Faculty Publications

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    Properties of ZnO:Bi thin films prepared by spray pyrolysis technique
    (Elsevier Ltd, 2013) Sadananda Kumar, N.; Bangera, K.V.; Anandan, C.; Shivakumar, G.K.
    Undoped and Bi doped zinc oxide thin films were deposited on glass substrate at 450 °C using spray pyrolysis technique. The X-ray diffraction studies shows that Bi doped ZnO films are polycrystalline hexagonal structure with a preferred orientation along (101) direction. Crystallites size of the films decreases with increasing doping concentration. Scanning electron microscope image shows change in the surface morphology. The composition of Zn, O and Bi elements in the undoped and Bi doped ZnO films were investigated by X-ray photoelectron spectroscopy. Bi doped ZnO thin films show a transparency nearly 75% in the visible region. The optical band gap of ZnO thin films reduces from 3.25 eV to 3.12 eV with an increase in Bi concentration from 0 to 5at.% respectively. Electrical conductivity of ZnO thin films increased from 0.156 to 6.02S/cm with increasing Bi dopant concentration from 0% to 5% respectively. © 2013 Elsevier B.V. All rights reserved.
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    Synthesis and characterization of Cu 1-x Zn x O composite thin films for sensor application
    (Elsevier Ltd, 2019) Bharath, S.P.; Bangera, K.V.; Shivakumar, G.K.
    Cu 1-x Zn x O composite thin films were prepared using industrially applicable spray pyrolysis technique for volatile organic compound (VOCs)sensor application. Sensing properties for different concentration of VOCs such as acetone, ethanol and methanol were studied at different sensor operating temperature. XRD studies on prepared thin films confirmed formation of CuO[sbnd]ZnO composite thin films with presence of different peaks for monoclinic structured CuO and hexagonal structure ZnO, it was also observed that formation of composite material improves sensing property towards VOCs. Granular morphology observed from SEM images were also contributed to enhance sensitivity of Cu 1-x Zn x O thin films. Hot probe experiment reveals that all the thin films were p-type in conductivity nature. Maximum electrical conductivity was achieved for Cu 0.75 Zn 0.25 O composite thin films, which also showed highest sensing property for VOCs. Cu 0.75 Zn 0.25 O thin films were selective towards ethanol and were capable of detecting 1 ppm of ethanol at operating temperature of 290 °C. © 2019