Faculty Publications
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Item Design of haul road lighting system. Part II: Design based on optimal cost considerations(2006) Karmakar, N.C.; Mangalpady, M.; Rao, Y.V.; Yaragatti, U.R.The proper selection of lighting installations is very important for the provision of cost-effective lighting systems without compromising light quality. In this study a computer program was developed to evolve a cost-effective lighting system for haul roads in surface mines. This program is beneficial in assessing the viability of various lighting installations in order to achieve cost-effective solutions. Using the program, illumination design was studied for an 800 m long stretch of haul road. Nine different types of light sources were considered at mounting heights of 12 m and 16 m. The study shows that at a 12 m mounting height, 100 W high-pressure sodium vapour (HPSV) lamps offer the most cost-effective design, followed by 250 W HPSV lamps. In the case of 16 m pole heights the annual lighting cost is minimum for 150 W HPSV lamps, followed by 250 W HPSV lamps. This work also shows that optimum design based on energy consumption need not be the same as design based on optimum cost considerations as cost parameters may vary widely with location.Item Design of haul road lighting system. Part I: Design based on optimal energy considerations(2006) Karmakar, N.C.; Mangalpady, M.; Rao, Y.V.; Yaragatti, U.R.Electrical energy consumption is a major cost component of haul road lighting. Haul road lighting depends on many parameters such as type and wattage of sources, mounting height and tilt angle of light fixtures. In this study a computer model has been developed for optimum energy consumption of any haul road lighting system. Using the program, illumination design was studied for a stretch of 800m long haul road. Nine different types of light sources were considered for mounting heights of 12 and 16m. High-pressure sodium vapour (HPSV) lamps of 100W proved to be energy efficient at a 12m height whereas at 16m height, energy consumption was minimum for 150 W HPSV lamps. Thus the developed computer program proved to be successful in evaluating the performance of lighting designs from the point of view of energy consumption.Item New luminescent 2-methoxy-6-(4-methoxy-phenyl)-4-p-tolyl-nicotinonitrile: Synthesis, crystal structure, DFT and photophysical studies(2014) Ahipa, T.N.; Kamath, P.R.; Kumar, V.; Vasudeva Adhikari, A.V.In the current communication, we report the synthesis, spectroscopic, crystal structure, DFT and photophysical studies of a new nicotinonitrile derivative, viz. 2-methoxy-6-(4-methoxy-phenyl)-4-p-tolyl-nicotinonitrile (2) as a potential blue light emitting material. The compound 2 was synthesized in good yield via a simple route. The acquired spectral and elemental analysis data were in consistent with the chemical structure of 2. The single crystal study further confirms its three dimensional structure, molecular shape, and nature of short contacts. Its DFT calculations reveal that compound 2 possesses a non-planar structure and its theoretical IR spectral data are found to be in accordance with experimental values. In addition, its UV-visible and fluorescence spectral measurements prove that the compound exhibits good absorption and fluorescence properties. Also, it shows positive solvatochromic effect when the solvent polarity was varied from non-polar to polar. © 2014 Elsevier B.V. All rights reserved.Item Use of light emitting diodes (LEDs) for enhanced lipid production in micro-algae based biofuels(Elsevier B.V., 2017) Severes, A.; Hegde, S.; D'Souza, L.; Hegde, S.Microalgae are an alternative source for renewable energy to overcome the energy crises caused by exhaustion of fuel reserves. Algal biofuel technology demands a cost effective strategy for net profitable productivity. Inconsistent illumination intensities hinder microalgal growth. The light-utilizing efficiency of the cells is critical. Light scarcity leads to low production and high intensities cause photo-inhibition. We report effective usage of LEDs of different band wavelengths on the growth of microalgae in a closed, controlled environment to generate biomass and lipid yields. Among the different intensity and wavelengths tested. The light intensities of 500 lx of blue-red combination gave maximum biomass in terms of cell density. LED of red light 220 lx wavelength doubled the lipid dry weight from 30% (w/w) in white light to 60% (w/w). Thin layer lipid chromatogram demonstrated a dense and prominent spot of triacylglycerols in the red light, 220 lx grown cultures. The FTIR profile indicates that different wavelength exposure did not alter the functional groups or change the chemical composition of the extracted lipids ensuring the quality of the product. We reiterate the fact that combination of red and blue LEDs is favoured over white light illumination for generation of biomass. In addition, we report an exciting finding of exposure to LEDs of red wavelength post-biomass generation lead to enhanced lipid production. This simple process doubled the lipid content harvested in 20 days culture period. © 2017 Elsevier B.V.Item Visible light-induced photocatalytic degradation of Reactive Blue-19 over highly efficient polyaniline-TiO2 nanocomposite: a comparative study with solar and UV photocatalysis(Springer Verlag service@springer.de, 2018) Kalikeri, S.; Kamath, N.; Gadgil, D.J.; Shetty K, V.Polyaniline-TiO2 (PANI-TiO2) nanocomposite was prepared by in situ polymerisation method. X-ray diffractogram (XRD) showed the formation of PANI-TiO2 nanocomposite with the average crystallite size of 46 nm containing anatase TiO2. The PANI-TiO2 nanocomposite consisted of short-chained fibrous structure of PANI with spherical TiO2 nanoparticles dispersed at the tips and edge of the fibres. The average hydrodynamic diameter of the nanocomposite was 99.5 nm. The band gap energy was 2.1 eV which showed its ability to absorb light in the visible range. The nanocomposite exhibited better visible light-mediated photocatalytic activity than TiO2 (Degussa P25) in terms of degradation of Reactive Blue (RB-19) dye. The photocatalysis was favoured under initial acidic pH, and complete degradation of 50 mg/L dye could be achieved at optimum catalyst loading of 1 g/L. The kinetics of degradation followed the Langmuir-Hinshelhood model. PANI-TiO2 nanocomposite showed almost similar photocatalytic activity under UV and visible light as well as in the solar light which comprises of radiation in both UV and visible light range. Chemical oxygen demand removal of 86% could also be achieved under visible light, confirming that simultaneous mineralization of the dye occurred during photocatalysis. PANI-TiO2 nanocomposites are promising photocatalysts for the treatment of industrial wastewater containing RB-19 dye. © 2017, Springer-Verlag GmbH Germany, part of Springer Nature.Item Solar light-driven photocatalysis using mixed-phase bismuth ferrite (BiFeO3/Bi25FeO40) nanoparticles for remediation of dye-contaminated water: kinetics and comparison with artificial UV and visible light-mediated photocatalysis(Springer Verlag service@springer.de, 2018) Kalikeri, S.; Shetty K, V.Mixed-phase bismuth ferrite (BFO) nanoparticles were prepared by co-precipitation method using potassium hydroxide as the precipitant. X-ray diffractogram (XRD) of the particles showed the formation of mixed-phase BFO nanoparticles containing BiFeO3/Bi25FeO40 phases with the crystallite size of 70 nm. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed the formation of quasi-spherical particles. The BFO nanoparticles were uniform sized with narrow size range and with the average hydrodynamic diameter of 76 nm. The band gap energy of 2.2 eV showed its ability to absorb light even in the visible range. Water contaminated with Acid Yellow (AY-17) and Reactive Blue (RB-19) dye was treated by photocatalysis under UV, visible, and solar light irradiation using the BFO nanoparticles. The BFO nanoparticles showed maximum photocatalytical activity under solar light as compared to UV and visible irradiations, and photocatalysis was favored under acidic pH. Complete degradation of AY-17 dyes and around 95% degradation of RB-19 could be achieved under solar light at pH 5. The kinetics of degradation followed the Langmuir–Hinshelhood kinetic model showing that the heterogeneous photocatalysis is adsorption controlled. The findings of this work prove the synthesized BFO nanoparticles as promising photocatalysts for the treatment of dye-contaminated industrial wastewater. © 2018, Springer-Verlag GmbH Germany, part of Springer Nature.Item Floating bed reactor for visible light induced photocatalytic degradation of Acid Yellow 17 using polyaniline-TiO2 nanocomposites immobilized on polystyrene cubes(Springer, 2020) Nair, V.R.; Shetty K, V.In the present study, PANI-TiO2 nanocomposites have been used in suspended and immobilized form for photocatalytic degradation of Acid Yellow 17 (AY-17) dye under visible light. PANI-TiO2 nanocomposites were immobilized in polystyrene cubes to form PANI-TiO2 @ polystyrene cubes. The nanocomposites were found to be visible light active both in suspended and immobilized form. PANI-TiO2 nanocomposite with 13% TiO2 loading was found to be the optimum in terms of maximum degradation of AY-17. The efficiency of floating bed photoreactor (FBR) operated in liquid recycle mode using PANI-TiO2 @ polystyrene cubes was studied. In this reactor, around 89% degradation of 1 L of AY-17 with an initial concentration of 10 mg/L could be achieved with 2.83 g/L per pass of immobilized catalyst. The FBR operated with PANI-TiO2 @ polystyrene cubes has exhibited good performance as a photocatalytic reactor and may be recommended over other conventional photo reactors for treatment of wastewater contaminated with synthetic dyes. The kinetics of degradation of AY-17 by photocatalysis under visible light with suspended PANI-TiO2 and PANI-TiO2 @ polystyrene cubes followed first-order kinetics. The values of apparent kinetic parameter for degradation by immobilized photocatalysts are lower than the corresponding kinetic parameter for suspended photocatalysts. It confirms the existence of diffusional limitations in photocatalysis by PANI-TiO2 @polystyrene cubes. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.Item Enhanced photocatalytic efficiency of layered CdS/CdSe heterostructures: Insights from first principles electronic structure calculations(Institute of Physics Publishing helen.craven@iop.org, 2020) Shenoy, S.; Tarafder, K.Metal sulfides are emerging as an important class of materials for photocatalytic applications, because of their high photo responsive nature in the wide visible light range. In this class of materials, CdS with a direct band gap of 2.4 eV, has gained special attention due to the relative position of its conduction band minimum, which is very close to the energies of the reduced protons. However, the photogenerated holes in the valence band of CdS are prone to oxidation and destroy its structure during photocatalysis. Thus constructing a CdS based heterostructure would be an effective strategy for improving the photocatalytic performance. In this work we have done a detail theoretical investigation based on hybrid density functional theory calculation to get insight into the energy band structure, mobility and charge transfer across the CdS/CdSe heterojunction. The results indicate that CdS/CdSe forms type-II heterostructure that has several advantages in improving the photocatalytic efficiency under visible light irradiation. © 2020 IOP Publishing Ltd.Item Photomechanical actuation of polydimethylsiloxane/carbon black nanocomposite(Institution of Engineering and Technology jbristow@theiet.org, 2020) Hiremath, S.; Kulkarni, S.M.Materials such as carbon black (CB), carbon nanotube, graphene, etc. have been found to deform on exposure to the light source. Introducing these materials into polymers could convert them to photo-responsive composites. This is demonstrated by the experiment in which polydimethylsiloxane (PDMS) polymer containing CB nanofiller composites is prepared, and its photomechanical actuation from exposure to IR light source is recorded using a laser displacement sensor. The particle size analysis reveals the size of the CB, which is verified by the dynamic light scattering method. The UV-vis-IR spectrophotometer study shows that an increase in the light absorbance capacity of nanocomposites compared to the plain polymer. The PDMS/CB nanocomposite beam exhibited a significant deformation compared to plain PDMS. Deformation of the order of 10-11 mm is observed for a given IR source. The deformation found to have good repeatability but with some thermal hysteresis in cyclic actuation and de-actuation. © 2020 Institution of Engineering and Technology. All rights reserved.Item Resonance levels in GeTe thermoelectrics: Zinc as a new multifaceted dopant(Royal Society of Chemistry, 2020) Bhat, D.K.; Shenoy, U.S.Recently doping has been widely used in enhancing the thermoelectric properties of lead-free GeTe. But much of the work has been concentrated on carrier concentration tuning or phonon scattering. Until now, only indium has been reported to be the best resonant dopant in cubic GeTe. Herein, for the first time we introduce zinc as a resonant dopant to the cubic GeTe family. We show that zinc in GeTe not only introduces resonance states but also increases the band gap and raises the heavy hole valence band above the light hole valence band leading to enhanced Seebeck values. This multifunctional dopant incorporation in GeTe leads to enhanced transport properties as predicted by Boltzmann transport properties calculations based on first principles density functional theory electronic structure calculations. This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.