4-Amino-3-(p-tolyl-oxymeth-yl)-1H-1,2,4-triazole-5(4H)-thione

Abstract

In the title triazole compound, C<inf>10</inf>H<inf>12</inf>N <inf>4</inf>OS, the triazole ring is essentially planar [maximum deviation = 0.009 (1) Å] and forms a dihedral angle of 5.78 (4)° with the benzene ring. In the crystal structure, mol-ecules are linked into dimers by centrosymmetric N - H?S inter-actions. These dimers are linked into two-mol-ecule-wide tapes by N - H?N and S?S [3.2634 (3) Å] inter-actions. In addition, they are further inter-connected by weak N - H?S inter-actions into sheets parallel to the ab plane. The crystal structure is further stabilized by weak inter-molecular C - H?? inter-actions. © 2009 Fun et al.