Shet, A.S.Shetty K, V.2026-02-042024Canadian Journal of Chemical Engineering, 2024, 102, 7, pp. 2608-262784034https://doi.org/10.1002/cjce.25207https://idr.nitk.ac.in/handle/123456789/21046Volumetric oxygen mass transfer coefficient (k<inf>L</inf>a) is an important parameter in the design of various reactors and bioreactors. In the present work, the influence of α-Fe<inf>2</inf>O<inf>3</inf> nanofluid on the enhancement of k<inf>L</inf>a is studied in a pulsed plate column (PPC). An enhancement factor of greater than one showed that the nanofluid is favourable in enhancing the mass transfer rate. The effect of pulsing velocity on k<inf>L</inf>a is observed to fall under two regimes: the dispersion regime and emulsion regime. The k<inf>L</inf>a enhancement factor is found to be higher in TiO<inf>2</inf> nanofluid than in α-Fe<inf>2</inf>O<inf>3</inf> nanofluid, indicating that the type of nanofluid influences the enhancement factor. The order of magnitude analysis showed that localized convection triggered by the Brownian motion of nanoparticles is the phenomenon responsible for k<inf>L</inf>a enhancement. A dimensionless multiple regression analysis (MRA) model was developed to predict k<inf>L</inf>a in the nanoparticle loading range of 0.003–0.019 (v/v%), relating the Sherwood number with oscillating Reynolds number (1200 ≤ Re<inf>o</inf> ≤ 20,000), gas flow Reynolds number (0.135 ≤ Re<inf>g</inf> ≤0.370), Schmidt number (1300 ≤ Sc ≤2700), and Brownian Reynolds number (2.81 × 10−4 ≤ Re<inf>B</inf> ≤5 × 10−4). The pseudo-homogeneous model could accurately predict the enhancement until critical loading conditions. © 2024 Canadian Society for Chemical Engineering.Brownian movementEmulsificationFlow of gasesHematiteMass transferNanofluidicsOscillating flowOxygenRegression analysisTiO2 nanoparticlesTitanium dioxideEnhancement factorExperimental investigationsNanofluidsOrder-of-magnitude analysisOxygen mass transferPlate columnsPulsed plate columnPulsing velocityReynold numberΑ-fe2O3 nanofluidReynolds number