Characterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopy

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dc.contributor.authorDugar, S.
dc.contributor.authorIzarova, N.V.
dc.contributor.authorMal, S.S.
dc.contributor.authorFu, R.
dc.contributor.authorJoo, H.-C.
dc.contributor.authorLee, U.
dc.contributor.authorDalal, N.S.
dc.contributor.authorPope, M.T.
dc.contributor.authorJameson, G.B.
dc.contributor.authorKortz, U.
dc.date.accessioned2026-02-05T09:33:17Z
dc.date.issued2016
dc.description.abstractWe report on the feasibility of applying high-resolution solid-state 195Pt MAS NMR spectroscopy for several PtIV-containing polyoxotungstates, and of 195Pt as well as 51V for a PtIV-containing polyoxovanadate. This method is particularly useful for polyanions which are unstable in solution and/or poorly soluble, as well as for systems exhibiting crystallographic disorder of Pt and W sites. We also report solution 195Pt and 183W NMR spectra of hexatungstoplatinate(iv) [H<inf>3</inf>PtW<inf>6</inf>O<inf>24</inf>]5- for the first time. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016.
dc.identifier.citationNew Journal of Chemistry, 2016, 40, 2, pp. 923-927
dc.identifier.issn11440546
dc.identifier.urihttps://doi.org/10.1039/c5nj01242b
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/26065
dc.publisherRoyal Society of Chemistry
dc.subjectplatinum
dc.subjectpolyanion
dc.subjecttungsten
dc.subjectanisotropy
dc.subjectArticle
dc.subjectchemical analysis
dc.subjectcrystal structure
dc.subjectcrystallography
dc.subjectdegradation
dc.subjecthydrogen bond
dc.subjectnuclear magnetic resonance spectroscopy
dc.subjectpriority journal
dc.subjectproton transport
dc.subjectX ray diffraction
dc.titleCharacterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopy

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