Faculty Publications
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Item Industrial wastewater treatment using bioelectrochemical systems and the potential for energy recovery(Elsevier, 2022) Kumar, M.; Sinharoy, A.; Uddandarao, U.; Singh, K.S.Energy crises and environmental pollution are predicted to be among the major global problems in the 21st century. Over past centuries, massive increase in human population and industrial development has resulted in energy crises, global climate change, environmental degradation, and associated health problems. Therefore, the greatest challenge for researchers is to find alternative sources of energy and means to prevent and reduce environmental degradation, due to which, biotechnological products and processes using renewable resources have gained attention during recent times. In this context, bioelectrochemical systems (BESs) have the potential to provide solutions for simultaneous wastewater treatment and resource recovery in the form of bioenergy and other value added products. Both types of BES, viz., microbial fuel cell and microbial electrolysis cell, are capable of treating wastewater generated from a variety of industrial sources and producing energy (electricity, hydrogen, methane) as well as recovering other resources such as biomass, heavy metals, nutrients (nitrogen, phosphate), and minerals. This chapter is focused on providing a detailed overview of different BESs, more particularly, MFCs used for treatment of industrial wastewater, and the potential for bioenergy production. © 2023 Elsevier Inc. All rights reserved.Item Continuous Production of Clean Hydrogen from Wastewater by Microbial Usage(wiley, 2023) Satishkumar, P.; Isloor, A.M.; Farnood, R.Biohydrogen production from wastewater is a prominent way to address escalating global energy demand and alarming environmental pollution. The need for renewable, sustainable, economic, and environment-friendly pathways for energy generation is fulfilled by biohydrogen evolution. Wastewaters contain a vast array of organic contents, as well as microbes and are a suitable source for bioreactors. Treatment of wastewaters with hydrogen-generating bacteria significantly aids its purification process by reducing chemical oxygen demand with simultaneous hydrogen generation. Among the various methods that are available for hydrogen production from microbes, photo fermentation, dark fermentation, and microbial electrolysis cells are discussed thoroughly. Continuous hydrogen generation systems are most suitable for large scale commercial production. Uniform product quality is obtained in the case of continuous systems. Microbial electrolysis cells have been found to yield exceptionally good hydrogen purity. A variety of factors that affect hydrogen evolution in all the techniques are reviewed in detail. © 2023 Scrivener Publishing LLC. All rights reserved.Item Performance of pulsed plate bioreactor for biodegradation of phenol(2007) Shetty K, K.V.; Kalifathulla, I.; Srinikethan, G.Biodegradation of phenol was carried out using Nocardia hydrocarbonoxydans immobilised on glass beads, in a pulsed plate bioreactor. The effect of operating parameters like frequency of pulsation and amplitude of pulsation on the performance of pulsed plate bioreactor for biodegradation of phenol in a synthetic wastewater containing 500 ppm phenol was studied. Axial concentration profile measurements revealed that the pulsed plate bioreactor shows continuous stirred tank behaviour. As the amplitude was increased, percentage degradation increased, reaching 100% at amplitude of 4.7 cm and higher. Introduction of pulsation is found to increase the percentage degradation. Percentage degradation has increased with increase in frequency and 100% degradation was achieved at 0.5 s-1 and above. Biofilms developed in a non-pulsed bioreactor were thicker than those in the pulsed plate bioreactor. But biofilm thickness remained almost constant with increasing frequency. Biofilm density was found to be influenced by pulsation. The time required to reach steady state was more for pulsed reactor than the non-pulsed reactor and this start-up time had increased with increase in frequency of pulsation. The performance studies reveal that the pulsed plate bioreactor with immobilized cells has the potential to be an efficient bioreactor for wastewater treatment. © 2006 Elsevier B.V. All rights reserved.Item ANN & regresssion analysis based predictions of BOD5 & COD for refinery wastewater(2007) Rene, E.R.; Saidutta, M.B.Industrial wastewater quality is indicated by several physico-chemical and biological parameters. If a Suitable correlation is established between them, some difficult and not instantaneously available parameters can be easily predicted. Such correlations are traditionally achieved by regression analysis. However, non-linear fluctuations are not easily represented by these correlations. Models based on artificial neural networks (ANNs) are fast emerging as an alternative tool to predict and forecast water quality parameters based on a well-defined set of training data that are easily available. The present study reports the correlations for BOD5 and COD with TOC for a refinery wastewater. Additionally, 12 ANN based models were developed to forecast the BOD5 and COD by considering other water quality indices as the input data. The results from this study indicate that ANNs are simple and reliable, under adequately trained conditions.Item Biological phenol removal using immobilized cells in a pulsed plate bioreactor: Effect of dilution rate and influent phenol concentration(2007) Shetty K, K.V.; Ramanjaneyulu, R.; Srinikethan, G.The continuous aerobic biodegradation of phenol in synthetic wastewater was carried out using Nocardia hydrocarbonoxydans immobilized over glass beads packed between the plates in a pulsed plate bioreactor at a frequency of pulsation of 0.5 s-1 and amplitude of 4.7 cm. The influence of dilution rate and influent phenol concentration on start up and steady state performance of the bioreactor was studied. The time taken to reach steady state has increased with increase in dilution rate and influent phenol concentration. It was found that, as the dilution rate is increased, the percentage degradation has decreased. Steady state percentage degradation was also reduced with increased influent phenol concentration. Almost 100% degradation of 300 and 500 ppm influent phenol could be achieved at a dilution rate of 0.4094 h-1 and more than 99% degradation could be achieved with higher dilution rates. At a higher dilution rate of 1.0235 h-1 and at concentrations of 800 and 900 ppm the percentage degradation has reduced to around 94% and 93%, respectively. The attached biomass dry weight, biofilm thickness and biofilm density at steady state were influenced by influent phenol concentration and dilution rate. © 2007 Elsevier B.V. All rights reserved.Item Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind wood activated with sulphuric acid(2008) Singh, C.K.; Sahu, J.N.; Mahalik, K.K.; Mohanty, C.R.; Mohan, B.R.; Meikap, B.C.The low-cost activated carbon were prepared from Tamarind wood material by chemical activation with sulphuric acid for the adsorption of Pb(II) from dilute aqueous solution. The activated carbon developed shows substantial capacity to adsorb Pb(II) from dilute aqueous solutions. The parameters studied include physical and chemical properties of adsorbent, pH, adsorbent dose, contact time and initial concentrations. The kinetic data were best fitted to the Lagergren pseudo-first-order and pseudo-second order models. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models. The maximum removal of lead(II) was obtained 97.95% (experimental) and 134.22 mg/g (from Langmuir isotherm model) at initial concentration 40 mg/l, adsorbent dose 3 g/l and pH 6.5. This high uptake showed Tamarind wood activated carbon as among the best adsorbents for Pb(II). © 2007 Elsevier B.V. All rights reserved.Item Bed depth service time model for the biosorption of reactive red dye using the Portunus sanguinolentus shell(2010) JagadeeshBabu, P.E.; Krishnan, R.; Singh, M.Biosorption is an efficient and regenerative technique that often uses low-cost adsorbent materials, particularly for the treatment of wastewaters containing dyes and heavy metals. This study investigates the ability of crab shell (Portunus sanguinolentus) to remove reactive red dye in a packed bed up-flow column (internal diameter 2 cm; height 35 cm). Crab shell has high surface area (after proper size reduction) and high regenerative capacity. The experiments were performed with different bed heights (20 and 30 cm) and using different flow rates (12 and 17 ml/min) in order to obtain experimental breakthrough curves. The bed depth service time (BDST) model was used to analyze the experimental data and the model parameters were evaluated. The column regeneration studies were carried out for five different sorption-desorption cycles. The elutant used for the regeneration of the sorbent was 0.01 M EDTA (disodium) solution at pH 9.8 adjusted using NH4OH. This solution was found to have the best bed regeneration capacity and could be reused for several sorption-desorption cycles. The elution efficiency was greater than 99.1% in all seven cycles. Continuous use of the crab shell leads to a decrease in the adsorptive performance, as observed by the breakthrough curves becoming flatter and also because of a broader mass transfer zone. © 2009 Curtin University of Technology and John Wiley & Sons, Ltd.Item Characterization and proinflammatory response of airborne biological particles from wastewater treatment plants(2011) Gangamma, S.; Patil, R.S.; Mukherji, S.Wastewater contains a variety of microorganisms, and unit operations in the plants could release these biological components into the air environment. These airborne biological particles could have adverse health effects on plant workers and the downwind population. This study provides a first report on the concentration and characterization of the airborne biological particles in six wastewater treatment plants in Mumbai, India. The study indicates that 49% and 27% of the samples exceed, respectively, the exposure limit for airborne endotoxin and bacteria in occupational settings. Endotoxin was identified as the single most important component of the particulate matter responsible for induction of proinflammatory indicator (tumor necrosis factor-?) in in vitro assay. Identification of several clinically important bacterial species in the samples suggests that the workers at the treatment plant are exposed to opportunistic and infectious bacteria. Principal component analysis was used to identify the groups among the bacterial species which serves as the signature for transport study. Analysis also shows that the component related to spore-forming bacteria is present in all samples. © 2011 American Chemical Society.Item Inhibitory and stimulating effect of single and multi-metal ions on hexavalent chromium reduction by Acinetobacter sp. Cr-B2(Kluwer Academic Publishers, 2014) Hora, A.; Shetty K, V.Potential application of chromium reducing bacteria for industrial scale wastewater treatment demands that effect of presence of other metal ions on rate of Cr(VI) reduction be investigated, as industrial wastewaters contain many toxic metal ions. In the current study, the effect of different heavy metal ions (nickel, zinc, cadmium, copper, lead, iron) on chromium reduction by a novel strain of Acinetobacter sp. Cr-B2 that shows high tolerance up to 1,100 mg/L and high Cr(VI) reducing capacity was investigated. The alteration in Cr(VI) reduction capacity of Cr-B2 was studied both in presence of individual metal ions and in the presence of multi-metal ions at different concentrations. The study showed that the Cr(VI) reduction rates decreased in presence of Ni2+, Zn2+ and Cd2+ when present individually. Pb2+ at lower concentration did not show significant effect while Cu2+ and Fe3+ stimulated the rate of Cr(VI) reduction. In the studies on multi-metal ions, it was observed that in presence of Cu2+ and Fe3+, the inhibiting effect of Ni2+, Zn2+, Cd2+ and Pb2+ on Cr(VI) reduction was reduced. Each of these metals affect the overall rate of Cr(VI) reduction by Cr-B2. This work highlights the need to consider the presence of other heavy metal ions in wastewater when assessing the bioreduction of Cr(VI) and while designing the bioreactors for the purpose, as rate of reduction is altered by their presence. © 2014, Springer Science+Business Media Dordrecht.Item Reuse of incinerated textile mill sludge as adsorbent for dye removal(Springer Verlag service@springer.de, 2015) Jahagirdar, S.S.; Shrihari, S.; Manu, B.Textile industry is one of the largest and oldest industries in India. Textile mill uses large quantities of water for its variety of wet processes, which in turn generates a large amount of waste water. Effluent treatment plants treat textile mill waste water using a variety of chemical coagulants thus producing greater amount sludge. Disposal of sludge is a challenging problem. In this study Textile mill sludge was incinerated at 800°C and used as an adsorbent without any activation. SEM images confirmed that, sludge ash was porous in nature and could be used as an adsorbent. For the entire study, Remazol blue dye was used. Experimental studies were carried out in an acidic pH range, showed good dye removal by using incinerated textile mill sludge ash. Experimental results obtained fitted well in Langmuir and Freundlich isotherms. © 2015, Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg.