Faculty Publications
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Item Effects of Solvents on Structure, Morphology and Thermal Stability of Polystyrene-HNTs Nanocomposites by Ultrasound Assisted Solution Casting Method(Elsevier Ltd, 2017) Buruga, K.; Kalathi, J.T.Polymer-clay nanocomposites are extensively investigated as they are economical in comparison with other nanofillers and drastically enhances various physical and engineering properties of polymers. Among various clays used for polymer-nanocomposites, Halloysite nanotubes (HNTs) have gained tremendous attention as they have unique structure and properties. In the present work we have successfully synthesised polystyrene-HNT nanocomposites by ultrasound assisted solution intercalation method. In this method solvent plays a very crucial role in enhancing the overall properties of resultant nanocomposites as arrangement of filler in the polymer matrix depends upon how well the solvent is able to disperse filler which inturn enhances polymer properties. Hence in this work solvents toluene, benzene, chloroform, dichoromethane (DCM), tetrahydrofuran (THF) and carbontetrachloride (CCl4) were used for synthesis of nanocomposites and effect of these solvent on structure, morphology and thermal stability of nanocomposites was investigated. As per the characterization analysis, toluene was found to be the best solvent for synthesis of nanocomposites with enhanced properties and use of ultrasound aided in uniform distribution of clay in polymer matrix. Increase in basal spacing on sonication was revealed by x-ray diffraction (XRD) analyses. Scanning electron microscopy (SEM) results revealed uniform dispersion of filler inside the matrix on using acoustic cavitation as it promotes proportionate distribution of filler into the polymer matrix. Fourier transform and infrared (FT-IR) results confirmed encapsulation of HNTs into polymer. Differential scanning calorimetry (DSC) reports illustrated increase in glass transition temperature (Tg) on incorporating HNTs. © 2017 Elsevier Ltd.Item Ultrasound assisted Synthesis of Poly (styrene-Co-methylmethacrylate)-HNT's Nanocomposites by In-Situ Emulsion Copolymerization and its Characterization(Elsevier Ltd, 2017) Buruga, K.; Kalathi, J.T.Poly (styrene-co-methylmethacrylate)-HNT nanocomposites have been successfully synthesized by ultrasound assisted emulsion copolymerization without modification of HNT's. The key parameters that affect the stability of the emulsion and hence the properties of the resulting nanocomposites are sonication time and clay loading. The effectsof these parameters on the process were investigated in this study. Thesynthesized nanocomposites were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform and infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) to investigatemorphology and thermal stability. The embodiment of the HNTs into the copolymer matrix was confirmed by FTIR, and XRD analyses positively delineated the complete exfoliation of HNTs into the copolymer matrix on sonication for 60 min. SEM analyses revealed homogenous dispersion of HNTs into the copolymer matrix and DSC analysis showed significant improvement in glass transition temperature (Tg)of composites upto 2 weight% of HNT loading and any further loading of HNT resulted in decrease in Tg.Zeta size and zeta potential analyses confirmed the particles were in nanoscale and possessed good stability respectively. This sonochemical route of preparation proves to be a promising way to accomplish nanocomposites synthesis with insitu polymerisation and to obtain better dispersion of particles in resulting composites. © 2017 Elsevier Ltd.Item A continuous flow microreactor as a practical tool for the synthesis of active pharmaceutical ingredients(Institution of Chemical Engineers, 2024) Bhaskar, K.; Rashed, M.; Bhat, K.; Lee, J.; Kim, K.-H.; Buruga, K.Continuous flow processing has become a key technology to maximize the capabilities of chemical syntheses. Numerous new tactics have been devised to synthesize various chemicals including active pharmaceutical ingredients (APIs) via a continuous flow system using microreactors. This review aims to illustrate the holistic system approach and diverse applications of continuous flow microreactors for the synthesis of APIs (with respect to type, design, and fabrication). This review also highlights the applicability of continuous flow microreactors in the synthesis of APIs in contrast to conventional batch-type methods along with a discussion of their merits and demerits. Overall, this review is expected to offer valuable insights into the utility of continuous flow microreactor technology for the upscaled production of commercially feasible APIs. © 2024 The Institution of Chemical EngineersItem Donor-acceptor polymers by solid state eutectic melt reaction for optoelectronic applications(Elsevier Ltd, 2017) Bathula, C.; Kang, Y.; Buruga, K.We report, the synthesis of novel donor–acceptor conjugated polymers based on benzo[1,2-b:4,5-b?]dithiophene (BDT) donor and 4,7-bis(5-bromothiophen-2-yl)benzo[c] [1,2,5]thiadiazole (DTBT) acceptor by solvent-free eutectic melt polymerization reaction (EMP). The most important fact is, reaction between solid reactants actually proceeds through bulk liquid phases, due to the formation of eutectics between the reactants and product(s) and any evolution of heat. In the present study, crystalline solid with moderately high vapor pressure and low melting temperature such as naphthalene is explored for forming eutectics in melt polymerization reaction. The HOMO and LUMO energy levels of the polymer P2 synthesized by EMP were found to be ?5.30 eV and ?3.77 eV. Optical bandgap was determined to be 1.53 eV. The solid-state reactions are important not only due to their high efficiency and selectivity but also for their more economical and eco-friendly procedures involved in the reaction. © 2017 Elsevier B.V.Item Optical, Electrochemical and Thermal Studies of Conjugated Polymers Synthesized by Eutectic Melt Reaction(Springer New York LLC barbara.b.bertram@gsk.com, 2017) Bathula, C.; Buruga, K.; Kang, Y.; Khazi, I.A.M.This paper reports on the synthesis of a novel donor–acceptor conjugated polymers, P1 and P2 by solvent free eutectic melt polymerization reaction. Triisopropylsilylethynyl(TIPS) substituted benzo[1,2-b:4,5-b?]dithiophene(BDT) is used as donor, thienithiophene(TT) and thienopyrroledione(TPD) are utilized as acceptors for demonstrating eutectic polymerization. The most important fact in the solvent-free reaction between solid reactants actually proceeds through bulk liquid phases. Such liquid phases are possible due to the formation of eutectics between the reactants and product(s) and any evolution of heat. Naphthalene is explored in this reaction for forming eutectics with the reactants, resulting in desired polymers. Thermal stability, optical and electrochemical properties of these polymers were determined. Optical band gaps of the polymers were found to be 1.58 and 1.65 eV. Electrochemical studies by cyclic voltametry experiment revealed HOMO and LUMO energy levels to be ?5.22, ?5.60 eV, and ?3.76, ?4.16 eV, respectively. The polymers were thermally stable up to 285–400 °C. Thermal, optical and electrochemical studies indicated these materials to be promising candidates in organic electronic applications. © 2017, Springer Science+Business Media New York.Item Microwave assisted synthesis of bithiophene based donor-acceptor-donor oligomers and their optoelectronic performances(Elsevier B.V., 2017) Bathula, C.; Buruga, K.; Lee, S.K.; Khazi, I.A.M.; Kang, Y.In this article we present the synthesis of two novel bithiophene based symmetrical ? conjugated oligomers with donor-acceptor-donor (D-A-D) structures by microwave assisted PdCl2(dppf) catalyzed Suzuki coupling reaction. These molecules contain electron rich bithiophene as a donor, dithienothiadiazole[3,4-c]pyridine and phthalic anhydride units as acceptors. The shorter reaction time, excellent yields and easy product isolation are the advantages of this method. The photophysical prerequisites for electronic application such as strong and broad optical absorption, thermal stability, and compatible energy levels were determined for synthesized oligomers. Optical band gap for the oligomers is found to be 1.72–1.90 eV. The results demonstrated the novel oligomers to be promising candidates in organic optoelectronic applications. © 2017 Elsevier B.V.Item Green synthesis of palladium nanoparticles using fenugreek tea and their catalytic applications in organic reactions(Elsevier B.V., 2017) Mallikarjuna, K.; Bathula, C.; Buruga, K.; Shrestha, N.K.; Noh, Y.-Y.; Kim, H.In this communication, we present the fenugreek tea aided green synthesis of Pd nanoparticles (PdNPs@FT). The synthesized PdNPs were characterized by UV–Visible spectroscopy, scanning electron microscopy (SEM), small area electron diffraction (SAED), fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). FT-IR manifested that polyol and amide groups present in fenugreek may have participated in the synthesis of palladium nanoparticles. PdNPs@FT exhibited high catalytic activity towards hydrogenation of 4-nitrophenol to 4-aminophenol. PdNPs@FT catalyzed Suzuki–Miyaura coupling reaction between bromobenzene and phenyl boronic acid gave desired biphenyl in excellent yield. © 2017 Elsevier B.V.Item Selenophene based benzodithiophene polymers as potential candidates for optoelectronic applications(Elsevier Ltd, 2018) Bathula, C.; Khadtare, S.; Buruga, K.; Kadam, A.; Shrestha, N.K.; Noh, Y.-Y.This work reports on the synthesis and characterization of two novel conjugated polymers consisting of selenophene substituted benzo[1,2-b:4,5-b?]dithiophene (SeBDT) donor, and dithienothiadiazole[3,4-c]pyridine(DTPyT)-P1 or thieno[3,4]pyrroledione(TPD)-P2 acceptors. The synthesized polymers are characterized for the significant photophysical prerequisites essential for organic electronics such as strong and broad optical absorption, thermal stability, and compatible highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels. The polymers are thermally stable up to 280–370 °C, and the optical band gaps for P1, P2 calculated from their film absorption edges are found to be 1.53 and 1.84 eV, respectively. In addition, the electrochemical studies of P1, P2 reveal the HOMO and LUMO energy levels of ?5.02,-5.04 eV, and ?3.49, ?3.20 eV, respectively, suggesting these materials to be potential candidates for the applications in organic electronics. © 2017 Elsevier LtdItem A facile synthesis of halloysite nanotubes based polymer nanocomposites for glass coating application(Elsevier Ltd, 2018) Buruga, K.; Kalathi, J.T.Halloysite-based polymethyl methacrylate (HNT-PMMA) and polystyrene (HNT-PS) nanocomposite coatings for glasses were synthesized by ultrasound-assisted solution blending method. The coatings were then dip-coated on four different types of soda-lime glass and the spectral, mechanical properties of the coated glasses were analyzed. The coated glass samples displayed a better scratch resistance and surface hydrophobicity, compared to uncoated samples, without any significant changes in their inherent spectral properties. The thermal and mechanical properties (Tg and tensile strength) of the nanocomposites were also enhanced compared to neat polymers. The improvement in thermal and scratch resistance of the coatings is ascribed to the inclusion of halloysite nanotubes (HNTs) in the polymer matrix. Hence, HNT-based PMMA/PS nanocomposite coatings can be effectively used for glasses in automotive and architectural applications. © 2017 Elsevier B.V.Item Polystyrene-halloysite nano tube membranes for water purification(Korean Society of Industrial Engineering Chemistry A-803 Twin Bldg 275-3 Yangjae-Dong Seocho-Kul Seoul 137-130, 2018) Buruga, K.; Kalathi, J.T.; Kim, K.-H.; Ok, Y.S.; Boukhvalov, B.Membrane technologies are a sustainable solution for treatment of water and wastewater. Here, the technical feasibility of polystyrene-halloysite nanotube (PS-HNT) membranes, fabricated by an ultrasound-assisted solution casting method, was explored for water purification. To this end, the effects of various solvents on the structure, morphology, thermal, and mechanical properties of PS-HNT membranes were investigated. Introduction of HNTs (5 wt%) into the polystyrene matrix demonstrated excellent thermal and mechanical properties along with good water flux, rejection of unwanted components, recovery, and regeneration cycles. These membranes were overall useful enough to purify real wastewater collected from pulp and paper mill. © 2017 The Korean Society of Industrial and Engineering Chemistry