Praveen, L.L.Kailasam, K.Vardhan, R.V.Mandal, S.2026-02-052024Transactions of the Indian Ceramic Society, 2024, Vol.83, 3, p. 149-1650371750Xhttps://doi.org/10.1080/0371750X.2024.2353255https://idr.nitk.ac.in/handle/123456789/28259Ever since the discovery of ultra-hydrophobicity in lotus leaf, rigorous experiments have been carried out to replicate and understand its wetting nature using ceramic oxide based coatings on various substrates. Enormous applications dealing with ultra-hydrophobic nature have been explored which led to the discovery of intrinsic hydrophobic nature in rare-earth oxides. Several studies reported intrinsic hydrophobic behavior exhibited by rare earth oxides. Among all rare earth oxides, ytterbium-oxide (Yb<inf>2</inf>O<inf>3</inf>) has numerous applications in different fields because of its ability to phase change with pressure, abrasion resistance, high hardness and melting point. This review gives a basic understanding of wettability studies carried out on Yb<inf>2</inf>O<inf>3</inf> coating via the solution precursor plasma spray (SPPS) technique outlined in the literature and aims to understand the mechanism of post-processing treatments, revealing the conditions affecting the reversible wettability. Additionally, the mechanical durability tests performed on thermal-sprayed Yb<inf>2</inf>O<inf>3</inf> coatings are summarized along with the cost-effective approach of SPPS technique over other plasma spray techniques. The ultra-hydrophobicity in Yb<inf>2</inf>O<inf>3</inf> coatings and its existing applications propels the development of novel device-designing strategies in the field of bio-sensing and oil-water separation. © 2024 Indian Ceramic Society.Plasma spray coatingSuper-hydrophilicUltra-hydrophobicVacuum treatmentWater contact angleYtterbium oxide