Diesel soot oxidation over Mn–Pr–Ce oxide catalysts: structural changes and the impact of Mn doping

Abstract

The soot oxidation activity of manganese-doped ceria-praseodymium catalysts, synthesized via solution combustion synthesis, was evaluated. The analyses performed with XRD and Raman spectroscopy indicated that the Mn-doped CP catalysts displayed the typical fluorite structure of CeO<inf>2</inf>. The addition of Mn to CP led to a reduction in crystallite size from 14 nm to below 10 nm. The F<inf>2g</inf> Raman active mode of fluorite-structured Ce and the oxygen vacancies resulting from the addition of Mn and Pr (bands B 560 cm–1 to 580 cm–1) were consistently observed across all Mn-doped CP catalysts. 15 and 20 Mn-CP exhibited an additional secondary phase identified as Mn<inf>2</inf>O<inf>3</inf>. The analysis of BET surface area and BJH pore size revealed that the Mn-doped CP catalysts exhibited both micro and mesoporous characteristics. The H<inf>2</inf>-TPR and O<inf>2</inf>-TPD profiles indicated enhanced reducibility resulting from the incorporation of Mn and Pr into CeO<inf>2</inf>-doped catalysts. The improved T<inf>50</inf> (365 ± 1 1C) for the 5 Mn-CP catalytic system is primarily due to its increased specific surface area of 45 m2 g–1 and the presence of active surface adsorbed oxygen species identified in the XPS and O<inf>2</inf>-TPD studies. 5 Mn-CP exhibited the lowest activation energy value compared to all other Mn-doped catalysts. © 2025 The Author(s)