Faculty Publications

Permanent URI for this communityhttps://idr.nitk.ac.in/handle/123456789/18736

Publications by NITK Faculty

Browse

Subject: search.filters.subject.Titanium

Search Results

Now showing 1 - 10 of 46
  • No Thumbnail Available
    Item
    The direct conversion of benzene to phenol by hydroxylation with hydrogen peroxide was carried out over various transition metals impregnated on MCM-41 and activated carbon. Copper-, iron-, and vanadium-impregnated on activated carbon gave better yields of phenol when compared to the corresponding reactions using cobalt-, nickel-, manganese-, and titanium-impregnated catalysts. Comparison of the MCM-41 and activated carbon-supported catalysts showed that activated carbon-supported catalysts gave a higher yield of phenol than did the MCM-41-supported catalysts. The activity of the transition metals supported on activated carbon in the production of phenol was V > Fe > Cu; the corresponding activity of the transition metals supported on MCM-41 was Cu > Fe > V. In addition to the role of transition metals in catalyzing the hydroxylation reaction, the hydrophobic nature of the activated carbon surface seems to enhance the performance of these catalysts relative to the MCM-41-supported catalysts.
    (Benzene hydroxylation to phenol catalyzed by transition metals supported on MCM-41 and activated carbon) Choi, J.-S.; Kim, T.-H.; Saidutta, M.B.; Sung, J.-S.; Kim, K.-I.; Jasra, R.V.; Song, S.-D.; Rhee, Y.-W.
    2004
  • No Thumbnail Available
    Item
    Influence of die angle on containerless extrusion of commercially pure titanium tubes
    (2007) Srinivasan, K.; Venugopal, P.
    Containerless tube extrusion has been investigated with commerically pure titanium at room temperature and a strain rate of 0.07 s-1 using 20 conical dies of five different strains and four different angles with MoS2 lubricant. Theoretical punch pressures have been calculated using appropriate equations from slab analysis of the process and compared with experimentally determined punch pressures. It is found that there exists an optimum angle at which the punch pressure is the least at a given strain.
  • No Thumbnail Available
    Item
    Eclipta prostrata leaf aqueous extract mediated synthesis of titanium dioxide nanoparticles
    (2012) Govindasamy, G.; Rahuman, A.A.; Priyamvada, B.; Khanna, V.G.; Devarepally, D.K.; Jose, P.J.
    Eco-friendly, nontoxic, inexpensive, abundantly available hitherto unreported Eclipta prostrata leaf extract is used for the biosynthesis of titanium dioxide nanoparticles (TiO 2 NPs). The TiO 2 NPs were characterized by FTIR, XRD, AFM and FESEM analysis. FTIR peak implicated the role of carboxyl group OH stretching amine NH stretch in the formation of TiO 2 NPs. XRD characterized in crystallographic plane of rutile phase. AFM showed uneven surface morphology which indicates the presence of both individual and agglomerated nanoparticles. FESEM analysis showed shape in spherical clusters, quite polydisperse and it ranges in size from 36 to 68 nm with calculated average size of 49.5 nm. In this paper, we have demonstrated a novel biological route for the synthesis of TiO 2 NPs. © 2011 Elsevier B.V. All rights reserved.
  • No Thumbnail Available
    Item
    Hardness and electrochemical behavior of ceramic coatings on CP titanium by pulsed laser deposition
    (2012) Sujaya, C.; Shashikala, H.D.
    Thin films of alumina and silicon carbide are deposited on titanium substrate by the pulsed laser deposition technique using Nd: YAG laser. Deposited films are characterized using x-ray diffraction, scanning electron microscopy, energy-dispersive x-ray spectroscopy, absorption spectroscopy and nanoindentation. Film hardness of the ceramic coating is found to be high compared to that of the substrates. Corrosion behavior of substrates after ceramic coating is studied in 3. 5% NaCl solution by potentiodynamic polarization and electrochemical impedance spectroscopy measurements. Experimental results show an increase in corrosion resistance of titanium after being coated with a ceramic material. © 2012 Allerton Press, Inc.
  • No Thumbnail Available
    Item
    Behavior of Alloying Elements during Electro-Slag Remelting of Ultrahigh Strength Steel
    (2012) Bandyopadhyay, T.R.; Rao, P.K; Prabhu, N.
    The paper deals with the behavior of principal constituents of an ultrahigh strength steels during ESR. The multiple analyses show no significant variation in the concentrations of silicon, manganese, vanadium, molybdenum, sulphur and phosphorus while concentrations of carbon, chromium, aluminium and titanium in the ESR ingot are found to be within the range of ± 0.01, ± 0.12, ± 0.008 and ± 0.01% respectively. Silicon and manganese show a loss of 0- 55 and 2-13% respectively whereas the degree of desulphurization is in the range of 0 (in Ar shield) to 52 (in air). The lower carbon and chromium content of the electrode than the aimed value can be corrected by adding ferrochromium in-situ during ESR. The recovery of carbon from FeCr was nearly 100% in most of the melts while the recovery of chromium varied over a fairly wide range. The distributions of carbon and chromium are also uniform along the height and width of ESR ingots. The recovery of the inoculant titanium was relatively low at the bottom of the ingot and it increases with height and reached a constant value above 100-150 mm height. For the same addition of titanium, its recovery decreases during ESR with argon shielding. © Metallurgical and Mining Industry.
  • No Thumbnail Available
    Item
    Solar photocatalysis for treatment of Acid Yellow-17 (AY-17) dye contaminated water using Ag@TiO2 core-shell structured nanoparticles
    (2013) Khanna, A.; Shetty K, K.
    Wastewater released from textile industries causes water pollution, and it needs to be treated before discharge to the environment by cost effective technologies. Solar photocatalysis is a promising technology for the treatment of dye wastewater. The Ag@TiO2 nanoparticles comprising of Ag core and TiO2 shell (Ag@TiO2) have unique photocatalytic property of inhibition of electron-hole recombination and visible light absorption, which makes it a promising photocatalyst for use in solar photocatalysis and with higher photocatalytic rate. Therefore, in the present work, the Ag@TiO2 nanoparticles synthesized by one pot method with postcalcination step has been used for the degradation of Acid Yellow-17 (AY-17) dye under solar light irradiation. The Ag@TiO2 nanoparticles were characterized using thermogravimetric-differential thermal analysis, X-ray diffraction, transmission electron microscopy, selected area electron diffraction, and energy dispersive X-ray analysis. The catalyst has been found to be very effective in solar photocatalysis of AY-17, as compared to other catalysts. The effects of pH, catalyst loading, initial dye concentration, and oxidants on photocatalysis were also studied. The optimized parameters for degradation of AY-17 using Ag@TiO2 were found to be pH 3, dye/catalyst ratio of 1:10 (g/g), and 2 g/L of (NH4)2S2O8 as oxidant. Efficient decolorization and mineralization of AY-17 was achieved. The kinetics of color, total organic carbon, and chemical oxygen demand removal followed the Langmuir-Hinshelwood model. Ag@TiO2 catalyst can be reused thrice without much decline in efficiency. The catalyst exhibited its potential as economic photocatalyst for treatment of dye wastewater. © 2013 Springer-Verlag Berlin Heidelberg.
  • No Thumbnail Available
    Item
    Solar light induced photocatalytic degradation of Reactive Blue 220 (RB-220) dye with highly efficient Ag@TiO2 core-shell nanoparticles: A comparison with UV photocatalysis
    (2014) Khanna, A.; Shetty K, K.
    Ag core-TiO2 shell (Ag@TiO2) structured nanoparticles with Ag to TiO2 molar ratio of 1:1.7 were synthesized using one pot synthesis method and post calcination was carried out at 450°C for 3h to convert it from amorphous to crystalline form. The Ag core and TiO2 shell formation was confirmed by TEM and AFM. The particle size analysis revealed the average size of Ag@TiO2 as approximately around 30nm. EDS spectra showed the presence of O, Ag, and Ti elements. The improvement in optical properties was proved by DRS which showed significant red shift by Ag core in visible region. Ag@TiO2 exhibited better photocatalytic activity as compared to Degussa P25-TiO2, synthesized TiO2, and the Ag doped TiO2 photocatalysts under UV and solar light irradiation for degradation of Reactive Blue 220 (RB-220) dye. Higher rate of photocatalysis of RB-220 with Ag@TiO2 was obtained under solar light irradiation as compared to UV light irradiation, confirming the capability of the catalyst to absorb both UV and visible light. The kinetics of degradation of dye was found to follow modified Langmuir Hinshelwood (L-H) kinetic model. Ag@TiO2 can be recycled without much decline in the efficacy. Ag@TiO2 has been found to be the effective photocatalyst for degradation of water contaminated with azo dyes under both UV and solar light irradiations. © 2013 Elsevier Ltd.
  • No Thumbnail Available
    Item
    Titanium foam with coarser cell size and wide range of porosity using different types of evaporative space holders through powder metallurgy route
    (Elsevier Ltd, 2014) Mondal, D.P.; Patel, M.; Das, S.; Jha, A.K.; Jain, H.; Gupta, G.; Arya, S.B.
    Ti-foams were made using different evaporative types of space holders such as acrowax and ammonium bicarbonate with a wide range of porosities (55-89%) through powder metallurgy technique. Cold compaction pressure was varied from 100 to 200. MPa in order to examine the effect of cold compaction pressures on the absolute porosities of the foams. The cell size, cell wall thickness and porosities of the foams were characterised as a function of cold compaction pressures and type of space holders. Empirical correlation has been established to predict foam porosities from compaction pressures and volume fraction of space holder. The sintered foams were found to be free from residue of the space holder. However, approximate 8-10% of titanium oxidized during sintering. The foam made with acrowax, as space holder attains slightly higher strength, modulus and energy absorption. © 2014 Elsevier Ltd.
  • No Thumbnail Available
    Item
    Efficacy of titanium doped-indium tin oxide (Ti/TiO2-ITO) films in rapid oxygen generation under photocatalysis and their suitability for bio-medical application
    (2014) Subrahmanyam, A.; Ananthakrishnan, A.; Rakibuddin, M.; Paul Ramesh, T.; Raveendra Kiran, M.R.; Shankari, D.; Chandrasekhar, K.
    The present work describes in detail the photocatalytic properties of controlled titanium doped indium tin oxide (Ti/TiO2-ITO) composite thin films prepared by DC magnetron sputtering and their applicability to developing a bio-medical lung assistive device. The catalytic films of various thicknesses (namely, C1, C2, C3 and C4) were characterized using surface imaging (SEM), X-ray analyses (XRD and EDX), and Raman studies. The optical band gaps of the prepared films are ?3.72-3.77 eV. Photocatalytic efficiencies of the film catalysts were investigated with the aid of a model organic molecule (Rhodamine B dye). The overall photodegradation capacity of the films was found to be slow kinetically, and the catalyst C1 was identified as having a better degradation efficiency (RhB 5 ppm, at pH 6.5) over 5 h under irradiation at 254 nm. The distinctive features of these composite films lie in their oxygen accumulation capacity and unique electron-hole pair separation ability. Investigations on oxygen species revealed the formation of superoxide radicals in aqueous systems (pH 6.5). The prepared films have TiO2 in the anatase phase in the surfaces, and possess the desired photocatalytic efficiency, compatibility to the heme system (are not involved in harmful hydroxyl radical production), and appreciable reusability. Especially, the thin films have a significant ability for mobilization of oxygen rapidly and continuously in aqueous medium under the irradiation conditions. Hence, these films may be a suitable choice for the photo-aided lung assistive design under development. © the Partner Organisations 2014.
  • No Thumbnail Available
    Item
    Analysis of surface roughness and hardness in ball burnishing of titanium alloy
    (Elsevier B.V., 2014) Revankar, G.D.; Shetty, R.; Rao, S.S.; Gaitonde, V.N.
    Ball burnishing is a popular post-machining metal finishing operation. An attempt has been made in this paper to optimize the process parameters during burnishing of titanium alloy (Ti-6Al-4V). Ball burnishing process parameters such as burnishing speed, burnishing feed, burnishing force and number of passes were considered to minimize the surface roughness and maximize the hardness. The lubricated ball burnishing experiments were planned as per L25 orthogonal array and signal to noise (S/N) ratio was applied to measure the proposed performance characteristics. The validation tests with the optimal levels of parameters were performed to illustrate the effectiveness of Taguchi optimization. The optimization results revealed that burnishing feed and burnishing speed are the significant parameters for minimizing the surface roughness, whereas burnishing force and number of passes play important roles in maximizing the hardness. The optimization results showed greater improvements in surface finish (77%) and hardness (17%) when compared to pre-machined surfaces. © 2014 Elsevier Ltd. All rights reserved.