Faculty Publications
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Item Phase change materials in chemical and process engineering(Elsevier, 2023) Chavan, S.; Manickam, M.; Arumuga Perumal, A.P.; Gumtapure, V.This chapter is concerned with phase change materials in chemical and process engineering. Industrial waste heat recovery is explored as a source of heating and cooling with the application of phase change materials, which is well known. Consequently, heat transformation technologies are presented in detail along with their technical and economic potentials. Initially, utilization of phase change materials in process industries is discussed, which covers on-site and off-site industrial applications. The concept of on-site and off-site thermal energy utilization is well defined. The large amount of industrial waste heat is generated, which can be stored in the phase change materials, and it can be transported to the place where there is energy requirement in particular. Industries such as metal manufacturing, nonmetal manufacturing, chemicals and chemical products, pulp, and food processing industries are the main focuses of the present study. All the technical aspects are discussed in detail with respect to the future scope of phase change materials with thermal energy storage systems. Thermal energy utilization using phase change materials for chemical process industries also has great potentiality for various applications such as thermal fluid heating systems, gas-fired systems, and solar heating systems, which are also discussed. A comprehensive study has been carried out for potential usage of phase change materials for various manufacturing and process engineering applications. © 2023 Elsevier Ltd. All rights reserved.Item Cooling packing and cold energy storage(Elsevier, 2023) Chavan, S.; Manickam, M.; Arumuga Perumal, A.P.; Gumtapure, V.This chapter is divided into two parts: first part discusses about cooling packing applications of phase change materials, and second part discusses about cold thermal energy storage application of PCM. Consequently, methods of thermal energy storage are briefly explained, specifically for cooling packing applications along with present challenges of the technology. The second part of the chapter discusses in brief about cold thermal energy storage specifically basic working principle, loading of cold thermal energy storage for operational purposes CTES in selecting and characterizing storage media, water versus ice thermal energy storage, PCM used for cold thermal storage, advantages, disadvantages, and finally, battery thermal management system in electric vehicle are discussed in brief with updated knowledge in the field of real-time application. © 2023 Elsevier Ltd. All rights reserved.Item Characterization of metal-PCMs for thermal energy storage applications(Trans Tech Publications Ltd ttp@transtec.ch, 2015) Sudheer, R.; Prabhu, K.In recent years phase change materials have emerged to be ideal energy storage materials for their higher energy density over sensible heat storing materials. Use of phase change materials (PCM) have been successfully implemented at lower temperature applications with various organic compounds. On the other hand, high temperature applications have been solely dominated by various salts, their eutectics and mixtures as phase change materials. This work discusses the suitability of metals and alloys for thermal energy storage applications as the phase change material. Metals offer superior thermal conductivities with considerable energy density compared to salts. Here, two alloys namely, Sn-0.3Ag-0.7Cu (SAC) solidifying over 212-224°C and ZA8 (Zn-8%Al) solidifying over 378-405°C have been studied. Thermal analysis of PCMs using Computer Aided Cooling Curve Analysis (CA-CCA) and DSC technique were performed to predict the solidification path. In addition to this, Newtonian technique was employed to estimate the latent heat of fusion for these phase change materials. Cooling rate curves and Fraction Solid curves offered a better insight into their ability to receive and discharge heat over the concerned temperature range. © (2015) Trans Tech Publications, Switzerland.Item Preparation and characterization of nanoparticle blended polymers for thermal energy storage applications(American Institute of Physics Inc. subs@aip.org, 2019) Chavan, S.; Gumtapure, V.; Arumuga Perumal, D.A.This paper is concerned with the comprehensive procedure of preparing, morphological characterization and thermal property evaluation of nanoparticle blended polymer composites. Polymer composites are intended to consecrate the thermal energy storage applications. Linear low-density polyethylene (LLDPE) is incorporated with functionalized graphene with different concentrations (1, 3 and 5%). The morphological study revealed compatibility of polymer composites, at lower concentrations (1-3%,) it shows homogenous dispersion, but above threshold limit the particle distribution is non-homogenous with coarse surface structures. Higher concentration (5%) of nanoparticles emulsifies the molecules and generates micelles between themselves. The thermal conductivity of the polymer composite is significantly enhanced with the reduction of specific heat. At lower concentrations polymer exhibits homogeneous dispersion and the interfacial interaction is comparatively higher, optimal concentration (3%,) of nanoparticle provides favorable results and hence polymer composites with ideal concentration can be utilized for thermal energy storage applications. © 2018 Author(s).Item Environmental Engineering for Ecosystem Restoration—An Introduction(Springer Science and Business Media Deutschland GmbH, 2024) Vinod Chandra Menon, N.; Kolathayar, S.; Sreekeshava, K.S.; Bhargavi, C.This extensive volume addresses a range of environmental challenges and explores sustainable solutions across various domains. The research encompasses studies on paper consumption trends, thermal energy storage systems in green buildings, health risks associated with long-term noise exposure in urban areas, and passive design principles for buildings in cold and arid climates. The volume also delves into GIS-based assessments for ecosystem restoration, including groundwater quality in a smart city and spatiotemporal variability of short-term meteorological drought in semi-arid regions. Natural risk and vulnerability studies cover topics such as landslide vulnerability and the impact of changing climate on rainfall. Land use and land cover maps are analyzed for spatio-temporal changes using remote sensing and GIS tools. In the realm of industrial assessment, the volume addresses the treatment of dye-based effluents from various industries, focusing on electrochemical systems and adsorption analysis. Soft computing and numerical methods are applied to assess saltwater intrusion in inland aquaculture areas and predict ammonia levels in aquaculture. The volume also explores hydraulic structures' role in flood mitigation, with a focus on energy dissipation using a rigid stepped spillway. Groundwater suitability for irrigation is evaluated using electrical resistivity techniques. Solid waste management and green materials are extensively discussed, covering life cycle assessment in the silk textile industry, carbon footprint assessment of green concrete liners, and the effects of fly ash on concrete properties. Water quality assessment studies include analyses of borewell water for drinking purposes, groundwater quality modeling using artificial neural networks, and the application of phytoremediation for sullage treatment. The volume concludes with discussions on solid waste management in rural areas, with a focus on adaptation strategies, and quantification of water efficiencies in residential buildings. The study contributes to understanding environmental challenges and provides valuable insights for policymakers, researchers, and practitioners. Key themes include sustainable practices, environmental impact assessment, and the development of innovative technologies for waste treatment. © The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024.Item A review on thermal energy storage using composite phase change materials(Bentham Science Publishers, 2018) Chavan, S.; Gumtapure, V.; Arumuga Perumal, D.A.Background: This paper intends to provide the elementary understanding about the development of thermal energy storage systems. Reviews of storage system performance are carried out from various characterization studies, experimental work, numerical investigations and patents. Several techniques employed to enhance the thermal performance have been reviewed and discussed. Composite phase change materials are the best alternative to achieve the cost feasibility in thermal energy storage systems without compromising the storage capacity. Objective: The purpose of this study is to give an outline and history of the thermal energy storage systems and enlighten the techniques used for storage density enhancement without significant modifications in the design. Methods: In this study, three methods such as, characterization studies, experimental work, numerical investigations and patents. It also addresses many research articles and recent patents on the thermal storage systems, various techniques adopted and applications of such systems. Results: Composite phase change materials are the best alternative to achieve the cost feasibility in thermal energy storage systems without compromising the storage capacity. Carbon based nanoparticles show excellent properties in the composite phase change materials. Conclusion: Composite phase change materials have greater potential for thermal energy storage applications and especially carbon-based nanoparticles like graphene, graphene oxide, carbon nanotubes, fullerene, graphite, graphite oxide, extracted graphite etc., are greatly enhancing the thermo-physical properties of composite phase change materials. Combination of paraffin-based phase change materials and carbon-based nanoparticles can be used for the future thermal energy storage applications. © 2018 Bentham Science Publishers.Item Thermal energy storage in concrete: A comprehensive review on fundamentals, technology and sustainability(Elsevier Ltd, 2024) Barbhuiya, S.; Das, B.B.; Idrees, M.This comprehensive review paper delves into the advancements and applications of thermal energy storage (TES) in concrete. It covers the fundamental concepts of TES, delving into various storage systems, advantages, and challenges associated with the technology. The paper extensively explores the potential of concrete as a medium for thermal energy storage, analysing its properties and different storage methods. Additionally, it sheds light on the latest developments in concrete technology specifically geared towards thermal energy storage. The evaluation section discusses measurement techniques, experimental evaluations and performance metrics. Environmental and economic aspects, including sustainability and cost analysis, are thoughtfully addressed. The review concludes by underlining the significance of thermal energy storage in concrete, emphasizing its role in efficient energy management and the promotion of sustainable practices. © 2023 The AuthorsItem Performance assessment of composite phase change materials for thermal energy storage-characterization and simulation studies(Bentham Science Publishers, 2021) Chavan, S.; Gumtapure, V.; Arumuga Perumal, D.Background: The present study mainly focuses on the development of new Thermal Storage Materials (TSM) and compare the performance for thermal energy storage capacity. Linear Low-Density Polyethylene (LLDPE) based Composite Phase Change Materials (CPCMs) is prepared, and its properties are analyzed using characterization, analytical calculations, and numerical simulation meth-ods. The composites are prepared by blending the functionalized graphene nanoparticles (1, 3 & 5%) with three different concentrations into LLDPE. All three CPCMs show enhanced thermal performance compared to the base material, but it is noticed that higher concentrations of nanoparticles increase the dynamic viscosity and produce an adverse effect on thermal performance. Thermal characterization shows improved latent heat capacity with nanoparticle concentration, analytical and numerical results also compared, which shown a difference of 10 to 25%. Objective: The purpose of this study is the development and evaluation of the thermal storage capacity of different thermal storage materials and enlighten the techniques used for characterizing the storage materials. Methods: Composite material preparation is carried out by using twin-screw extruders, characterization of developed material is done through FTIR, SEM, and DSC analysis. For complete analysis character-ization, analytical calculations and numerical simulation methods are used. Results: Linear low-density polyethylene-based composite materials can be successfully developed using a twin-screw extruder. This extrusion provided proper dispersion of nanoparticles into the base material, and it is validated by SEM analysis. DSC analysis confirmed the enhancement in the thermo-physical properties of composite materials. Conclusion: The latent heat capacity increased around 20% during the heating cycle and reduced ap-proximately 23% during the cooling cycle for base material and 5% addition of nanoparticle, respec-tively. The comprehensive study accomplishes that the optimum concentration of nanoparticle provides better thermal performance for thermal energy storage applications. © 2021 Bentham Science Publishers.Item Optimum selection of phase change material for solar box cooker integrated with thermal energy storage unit using multi-criteria decision-making technique(Elsevier Ltd, 2021) Anilkumar, B.C.; Maniyeri, R.; Anish, S.Various thermal energy storage (TES) materials are used to increase the efficacy of solar cooker in off-sun hours. For the past few decades, phase change materials (PCMs) used as heat storage medium have become research interest. Selection of optimum PCM is important for the effective and efficient heat storage. Therefore, the main objective of the current study is to select the optimum PCM among the alternatives to be used for TES unit incorporated in solar box cooker (SBC). The PCMs are pre-screened among the alternatives used in earlier works based on the melting temperature. The optimum PCM is then selected with the aid of different multi-criteria decision -making (MCDM) techniques like TOPSIS, EDAS and MOORA. The criteria weights required for the optimization algorithm is found by using AHP, ENTROPY and CRITIC methods. Also, compromised values between the weights obtained through these methods are computed. The optimization algorithms are solved using MATLAB. The results of all MCDM techniques show that erythritol is the best alternative for the TES medium incorporated in the SBC. Further, the optimum mass of PCM and dimensions of the TES unit required for the SBC to operate during sun down hours for some specific duration is calculated by using a simple iterative solver developed with MATLAB. There is good agreement between the computational procedure and experimental study using paraffin wax as the TES medium. The iterative solution procedure also selects erythritol to be the best alternative as it required lesser quantity compared with other PCMs. Therefore, we recommend erythritol as the best PCM for the SBC incorporated with TES unit. © 2021Item Modified thermal energy storage unit for solar cookers using iterative design algorithm(Elsevier Ltd, 2022) Anilkumar, B.C.; Maniyeri, R.; Anish, S.The use of phase change materials (PCMs) as thermal energy storage (TES) mediums has gained notable attention in recent years due to their high energy density and constant temperature characteristics which makes them suitable for solar cookers (SCs). Therefore, the primary objective of this study is to develop a modified TES unit containing PCM as heat storage medium incorporated with cooking vessel for SCs. The TES units use PCM filled on all sides, including the lid, enhancing heat transfer to food load. The design of TES unit is carried out by developing computational procedure. MATLAB code is written to implement the iterative procedure, simplifying exhaustive calculations required for optimizing and designing the TES unit. The present work also aims to design, fabricate and test different geometries of TES units using paraffin wax as the PCM. After six hours, cooking load temperature in all geometries of TES units reached the melting point of PCM. TES units with cylindrical shapes perform best among hexagon and square designs. Through computational procedure, cylindrical configuration is the best as it takes least amount of PCM to keep steady temperature over a specific period. Based on the computational procedure developed in this study, TES container will be designed to enhance SC performance during sundown hours and maximize the use of latent heat stored within the PCM. © 2022
