Cyclic Oxidation and Hot-Corrosion Behavior of HVOF-Sprayed NiCrAl Coating on Industrial Boiler Tube Steels

Abstract

At high temperatures, coatings provide a protective scale development on surfaces to maintain long-term stability. In the current study, ASTM-SA210-Grade A1 (GrA1) and ASTM-SA213-T-11 (T11) boiler tube steels were coated with NiCrAl alloy with high-velocity oxy-fuel (HVOF) to prevent oxidation and hot corrosion. For hot corrosion and oxidation, 50 cycles at 900°C were taken into account. Additionally, tests of hot-corrosion behavior were conducted in an atmosphere containing molten salt (Na<inf>2</inf>SO<inf>4</inf>-60%V<inf>2</inf>O<inf>5</inf>), while tests of oxidation behavior were conducted in static air. The kinetics of oxidation were calculated using the thermogravimetric method. Using XRD, EPMA, and SEM/EDAX methods, the produced oxide scales were characterized. The oxidation rate of NiCrAl-coated steels was found to be lower than that of uncoated steels. The coated steels subjected to oxidation in air exhibit slow scale growth kinetics and oxides of α-Al<inf>2</inf>O<inf>3</inf> and Cr<inf>2</inf>O<inf>3</inf> on the outermost surface, while accelerated oxidation caused by the molten salt exhibits metastable Al<inf>2</inf>O<inf>3</inf>. Along the nickel-rich splat boundary, Cr and Al were formed a preferential oxidation, which prevents other oxygen from entering the coating via pores and voids, resulting in steady-state oxidation. © The Minerals, Metals & Materials Society 2024.