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Title: Palladium complex in a room temperature ionic liquid: A convenient recyclable reagent for catalytic oxidation
Authors: Dileep, R.
Bhat, B.R.
Kumara, T.H.S.
Issue Date: 2014
Citation: Green Chemistry Letters and Reviews, 2014, Vol.7, 1, pp.32-36
Abstract: Palladium (Pd)-catalyzed carbonylation of alcohols proceeds in ionic liquid (IL) media (1-ethyl-3-methylimidazolium hexafluorophosphate). Carbonylation of primary/secondary alcohols to aldehydes/ketones was greatly accelerated by the use of a Pd-based catalyst in the presence of NaOCl as an oxidant. The catalyst was more easier to recycle in the IL [Emim]PF6 with an equal-proportioned CH2Cl2 than in the single CH2Cl2 or IL. 2014 The Author(s). Published by Taylor &amp
Appears in Collections:1. Journal Articles

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