Visible light irradiated photocatalytic reduction of CO2 to hydrocarbons using hybrid polyaniline/ CuO nanocomposite in aqueous system

Abstract

The ever-increasing energy demand has resulted in an increase in CO<inf>2</inf> emissions and global warming. Photocatalytic reduction of CO<inf>2</inf> to methanol, which is considered to be the next generation alternate fuel is gaining interest to combat global warming and to move towards a methanol economy. The present work focuses on photocatalytic reduction of CO<inf>2</inf> using Polyaniline/CuO (PANI/CuO) nanocomposite to methanol, formic acid, and formaldehyde under visible light irradiation. CuO nanoparticles were synthesised using the aqueous extract of Tectona grandis (teak) leaves and further used in the synthesis of PANI/CuO nanocomposite with different CuO loading. PANI/CuO nanocomposite exhibited visible light activity in the reduction of CO<inf>2</inf> to form methanol, formic acid, and formaldehyde. Photocatalytic reduction of CO<inf>2</inf> with PANI/CuO nanocomposite containing 13.7% by weight of CuO resulted in a maximum yield of methanol. The band gap energy of the nanocomposite was found to be 2.28 eV, thus confirming its good visible light activity and the PANI-CuO heterojunction-based mechanism of photocatalysis is proposed. The synthesis of PANI-CuO photocatalyst uses CuO which is synthesised by an eco-friendly route with the utilisation of teak leaves, a timber industry waste and thus it can serve as a greener catalyst. © 2022 Indian Institute of Chemical Engineers.