Production of 5-(formyloxymethyl)furfural from biomass-derived sugars using mixed acid catalysts and upgrading into value-added chemicals

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dc.contributor.authorDutta, S.
dc.date.accessioned2026-02-05T09:28:00Z
dc.date.issued2020
dc.description.abstractIn this work, 5-(formyloxymethyl)furfural (FMF) has been produced from biomass-derived hexose sugars within a biphasic reaction mixture consisting of aqueous formic acid (85%), a strong Brønsted acid catalyst, and 1,2-dichloroethane as an organic extractant. Using a combination of aqueous hydrobromic acid and formic acid, under optimized condition (80 °C, 8 h, 10 wt% substrate loading), 68% isolated yield of FMF was obtained from fructose. FMF has been demonstrated as a renewable chemical building block for the synthesis of renewable chemicals of commercial significance such as 5-methylfurfural, 2,5-diformylfuran, and 2,5-furandicarboxylic acid in good to excellent isolated yields. © 2020 Elsevier Ltd
dc.identifier.citationCarbohydrate Research, 2020, 497, , pp. -
dc.identifier.issn86215
dc.identifier.urihttps://doi.org/10.1016/j.carres.2020.108140
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/23639
dc.publisherElsevier Ltd
dc.subjectAldehydes
dc.subjectCatalysts
dc.subjectFormic acid
dc.subjectFurfural
dc.subjectSugars
dc.subject1 ,2-dichloroethanes
dc.subject2 ,5-furandicarboxylic acids
dc.subjectBiphasic reaction
dc.subjectOptimized conditions
dc.subjectOrganic extractant
dc.subjectRenewable chemicals
dc.subjectSubstrate loading
dc.subjectValue-added chemicals
dc.subjectIndicators (chemical)
dc.subject1,2 dichloroethane
dc.subject5 (formyloxymethyl)furfural
dc.subjectaldehyde derivative
dc.subjectBronsted acid
dc.subjectformic acid
dc.subjectfructose
dc.subjectfuran derivative
dc.subjecthexose
dc.subjecthydrobromic acid
dc.subjecthydroxyaldehyde
dc.subjectunclassified drug
dc.subject5-methyl-2-furfural
dc.subjectcarbohydrate
dc.subjectfurfural
dc.subjectwater
dc.subjectaqueous solution
dc.subjectArticle
dc.subjectbiomass
dc.subjectcatalyst
dc.subjecthydrolysis
dc.subjectpriority journal
dc.subjectreaction analysis
dc.subjectreaction optimization
dc.subjectrenewable resource
dc.subjectsolvent extraction
dc.subjectsynthesis
dc.subjectcatalysis
dc.subjectchemistry
dc.subjectconformation
dc.subjectmolecular model
dc.subjecttemperature
dc.subjectBiomass
dc.subjectCarbohydrate Conformation
dc.subjectCatalysis
dc.subjectFormates
dc.subjectFuraldehyde
dc.subjectModels, Molecular
dc.subjectTemperature
dc.subjectWater
dc.titleProduction of 5-(formyloxymethyl)furfural from biomass-derived sugars using mixed acid catalysts and upgrading into value-added chemicals

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