Synthesis, characterization and nonlinear optical properties of 2-[(E)-2-(4-ethoxyphenyl)ethenyl]-1-methylquinolinium 4-substitutedbenzenesulfonate compounds

Abstract

In the present investigation, 2-[(E)-2-(4-ethoxyphenyl)ethenyl]-1-methylquinolinium 4-substituted benzenesulfonate (X = CH<inf>3</inf> (1), X = OCH<inf>3</inf> (2), X = Cl (3), X = Br (4)) have been synthesized and characterized by 1H NMR, UV-Vis and FT-IR spectroscopy methods. In addition compound 3 was also characterized by single crystal X-ray diffraction (XRD) and found that it crystallized out in the monoclinic space group P2<inf>1</inf> with cell parameters, a = 9.8072(9) Å, b = 6.4848(5) Å, c = 19.4405(16) Å, ? = 90°, ? = 103.421(5)°, ? = 90°, z = 2 and V = 1202.61(17) Å3. The nonlinear optical absorption of the samples has been studied at 532 nm using 5 ns laser pulses, employing the open-aperture z-scan technique. It is found that some of the samples are potential candidates for optical limiting applications. © 2009 Elsevier B.V. All rights reserved.