Simultaneous separation of ternary mixture using modified dual compression middle vessel batch distillation column: Control and dynamic optimization

Abstract

Background: Multivessel batch distillation has been found to be an effective method for the separation of multi-component mixtures. In this article, an effort has been made to devise a fast middle vessel batch distillation column (MVBDC) for the ternary separation of an Ethanol/Propanol/Butanol mixture by the means of inducing vapor compression in the system. Methods: ASPEN PLUS V12 has been used to generate the initial steady-state flowsheet of the process for equipment sizing. In contrast, ASPEN Dynamics was used to evaluate the performance of the batch distillation with various control structures and to perform a dynamic optimization on the proposed batch distillation column. MATLAB was used to identify single-input single-output transfer functions for more effective PID controller tuning. Significant Findings: The proposed Middle vessel batch distillation was found to separate each component of the mixture to a purity of 99 mol% in 22 h (for the cascade control structures) and 21.73 h (for the temperature control structure). This was found to be significantly lesser than the batch time of a conventional batch distillation column (28.12 h), while the energy consumed by the proposed column was 3.4 MMkcal lesser than the energy consumed by the conventional column. Dynamic optimization further reduced the batch time by 14.4% while simultaneously reducing the energy consumed by 20.3%. © 2022 Taiwan Institute of Chemical Engineers