Nickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application

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dc.contributor.authorSankaraperumal, A.
dc.contributor.authorKarthikeyan, J.
dc.contributor.authorNityananda Shetty, A.N.
dc.contributor.authorLakshmisundaram, R.
dc.date.accessioned2026-02-05T09:34:53Z
dc.date.issued2013
dc.description.abstractNew complex of Ni(II) with p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4- methyl thiosemicarbazone (CEAB-4-MTSC) have been synthesized and characterized by elemental analysis, IR, electronic, 1H NMR spectroscopy. The crystal structure of the free ligand and complex has been determined by single crystal X-ray diffraction technique. In the complex, thiosemicarbazone ligand is coordinated to nickel through (1:2 complex) SNNS mode. The complex crystallizes in the triclinic with space group P1?. The complex has been tested for their antibacterial activity against various pathogenic bacteria. From this study, it was found out that the activity of complex reaches the effectiveness of the conventional bacteriocide Streptomycin compared to simple ligand. © 2012 Elsevier Ltd. All rights reserved.
dc.identifier.citationPolyhedron, 2013, 50, 1, pp. 264-269
dc.identifier.issn2775387
dc.identifier.urihttps://doi.org/10.1016/j.poly.2012.11.006
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/26828
dc.publisherElsevier Ltd
dc.subjectBacteria
dc.subjectCrystal structure
dc.subjectIndium compounds
dc.subjectNickel compounds
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectPhenols
dc.subjectSingle crystals
dc.subjectX ray diffraction
dc.subjectBiological applications
dc.subjectCrystals structures
dc.subjectFree ligands
dc.subjectH NMR spectroscopy
dc.subjectNi(II) complex
dc.subjectSNNS donor type complex
dc.subjectSquare planar complex
dc.subjectStructural characterization
dc.subjectSynthesised
dc.subjectThiosemicarbazones
dc.subjectLigands
dc.titleNickel(II) complex of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde-4-methyl thiosemicarbazone: Synthesis, structural characterization and biological application

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