Phase Transfer Catalyst Assisted One-Pot Synthesis of 5-(Chloromethyl)furfural from Biomass-Derived Carbohydrates in a Biphasic Batch Reactor
| dc.contributor.author | Onkarappa, S.B. | |
| dc.contributor.author | Dutta, Saikat | |
| dc.date.accessioned | 2020-03-31T08:41:48Z | |
| dc.date.available | 2020-03-31T08:41:48Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | 5-(Chloromethyl)furfural (CMF), a bio-renewable chemical building block, has been produced in good isolated yields from biomass-derived carbohydrates within a closed aqueous HCl-1,2-dichloroethane biphasic reactor in the presence of benzyltributylammonium chloride (BTBAC) as a phase transfer catalyst (PTC). The solvent-economic, one-pot strategy afforded CMF in 73% isolated yield (90 C, 3 h) from sucrose with a combined yield of 84% for CMF and levulinic acid. The process was optimized on temperature, duration, solvent, type, and loading of PTC. Use of BTBAC led to nearly 10% increase in yield of CMF for all substrates when compared to control reactions. 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | en_US |
| dc.identifier.citation | ChemistrySelect, 2019, Vol.4, 25, pp.7502-7506 | en_US |
| dc.identifier.uri | https://idr.nitk.ac.in/jspui/handle/123456789/12522 | |
| dc.title | Phase Transfer Catalyst Assisted One-Pot Synthesis of 5-(Chloromethyl)furfural from Biomass-Derived Carbohydrates in a Biphasic Batch Reactor | en_US |
| dc.type | Article | en_US |
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