Fundamentals of multifunctional nanostructured coatings with recent updates

Abstract

This chapter provides a comprehensive overview of nanocoatings and their diverse applications. Nanocoatings are characterized by their nanoscale dimensions, typically ranging between 1 and 100nm and high-surface-to-volume ratios. They showcase remarkable properties such as protection against corrosion, wear, microbial action, and UV radiation and provide superior optical, electrical, and surface properties. Compared to the conventional coatings, the synthesis of nanocoating involves very little use of volatile organic compounds. Nanocoating is fabricated using synthesis techniques like chemical vapor deposition, electrodeposition, and Particle Vapor Deposition, etc. This chapter also discusses different types of nanocoatings reported in scientific literature, each with many applications. Ceramic-based nanocoatings, which are oxide-based ceramics like alumina (Al2O3), zirconia (ZrO2), and titania (TiO2), etc, are highlighted for their remarkable hardness and suitability for wear and corrosion-prone applications. Also, the applicability of polymer and metal matrix-based nanocoatings in packaging, automotive, thermal protection, and solar energy harnessing is emphasized; these nanocoatings find extensive potential in industries such as aerospace, transportation, and manufacturing, where superior mechanical properties and wear resistance are inevitable. To bring nanocoatings to a large scale in the future, it is essential to adapt cost-effective strategies and evaluate the adhesion between substrate and coating. Mathematic models may be developed to simulate various properties. Nature-inspired models could efficiently design nanocoatings, such as the lotus leaf effect. We also address some of the environmental challenges associated with nanocoating and emphasize the importance of considering factors like size, capping agent, and shape to mitigate such challenges. Nanocoatings offer great potential in enhancing material performance, protecting surfaces, and addressing industry challenges. © 2025 Elsevier Ltd. All rights are reserved.