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Item Effects of Solvents on Structure, Morphology and Thermal Stability of Polystyrene-HNTs Nanocomposites by Ultrasound Assisted Solution Casting Method(Elsevier Ltd, 2017) Buruga, K.; Kalathi, J.T.Polymer-clay nanocomposites are extensively investigated as they are economical in comparison with other nanofillers and drastically enhances various physical and engineering properties of polymers. Among various clays used for polymer-nanocomposites, Halloysite nanotubes (HNTs) have gained tremendous attention as they have unique structure and properties. In the present work we have successfully synthesised polystyrene-HNT nanocomposites by ultrasound assisted solution intercalation method. In this method solvent plays a very crucial role in enhancing the overall properties of resultant nanocomposites as arrangement of filler in the polymer matrix depends upon how well the solvent is able to disperse filler which inturn enhances polymer properties. Hence in this work solvents toluene, benzene, chloroform, dichoromethane (DCM), tetrahydrofuran (THF) and carbontetrachloride (CCl4) were used for synthesis of nanocomposites and effect of these solvent on structure, morphology and thermal stability of nanocomposites was investigated. As per the characterization analysis, toluene was found to be the best solvent for synthesis of nanocomposites with enhanced properties and use of ultrasound aided in uniform distribution of clay in polymer matrix. Increase in basal spacing on sonication was revealed by x-ray diffraction (XRD) analyses. Scanning electron microscopy (SEM) results revealed uniform dispersion of filler inside the matrix on using acoustic cavitation as it promotes proportionate distribution of filler into the polymer matrix. Fourier transform and infrared (FT-IR) results confirmed encapsulation of HNTs into polymer. Differential scanning calorimetry (DSC) reports illustrated increase in glass transition temperature (Tg) on incorporating HNTs. © 2017 Elsevier Ltd.Item Ultrasound assisted Synthesis of Poly (styrene-Co-methylmethacrylate)-HNT's Nanocomposites by In-Situ Emulsion Copolymerization and its Characterization(Elsevier Ltd, 2017) Buruga, K.; Kalathi, J.T.Poly (styrene-co-methylmethacrylate)-HNT nanocomposites have been successfully synthesized by ultrasound assisted emulsion copolymerization without modification of HNT's. The key parameters that affect the stability of the emulsion and hence the properties of the resulting nanocomposites are sonication time and clay loading. The effectsof these parameters on the process were investigated in this study. Thesynthesized nanocomposites were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform and infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) to investigatemorphology and thermal stability. The embodiment of the HNTs into the copolymer matrix was confirmed by FTIR, and XRD analyses positively delineated the complete exfoliation of HNTs into the copolymer matrix on sonication for 60 min. SEM analyses revealed homogenous dispersion of HNTs into the copolymer matrix and DSC analysis showed significant improvement in glass transition temperature (Tg)of composites upto 2 weight% of HNT loading and any further loading of HNT resulted in decrease in Tg.Zeta size and zeta potential analyses confirmed the particles were in nanoscale and possessed good stability respectively. This sonochemical route of preparation proves to be a promising way to accomplish nanocomposites synthesis with insitu polymerisation and to obtain better dispersion of particles in resulting composites. © 2017 Elsevier Ltd.