BaCu(C<inf>2</inf>O<inf>4</inf>)<inf>2</inf> · 6 H<inf>2</inf>O is triclinic, P1, with a = 6.5405(9), b = 9.202(3), c= 10.939(1) Å, ? = 8546(2), ? = 79.22(1), ? = 80.45(2), V = 636.99(1) Å3, Z=2, D<inf>0</inf>, = 2.14, D<inf>c</inf> = 2.465 g · cm<inf>-3</inf>, R = 0.074. wR = 0.0746 for 2219 significant reflections |F<inf>0</inf>| = 6.0?F<inf>0</inf>. The barium has eleven coordinations and the coordination polyhedra is a capped antiprism. Six water oxygen atoms are coordinated whereas the other five are coming from the oxalate group. In the unit cell the molecules form a polymeric network. One lattice water molecule belongs to the coordinating water. The barium oxygen distances vary from 2.75 Å to 3.15 Å.
| dc.contributor.author | Kasthuri, V.B. | |
| dc.contributor.author | Rao, P.M. | |
| dc.contributor.author | Nethaji, M. | |
| dc.date.accessioned | 2026-02-05T11:00:34Z | |
| dc.date.issued | The crystal structure of hydrated barium copper oxalate | |
| dc.description.abstract | 1996 | |
| dc.identifier.citation | Crystal Research and Technology, 1996, 31, 3, pp. 287-294 | |
| dc.identifier.issn | 2321300 | |
| dc.identifier.uri | https://doi.org/10.1002/crat.2170310305 | |
| dc.identifier.uri | https://idr.nitk.ac.in/handle/123456789/28061 | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject | Composition | |
| dc.subject | Coordination reactions | |
| dc.subject | Crystal structure | |
| dc.subject | Molecular structure | |
| dc.subject | Oxygen | |
| dc.subject | Polymers | |
| dc.subject | X ray analysis | |
| dc.subject | X ray crystallography | |
| dc.subject | Hydrated barium copper oxalate | |
| dc.subject | X ray structure analysis | |
| dc.subject | Copper compounds | |
| dc.title | BaCu(C<inf>2</inf>O<inf>4</inf>)<inf>2</inf> · 6 H<inf>2</inf>O is triclinic, P1, with a = 6.5405(9), b = 9.202(3), c= 10.939(1) Å, ? = 8546(2), ? = 79.22(1), ? = 80.45(2), V = 636.99(1) Å3, Z=2, D<inf>0</inf>, = 2.14, D<inf>c</inf> = 2.465 g · cm<inf>-3</inf>, R = 0.074. wR = 0.0746 for 2219 significant reflections |F<inf>0</inf>| = 6.0?F<inf>0</inf>. The barium has eleven coordinations and the coordination polyhedra is a capped antiprism. Six water oxygen atoms are coordinated whereas the other five are coming from the oxalate group. In the unit cell the molecules form a polymeric network. One lattice water molecule belongs to the coordinating water. The barium oxygen distances vary from 2.75 Å to 3.15 Å. |