Palladium complex in a room temperature ionic liquid: A convenient recyclable reagent for catalytic oxidation
No Thumbnail Available
Date
2014
Authors
Dileep, R.
Bhat, B.R.
Kumara, T.H.S.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Palladium (Pd)-catalyzed carbonylation of alcohols proceeds in ionic liquid (IL) media (1-ethyl-3-methylimidazolium hexafluorophosphate). Carbonylation of primary/secondary alcohols to aldehydes/ketones was greatly accelerated by the use of a Pd-based catalyst in the presence of NaOCl as an oxidant. The catalyst was more easier to recycle in the IL [Emim]PF6 with an equal-proportioned CH2Cl2 than in the single CH2Cl2 or IL. 2014 The Author(s). Published by Taylor &
Description
Keywords
Citation
Green Chemistry Letters and Reviews, 2014, Vol.7, 1, pp.32-36