Growth of octahedral structured AgBiS2 single crystals and its insights on the high performance electrocatalytic hydrogen generation

Abstract

Given the enormous depletion of fossil fuels and growing environmental concerns, there is an immediate need to develop alternative and clean energy sources. Hydrogen (H<inf>2</inf>), recognized for its cleanliness and renewability, is poised to meet future energy requirements. Consequently, ongoing research is focused on the development of electro-active, durable, and cost-effective catalysts to replace expensive noble metal-based electrocatalysts. In this study, microscale AgBiS<inf>2</inf> chalcogenide derived from a single crystal is reported as promising electrocatalysts for the Hydrogen Evolution Reaction (HER) with a remarkably low overpotential. The physico-chemical characterization of the AgBiS<inf>2</inf> catalyst has been investigated using various analytical techniques. The synthesized AgBiS<inf>2</inf> catalyst exhibits excellent HER activity, manifesting a low overpotential of 86 mV at a current density of 10 mA cm−2 and a Tafel slope of 44 mV dec−1, along with superior stability even after 24 h in HER at a very high current density. The developed AgBiS<inf>2</inf> also showcased stable production when subjected to a two-electrode system. The enhanced alkaline HER activity of AgBiS<inf>2</inf> can be attributed to its phase purity, high crystallinity, and the presence of high active sites. The observed high electrochemical performance and stability position AgBiS<inf>2</inf> as a potential electrocatalyst for the hydrogen evolution reaction. This finding holds significant promise in the quest for efficient, durable, and economically viable catalysts to drive the shift towards clean and renewable energy sources. © 2024 Hydrogen Energy Publications LLC