Conference Papers
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Item Synthesis, Characterization and Performance Studies of a New Metal-Free Organic Sensitizer for DSSC application(Elsevier Ltd, 2018) Naik, P.; Babu, D.D.; Su, R.; El-Shafei, A.; Vasudeva Adhikari, A.V.In this present work we report, design, synthesis and performance studies of a new metal-free organic dye (N, N'-PABA) based on N,N-dimethyl-4-vinyl aniline carrying 4-amino benzoic acid as acceptor, as sensitizers for sensitizing photoanode (TiO2). In the sensitizers, N,N-dimethylaniline ring acts as anelectron donorwhile para amino benzoic acid function as electron acceptor/anchoring units. It was synthesized via condensation reaction starting from simple 4-(N,N-dimethyl amino)benzaldehyde and their structures were confirmed using spectral techniques like FTIR, 1HNMR, 13CNMR, MS and elemental analysis. Further, it was subjected to electrochemical and optical characterization in order to evaluate their band gap and absorption/emission behavior. Further, DFT studies were performed using turbo mole V6.6 software package to evaluate their optimized geometry and FMO levels. Finally, DSSC devices were fabricated using this dye under simulated solar radiation AM1.5G and result revealed that it shows a conversion efficiency of 1%. © 2018 Elsevier Ltd.Item Performance Analysis of VMD to Decompose, Detrend and Denoise Power System Signals(Institute of Electrical and Electronics Engineers Inc., 2024) Rathod, N.S.; Shubhanga, K.N.Variational Mode Decomposition (VMD) has gained significant attention as an effective tool for signal processing, particularly in the fields of biomedical and speech processing. This paper explores the application of VMD to decompose complex power system signals which are non-stationary and nonlinear. Standard Empirical Mode Decomposition (EMD) and its variants often encounter challenges like mode mixing, boundary problems, and parameter dependency on noise levels, which may adversely affect the accuracy and reliability of the decomposition results. Since VMD effectively addresses these challenges by providing a more robust framework for decomposition, the resulting Intrinsic Mode Functions (IMFs) have been successfully used for mode estimation, detrending and denoising of power system signals. While denoising, to automate the process of identifying noisy IMFs reliably, Noise Identification Indices (NIIs) have been used. This study employs datasets from 3-machine, 9-bus power system and real-world ISO New England (ISO-NE) power system signals to demonstrate the efficacy and applicability of VMD in practical scenarios. These findings show up the potential application of VMD for analysing power system signals to advance signal processing techniques across various fields. © 2024 IEEE.
