Faculty Publications

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    Analysis of coefficient of thermal expansion in carbon black filled PDMS composite
    (Trans Tech Publications Ltd ttp@transtec.ch, 2020) Hiremath, H.; Sangamesh, R.; Kulkarni, S.M.
    Polymer composites are gaining attention due to their superior thermal properties. Especially carbon black /carbon nanotubes/ graphene filled polymer composites are used in energy harvesting, thermal actuators and MEMS. The coefficient of thermal expansion (CTE) is one of the most important properties in the polymer composite. In the present study, thermal expansion of polydimethylsiloxane (PDMS) matrix is filled with carbon black particle of varied volume fraction is modeled. Two-dimensional finite element (FE) model is computed in order to explain the thermal expansion behavior of the polymer composite and same is carried out for ambient to 70 K temperature. A 2D regular arrangement of circular particle packing model is set up and simulated. The FE model predicts that filler geometry has a little effect on the thermal expansion than the percentage of filler in the composite. Thermal expansion of composite is compared with the theoretical model. It shows that the CTE of composite reduces as the filler percentage increase, also gives good agreement in the both models. Hence, it is found that the addition of carbon black to the polymer composite could make it perform significantly better in thermal expansion. © 2020 Trans Tech Publications Ltd, Switzerland.
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    Effect of mushy state rolling on age-hardening and tensile behavior of Al-4.5Cu alloy and in situ Al-4.5Cu-5TiB2 composite
    (Elsevier Ltd, 2011) Siddhalingeshwar, I.G.; Herbert, M.A.; Chakraborty, M.; Mitra, R.
    The effect of mushy state rolling on aging kinetics of stir-cast Al-4.5Cu alloy and in situ Al-4.5Cu-5TiB2 composite and their tensile behavior in solution-treated (495°C) or differently aged (170°C) conditions, has been investigated. As-cast or pre-hot rolled alloy and composite samples were subjected to single or multiple mushy state roll passes to 5% thickness reduction at temperatures for 20% liquid content. Peak-aging times of mushy state rolled composite matrices have been found as ?7.5-10% of that of as-cast alloy. Such enhancement in aging kinetics is attributed to homogeneity in Cu atom distribution as well as increase in matrix dislocation density due to thermal expansion coefficient mismatch between Al and TiB2, matrix grain refinement and particle redistribution, achieved by mushy state rolling. Uniform precipitate distribution in mushy state rolled composite matrices leads to greater peak-age microhardness with higher yield and ultimate tensile strengths than those in as-cast alloy and composite. © 2010 Elsevier B.V.
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    The effect of the addition of strontium and cerium modifiers on microstructure and mechanical properties of hypereutectic Al-Si (LM30) alloy
    (ASTM International, 2013) Vijayan, V.; Ravi, M.; Prabhu, K.
    The present work deals with the melt treatment of LM30 hypereutectic Al-Si alloy using cerium and strontium and the assessment of its effect on microstructure and properties of the alloy. The addition of cerium simultaneously modified both primary and eutectic silicon, leading to an increase in ultimate tensile strength, as well as the wear resistance of the alloy. It was found that the coefficient of thermal expansion of the alloy decreased on modification of the microstructure. © 2013 by ASTM International.
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    Temperature dependent structural properties and bending rigidity of pristine and defective hexagonal boron nitride
    (Institute of Physics Publishing custserv@iop.org, 2015) Thomas, S.; Ajith, K.M.; Chandra, S.; Valsakumar, M.C.
    Structural and thermodynamical properties of monolayer pristine and defective boron nitride sheets (h-BN) have been investigated in a wide temperature range by carrying out atomistic simulations using a tuned Tersoff-type inter-atomic empirical potential. The temperature dependence of lattice parameter, radial distribution function, specific heat at constant volume, linear thermal expansion coefficient and the height correlation function of the thermally excited ripples on pristine as well as defective h-BN sheet have been investigated. Specific heat shows considerable increase beyond the Dulong-Petit limit at high temperatures, which is interpreted as a signature of strong anharmonicity present in h-BN. Analysis of the height fluctuations, ?h2?, shows that the bending rigidity and variance of height fluctuations are strongly temperature dependent and this is explained using the continuum theory of membranes. A detailed study of the height-height correlation function shows deviation from the prediction of harmonic theory of membranes as a consequence of the strong anharmonicity in h-BN. It is also seen that the variance of the height fluctuations increases with defect concentration. © 2015 IOP Publishing Ltd.
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    Effect of cooling rate on joint shear strength of Sn-9Zn lead-free solder alloy reflowed on copper substrate
    (ASTM International, 2017) Tikale, S.; Sona, M.; Prabhu, K.
    Reliability of the solder joint largely depends on mechanical strength, fatigue resistance, coefficient of thermal expansion, and intermetallic compound formation. Cooling rate significantly affects the physical properties of an alloy and influences the mechanical behavior of solder joints. In the present study, Sn-9Zn lead-free solder alloy was solidified on Cu substrate under furnace cooling (0.04°C/s), air cooling (0.16°C/s), and water cooling (94°C/s) conditions. The effect of varying cooling rates on the intermetallic compound (IMC) formation at the interface and the resulting joint shear strength was studied. A microstructure study revealed the presence of Cu5Zn8 and CuZn5 intermetallic compounds at the solder-substrate interface. The IMC layer thickness at the interface increased with a decrease in the cooling rate. The joint shear strength increased with an increase in the cooling rate. The air and furnace cooling resulted in the formation of a thick IMC layer. The IMC obtained from the furnace cooling was associated with micro-cracks leading to a decrease in the joint shear strength. © Copyright 2017 by ASTM International.
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    Effect of ripples on the finite temperature elastic properties of hexagonal boron nitride using strain-fluctuation method
    (Academic Press, 2017) Thomas, S.; Ajith, K.M.; Valsakumar, M.C.
    This work intents to put forth the results of a classical molecular dynamics study to investigate the temperature dependent elastic constants of monolayer hexagonal boron nitride (h-BN) between 100 and 1000 K for the first time using strain fluctuation method. The temperature dependence of out-of-plane fluctuations (ripples) is quantified and is explained using continuum theory of membranes. At low temperatures, negative in-plane thermal expansion is observed and at high temperatures, a transition to positive thermal expansion has been observed due to the presence of thermally excited ripples. The decrease of Young's modulus, bulk modulus, shear modulus and Poisson's ratio with increase in temperature has been analyzed. The thermal rippling in h-BN leads to strong anharmonic behaviour that causes large deviation from the isotropic elasticity. A detailed study shows that the strong thermal rippling in large systems is also responsible for the softening of elastic constants in h-BN. From the determined values of elastic constants and elastic moduli, it has been elucidated that 2D h-BN sheets meet the Born's mechanical stability criterion in the investigated temperature range. The variation of longitudinal and shear velocities with temperature is also calculated from the computed values of elastic constants and elastic moduli. © 2017 Elsevier Ltd
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    Investigation of the effect of BaTiO3/CoFe2O4 particle arrangement on the static response of magneto-electro-thermo-elastic plates
    (Elsevier Ltd, 2018) Mahesh, M.; Kattimani, S.
    In this article, a framework based on finite element (FE) methods is proposed for predicting the influence of spatial arrangement of two phase Barium Titanate (BaTiO3) and Cobalt Ferric Oxide (CoFe2O4) particulate composites on the static response of magneto-electro-thermo-elastic (METE) plates. The coupled material properties such as piezoelectric, piezomagnetic, dielectric, magnetic permeability, thermal expansion and pyro co-efficients vary significantly with the spatial arrangement of BaTiO3/CoFe2O4 particulates. The coupled FE governing equations accounting the effect of particle arrangement is presented by incorporating linear coupled constitutive equations of METE composites. Through the condensation technique, the governing equations of METE plates are solved to obtain direct (thermal displacements, electric and magnetic potentials) and derived quantities (stresses, electric displacements and magnetic flux densities). A special attention has been placed on evaluating the pyro-electric and pyro-magnetic coupling effects for different packing arrangement considered namely, Body Centered Cubic (BCC), Face Centered Cubic (FCC) and Simple Cubic (SC) METE particulate composites. Further, parametric studies are carried out to analyse the influence of boundary conditions and aspect ratio. The present study reveals that the multiphysics response of METE plates changes significantly with the packing arrangements of BaTiO3/CoFe2O4 particulates and geometrical parameters. It is believed that the obtained solutions would provide insights into design aspects of METE structures. © 2017 Elsevier Ltd
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    Optical and structural properties of BCBS glass system with and without alumina
    (Elsevier B.V., 2018) Bhattacharya, S.; Shashikala, H.D.
    BaO–CaO–Al2O3–SiO2 (BCAS) glass and their derivatives have gained extreme importance for their high endurance to elevated temperatures and being suitable for various electrochemical applications. Two glass systems, one being 50mol% [SiO2–B2O3]-xBaO-(45-x)CaO–5Al2O3 called as BCBSA and another without Al2O3 termed as BCBS were synthesized using melt quenching technique in the present work. Addition of ZnO and MgO as flux helped in melting them at 1300 °C which is much lower than the usual melting temperature of these glasses [1–4]. Density of the quenched glasses was measured by Archimedes method and structural bond vibrations were confirmed through FTIR. UV Visible spectroscopy was used to determine band gap energy and confirm the insulating nature of the synthesized glasses. The samples were isothermally heated at 700 °C, 800 °C for 50 h and at 900 °C for 50 and 100 h duration in air to allow the devitrification process to take place. The heat treated samples were analyzed by X-ray diffraction to identify the developed phases. Five Al2O3 free samples synthesized at 1300 °C by regular melt quenching technique were found to be devoid of the monocelsian phase. This is a detrimental phase for high temperature sealant applications as it has a very low coefficient of thermal expansion (CTE). Al2O3 free BCBS glasses, properties of which are being reported for the first time and glasses with low BaO concentrations are found to meet the requirements for high temperature applications as sealants in Solid Oxide Fuel Cell (SOFC). © 2018 Elsevier B.V.
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    Effect of BaO on thermal and mechanical properties of alkaline earth borosilicate glasses with and without Al2O3
    (Elsevier B.V., 2019) Bhattacharya, S.; Shashikala, H.D.
    BaO-CaO-Al2O3-SiO2 (BCAS) glass and their derivatives have gained extreme importance for their high endurance to elevated temperatures and suitability for various electrochemical applications. Two glass systems, one being 50 mol%[SiO2-B2O3]-xBaO-(45-x)CaO-5Al2O3 with x = 0, 10, 20, 25, 30, 35 and 40 mol%, represented as BCBSA and another without Al2O3 termed as BCBS, synthesized using melt quenching technique are considered here. The authors focus on the thermal and mechanical properties of these glasses. Reducing BaO concentrations improve the coefficient of thermal expansion (CTE/?) and other characteristic temperatures of glasses. Compacted glass pellets made of the water quenched frits show maximum shrinkage at 700 °C. Dilatometric analysis were conducted on compacts showing maximum shrinkage. CTE of these pellets are more than the bulk glasses. Glasses with low BaO concentrations exhibit high hardness and Young's modulus. Glasses bearing 20 mol% BaO, or even lesser, meet the thermal and mechanical properties required for high temperature sealants. © 2019 Elsevier B.V.
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    Influence of particulate surface treatment on physical, mechanical, thermal, and dielectric behavior of epoxy/hexagonal boron nitride composites
    (John Wiley and Sons Inc. cs-journals@wiley.com, 2020) Agrawal, A.; Chandraker, S.
    Physical, mechanical, thermal, and dielectric behavior of surface modified hexagonal boron nitride (hBN) in epoxy matrix was investigated in this paper. Effective treatment of microsize boron nitride involved silane coupling agent, (?-aminopropyl)triethoxysilane such that the coating resulted from the treatment amounted to 2% of the weight of silane coupling agent of the treated BN. The present work revealed that the chemical treatment of BN surface could effectively enhance the adhesion between matrix and filler material. The dispersion and wettability of the BN powder in epoxy matrix after surface treatment were improved. These imparted improved physical and excellent mechanical and thermal properties to the developed material. The experimental study on thermal properties of fabricated composites indicated that incorporation of modified particles exhibits improved glass transition temperature. As filler loading increases, coefficient of thermal expansion of composite decreases which further decreases when treated filler were used. Further, appreciable improvement in thermal conductivity is obtained when treated hBN is used in place of untreated one. The dielectric properties are investigated for wide frequency range and filler content and found to be increased with hBN content and decrease with frequency enhancement. Furthermore, mechanical properties of such composites were also largely enhanced when treated fillers were used. With modified properties, the presently developed material is suitable for microelectronic applications. © 2019 Society of Plastics Engineers