Oligopyrrole-Based Anion-Responsive ?-Electronic Systems That Exhibit Anion-Dependent Chiroptical Properties

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dc.contributor.authorLakshmi, V.
dc.contributor.authorHaketa, Y.
dc.contributor.authorSato, R.
dc.contributor.authorShigeta, Y.
dc.contributor.authorMaeda, H.
dc.date.accessioned2026-02-03T13:19:39Z
dc.date.issued2025
dc.description.abstractDipyrromethane dimers linked via a boron-bridged 1,3-propanedione moiety exhibited efficient anion-binding abilities. Trifluoromethyl and pentafluorophenyl moieties substituted at the meso positions of dipyrromethane induced chirality in the ?-electronic systems, whose conformations were controlled by anion binding. Anion complexes of the oligopyrrole-based chiral ?-electronic systems exhibited anion-dependent chiroptical properties, as seen in circular dichroism. © 2025 American Chemical Society.
dc.identifier.citationJournal of Organic Chemistry, 2025, 90, 26, pp. 8879-8885
dc.identifier.issn223263
dc.identifier.urihttps://doi.org/10.1021/acs.joc.5c00482
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/20186
dc.publisherAmerican Chemical Society
dc.subjectNegative ions
dc.subjectAnion complex
dc.subjectAnion-binding
dc.subjectBinding abilities
dc.subjectChiroptical properties
dc.subjectDipyrromethanes
dc.subjectElectronics system
dc.subjectInduced chirality
dc.subjectMeso positions
dc.subjectOligopyrroles
dc.subjectTrifluoromethyl
dc.subjectDichroism
dc.subjectanion
dc.subjectboron
dc.subjectdimer
dc.subjectdipyrromethane
dc.subjectmethane
dc.subjectpyrrole derivative
dc.subjectunclassified drug
dc.subjectArticle
dc.subjectchirality
dc.subjectcircular dichroism
dc.subjectcomplex formation
dc.subjectconformational transition
dc.subjectcontrolled study
dc.subjectoptical rotation
dc.subjectstereochemistry
dc.subjectsynthesis
dc.titleOligopyrrole-Based Anion-Responsive ?-Electronic Systems That Exhibit Anion-Dependent Chiroptical Properties

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