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dc.contributor.authorBhat, A.P.I.
dc.contributor.authorBhat, B.R.
dc.identifier.citationApplied Organometallic Chemistry, 2014, Vol.28, 6, pp.383-388en_US
dc.description.abstractA simple catalytic system of direct synthesis for the symmetrical biaryls using catalytic amounts of Co(II), Ni(II) and Cu(II) complexes has been developed. The reaction system involves in situ synthesis of Grignard reagents. The complexes, containing bidentate Schiff base and dmit (2-thioxo-1,3-dithiole- 4,5-dithiolate) ligands, were compatible with diverse functionalities and afford a high yield of biaryls in a single step, proving to be promising catalysts in homocoupling reactions. Atmospheric oxygen is used as an oxidant which renders a green, simple and economical catalytic route. Copyright 2014 John Wiley & Sons, Ltd.en_US
dc.titleSingle-step oxidative homocoupling of aryl Grignard reagents via Co(II), Ni(II) and Cu(II) Complexes under airen_US
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