Characterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopy

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dc.contributor.authorDugar, S.
dc.contributor.authorIzarova, N.V.
dc.contributor.authorMal, S.S.
dc.contributor.authorFu, R.
dc.contributor.authorJoo, H.-C.
dc.contributor.authorLee, U.
dc.contributor.authorDalal, N.S.
dc.contributor.authorPope, M.T.
dc.contributor.authorJameson, G.B.
dc.contributor.authorKortz, U.
dc.date.accessioned2020-03-31T08:18:42Z
dc.date.available2020-03-31T08:18:42Z
dc.date.issued2016
dc.description.abstractWe report on the feasibility of applying high-resolution solid-state 195Pt MAS NMR spectroscopy for several PtIV-containing polyoxotungstates, and of 195Pt as well as 51V for a PtIV-containing polyoxovanadate. This method is particularly useful for polyanions which are unstable in solution and/or poorly soluble, as well as for systems exhibiting crystallographic disorder of Pt and W sites. We also report solution 195Pt and 183W NMR spectra of hexatungstoplatinate(iv) [H3PtW6O24]5- for the first time. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016.en_US
dc.identifier.citationNew Journal of Chemistry, 2016, Vol.40, 2, pp.923-927en_US
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/10194
dc.titleCharacterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopyen_US
dc.typeArticleen_US

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