Electrocatalysis by crown-type polyoxometalates multi-substituted by transition metal ions; Comparative study

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dc.contributor.authorNaseer, R.
dc.contributor.authorMal, S.S.
dc.contributor.authorKortz, U.
dc.contributor.authorArmstrong, G.
dc.contributor.authorLaffir, F.
dc.contributor.authorDickinson, C.
dc.contributor.authorVagin, M.
dc.contributor.authorMcCormac, T.
dc.date.accessioned2026-02-05T09:33:40Z
dc.date.issued2015
dc.description.abstractAbstract The difference in electrochemical properties of three crown-type polyoxometalates multi-substituted by Fe3+, Ni2+ or Co2+ ions and their precursor has been rationalized with respect to their electrocatalytic performances studied in solution and in the immobilized state within the layer-by-layer film formed with a positively charged pentaerythritol-based Ru(II)-metallodendrimer. The film assembly was monitored with electrochemical methods and characterized by surface analysis techniques. An influence of the terminal layer on the electrode reaction and on film porosity has been observed. The electrocatalytic performance of the compounds on nitrite reduction was assessed in solution and in the immobilized state. © 2015 Elsevier Ltd.
dc.identifier.citationElectrochimica Acta, 2015, 176, , pp. 1248-1255
dc.identifier.issn134686
dc.identifier.urihttps://doi.org/10.1016/j.electacta.2015.07.152
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/26243
dc.publisherElsevier Ltd
dc.subjectCatalysis
dc.subjectCobalt
dc.subjectElectrocatalysis
dc.subjectMetal ions
dc.subjectMetals
dc.subjectOxides
dc.subjectReduction
dc.subjectRuthenium
dc.subjectRuthenium alloys
dc.subjectSurface analysis
dc.subjectTransition metals
dc.subjectComparative studies
dc.subjectElectrocatalytic performance
dc.subjectELectrochemical methods
dc.subjectLayer by layer
dc.subjectLayer-by-layer films
dc.subjectNitrite reduction
dc.subjectPolyoxometalates
dc.subjectSurface analysis techniques
dc.subjectTransition metal compounds
dc.titleElectrocatalysis by crown-type polyoxometalates multi-substituted by transition metal ions; Comparative study

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