Gurugubelli, R.C.Balla, V.K.Krishna, P.Bontha, S.2026-02-032025Journal of Alloys and Compounds Communications, 2025, 7, , pp. -https://doi.org/10.1016/j.jacomc.2025.100094https://idr.nitk.ac.in/handle/123456789/20135This study investigates the microstructure and high-temperature oxidation behavior of Ti-48Al-2Cr-2Nb (Ti-4822) alloy at 950°C processed using Electron Beam Powder Bed Fusion (EB-PBF) with feature addition using Laser Directed Energy Deposition (LDED). The EB-PBF substrates in As-Built (AB) and EB-PBF + Hot Isostatic Pressing (HIP) conditions were used for feature addition using LDED. Oxidation studies revealed oxide scales mainly comprising alternating bands of TiO<inf>2</inf> and Al<inf>2</inf>O<inf>3</inf>. The oxidation rate constant of AB + LDED samples was 1.223 mg2 cm?4 h?1 and AB+ HIP + LDED samples was 0.874 mg2 cm?4 h?1. The oxide scale thickness on the LDED-feature side was higher than that observed on the AB, /AB + HIP side (of the AB+LDED, AB+HIP+LDED) samples suggesting their poor oxidation resistance. This can be attributed to the ultra-fine massive-like ?-TiAl microstructure in LDED compared to the nano-sized ?<inf>2</inf>/? lamellae seen in EB-PBF (AB/ AB+HIP). Delamination and spallation of the oxide scale were observed at the interface between the substrate and LDED feature owing to the difference in oxide-scale growth rates and the presence of ?<inf>2</inf>-Ti<inf>3</inf>Al. © 2025 Elsevier B.V.Aluminum alloysAluminum oxideChromium alloysElectron beamsInterfaces (materials)Niobium alloysOxidation resistanceScale (deposits)Ternary alloysThermooxidationTitanium alloysDirected energyElectron-beamEnergy depositionsHigh temperature oxidation BehaviorHot-isostatic pressingsIntermetallic alloys and compoundsLaser processMg 2Oxide scalePowder bedHot isostatic pressingTitanium dioxide