Synthesis and Characterization of PVDF/Graphene Nanocomposite Membrane for Water Treatment Applications

Abstract

Membrane technology advancement has gained momentous consideration around the globe because of their appealing highlights, such as effectiveness, low expenses, and effective solutions for longstanding issues in alchemical industries. This study expected to incorporate graphene nanoparticles into Polyvinylidene difluoride (PVDF) to form nanofiltration (NF) layers using DMF (Dimethyl formamide) as solvent via DIPS (diffusion induced phase separation) technique. PVDF polymer membrane performances with varied percent (1 – 6% wt.) of graphene concentrations are studied with Infrared spectral, water uptake, water contact angle, and ion rejection measurements. Scanning electron microscope (SEM) analysis showed that the pore size is often regulated by incorporating graphene nanoparticles (80-90 nm) as compared to PVDF membranes. The PVDF membranes exhibited a relative increase in the contact angle from PVDF to PVDF-G6%, i.e., 50.3° to 63.46 ± .3, thus, showing a relative increase in hydrophobicity. The higher percent of graphene (> 6% by wt.) results in nano-particle accumulation that showed the performances of PVDF/graphene rejection possessing relatively the same results. The results confirmed that the prepared membranes possess an excellent ability to treat wastewater. © 2022 Trans Tech Publications Ltd, Switzerland.