NiWO4-ZnO-NRGO ternary nanocomposite as an efficient photocatalyst for degradation of methylene blue and reduction of 4-nitro phenol

Abstract

A novel NiWO<inf>4</inf>-ZnO-NRGO ternary nanocomposite has been efficiently synthesized by decorating nitrogen doped reduced graphene oxide (NRGO) with zinc oxide and nickel tungstate nanoparticles via a facile microwave irradiation technique and its capability to catalyze photodegradation of methylene blue (MB) dye in aqueous solution and reduction of 4-nitro phenol (4-NP) to 4-amino phenol (4-AP) using sodium borohydride was explored. The as-synthesized nanocomposite was characterized by X-ray diffraction (XRD), Raman spectroscopy, Brunauer-Emmett-Teller (BET) analysis, energy dispersive X-ray (EDX) analysis, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) spectroscopy and diffuse reflectance spectroscopy (DRS) techniques. The photocatalytic activity of the as-synthesized nanocomposite estimated through the photodegradation of MB under visible light irradiation showed 9 times improvement over pure NiWO<inf>4</inf>. It also showed excellent catalytic activity in reduction of 4-NP to 4-AP. The material also showed excellent stability and reusability. The entire study revealed that the novel NiWO<inf>4</inf>-ZnO-NRGO ternary nanocomposite can act as a promising bifunctional photocatalyst for environmental remediation and industrial application. © 2017 Elsevier Ltd