Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands

dc.contributor.authorRudresha, B.J.
dc.contributor.authorRamachandra, Bhat, B.
dc.contributor.authorSampath, Kumar, H.C.
dc.contributor.authorShiva, Kumar, K.I.
dc.contributor.authorSafakath, K.
dc.contributor.authorPhilip, R.
dc.date.accessioned2020-03-31T08:45:34Z
dc.date.available2020-03-31T08:45:34Z
dc.date.issued2011
dc.description.abstractThis research article describes the synthesis, characterization and third-order nonlinear optical studies of copper(I) complexes [Cu(Br)(N,N?-C12H6N2O2) (PPh3)] and [Cu(I)(N,N?-C12H6N 2O2)(PPh3)] abbreviated as [CuBrLPPh 3] (1) and [CuILPPh3] (2) (L = 1,10-phenanthroline-5,6- dione). Nonlinear optical properties of the complexes are investigated at 532 nm using single beam Z-scan and degenerate four-wave mixing (DFWM) techniques employing nanosecond laser pulses. The complexes show optical limiting behaviour due to "effective" two-photon absorption. The values of the effective two-photon absorption (2PA) coefficients (?), third-order nonlinear susceptibilities (?(3)), and figures of merit (F), are calculated. 2010 Elsevier B.V. All rights reserved.en_US
dc.identifier.citationSynthetic Metals, 2011, Vol.161, 43987, pp.535-539en_US
dc.identifier.urihttps://idr.nitk.ac.in/handle/123456789/13306
dc.titleSynthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligandsen_US
dc.typeArticleen_US

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
13306.pdf
Size:
373.56 KB
Format:
Adobe Portable Document Format