A catalytic process for the selective oxidation of alcohols by copper (II) complexes

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dc.contributor.authorRamakrishna, D.
dc.contributor.authorBadekai Ramachandra, B.
dc.date.accessioned2026-02-05T09:35:50Z
dc.date.issued2011
dc.description.abstractNovel copper (II)-N-(2-pyridyl)-N'-(5-R-salicylidene) hydrazine triphenylphosphine complexes have been synthesized and characterized. The complexes were effective in the catalytic oxidation of primary and secondary alcohols in presence of periodic acid (H<inf>5</inf>IO<inf>6</inf>) as oxidant. The oxidation reactions were carried out in acetonitrile. Electrochemical electron transfer study reveals CuII-CuI reduction in methanolic solutions. A mechanistic study of the above reactions has been proposed. © 2011 Elsevier B.V. All rights reserved.
dc.identifier.citationInorganic Chemistry Communications, 2011, 14, 5, pp. 690-693
dc.identifier.issn13877003
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2011.02.007
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/27258
dc.subjectCatalytic oxidation
dc.subjectCopper (II) complexes
dc.subjectPeriodic acid
dc.subjectSchiff base
dc.titleA catalytic process for the selective oxidation of alcohols by copper (II) complexes

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