4-Amino-3-(o-tolyl-oxymeth-yl)-1H-1,2,4-triazole-5(4H)-thione

Abstract

The asymmetric unit of the title compound, C<inf>10</inf>H <inf>12</inf>N<inf>4</inf>OS, contains two independent mol-ecules, A and B, which differ significantly in the relative orientations of the benzene and triazole rings. The dihedral angle between the above two rings is 6.94 (5)° in mol-ecule A and 77.60 (5)° in mol-ecule B. In the crystal, mol-ecules are linked into a three-dimensional network by N - H?S, N - H?O, N - H?N and C - H?S hydrogen bonds and ?-? inter-actions between the benzene and triazole rings [centroid-centroid distance = 3.5311 (6) Å] are also present. © 2009 Fun et al.