydrochloric acid (HCl) and sodium silicate (SS) immersion (single-stage treatment), and RA treated with mechanical scrubbing and SS immersion in two separate stages (multistage treatment). The subsequent phase of the experimental inquiry involves assessing the physical attributes of both treated and untreated RA. This is followed by conducting microstructural examinations utilizing techniques such as scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), and thermogravimetry-differential thermal analysis. The findings indicate that employing a two-step process, involving mechanical abrasion followed by immersion in SS, yields high-quality CRA. This conclusion is reinforced by the favorable physical performance observed. The water absorption values of CRA were lowered by 78 % through single-stage treatments such as immersion in HCl. The similar treatment is found to show densest concrete with calcium/silicon ratio reduced to around 81 % to that of untreated CRA. Additionally, for single-stage treated CRA samples, microstructural study using FTIR verified the creation of additional hydration products, whereas for two-stage treated CRA specimens, thermogravimetric analysis demonstrated the formation of stable CSH. According to the findings, it is advised to use a multistage process of jaw crushing, then treating it with mechanical abrasion and SS. This has the ability to improve the physical, chemical, and microstructural properties of CRA. © © 2024 by ASTM International,Item 3D printing aspects of fly ash and GGBS admixed binary and ternary blended cementitious mortar(Taylor and Francis Ltd., 2025) Mishra, S.K.; Upadhyay, B.; Das, B.B.This study investigates the integration of Ground Granulated Blast Furnace Slag (GGBS) and fly ash to sustainably reduce the usage of Ordinary Portland Cement (OPC) in 3D printable mortar to enhance printability and engineering performance. Four mortar mixes were developed, and their printability parameters, such as flowability, extrudability, open time, yield stress, shape retention, and buildability, were assessed. Among mixes, O70G30 (70% OPC, 30% GGBS) showed the best printability, with an 18.3% and 54.3% higher shape retention factor than the control and O70F30 mixes, respectively, which can be attributed to improved particle packing and 5.5% higher yield stress. However, its open time was 22.2% lower than the control. This reduction can be attributed to the finer particle size and higher specific surface area of GGBS, which increased water demand and accelerated the loss of workability. In the hardened state, O70G30 exhibited 24% lower water absorption and 18.5% reduced permeable porosity than the control, indicating a denser microstructure. Printed specimens exhibited anisotropic strength, with the highest values observed on the YZ plane and the lowest on the ZX plane. Depending on the loading direction and mix composition, their compressive strength was 9.4–35.6% lower than that of mould-cast samples, while the flexural strength improved by 16.19% to 40.18%. Microstructural analysis revealed a denser matrix with a lower Ca/Si ratio and enhanced secondary hydration, evidenced by stronger C–S–H peaks in XRD, pronounced Si–O–Si/Al bands in FTIR, and 41.22% higher bound water (WH) with reduced portlandite (CH) in TGA compared to O70F30. These promising results can be attributed to GGBS’s role in enhancing hydration, refining the microstructure, and improving the performance of 3D printable mortar, offering a sustainable and effective pathway for digital construction. Also, the Life Cycle Impact Analysis (LCIA) revealed that the incorporation of supplementary cementitious materials (SCMs) significantly reduces environmental impacts compared to the control mix. © 2025 Informa UK Limited, trading as Taylor & Francis Group.