Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands
dc.contributor.author | Rudresha, B.J. | |
dc.contributor.author | Ramachandra, Bhat, B. | |
dc.contributor.author | Sampath, Kumar, H.C. | |
dc.contributor.author | Shiva, Kumar, K.I. | |
dc.contributor.author | Safakath, K. | |
dc.contributor.author | Philip, R. | |
dc.date.accessioned | 2020-03-31T08:45:34Z | |
dc.date.available | 2020-03-31T08:45:34Z | |
dc.date.issued | 2011 | |
dc.description.abstract | This research article describes the synthesis, characterization and third-order nonlinear optical studies of copper(I) complexes [Cu(Br)(N,N?-C12H6N2O2) (PPh3)] and [Cu(I)(N,N?-C12H6N 2O2)(PPh3)] abbreviated as [CuBrLPPh 3] (1) and [CuILPPh3] (2) (L = 1,10-phenanthroline-5,6- dione). Nonlinear optical properties of the complexes are investigated at 532 nm using single beam Z-scan and degenerate four-wave mixing (DFWM) techniques employing nanosecond laser pulses. The complexes show optical limiting behaviour due to "effective" two-photon absorption. The values of the effective two-photon absorption (2PA) coefficients (?), third-order nonlinear susceptibilities (?(3)), and figures of merit (F), are calculated. 2010 Elsevier B.V. All rights reserved. | en_US |
dc.identifier.citation | Synthetic Metals, 2011, Vol.161, 43987, pp.535-539 | en_US |
dc.identifier.uri | https://idr.nitk.ac.in/handle/123456789/13306 | |
dc.title | Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands | en_US |
dc.type | Article | en_US |
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