Faculty Publications
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Item New manufacturing process of carbon-carbon composites and their mechanical properties(2011) Naik, P.S.; SurendranathanThis paper presents the synthesizing of carbon-carbon (CC) composites by preformed yarn (PY) method, by varying the percentage of carbon fiber volume. The PY used is carbon fiber bundle surrounded by coke and pitch which is enclosed in nylon-6. Three types of samples with fiber weight fractions of 30%, 40% and 50% respectively, are fabricated and tested. In each case, the PY is chopped and filled into a die of required shape and hot pressed at 600°C to get the carbonized composite. To obtain the graphitic structure, the specimen is heat treated at 1800°C followed by soaking for two hours. Further, one cycle pitch impregnation is done by hot isostatic pressing, to eliminate the voids. The characteristics such as hardness, compressive strength and creep, are studied. It is observed that, as the carbon fiber percentage increases the properties also improved, provided sintering is done at fairly higher temperatures. The superiority of the new class of CC composites made by the proposed PY technique over those obtained by the conventional methods is also demonstrated. © 2011 CAFET-INNOVA TECHNICAL SOCIETY.Item Effect of fiber weight fraction on mechanical properties of carbon-carbon composites(2012) Naik, P.S.; Orangalu, S.A.; Londhe, N.V.This article presents the synthesis of carbon-carbon (C/C) composites by preformed yarn (PY) method, by varying the percentage of carbon fiber weight fraction. The PY used was carbon fiber bundle surrounded by coke and pitch which was enclosed in nylon-6. Three types of samples with fiber weight fractions of 30, 40, and 50%, respectively, are fabricated and mechanical properties were studied. In each case, the PY was chopped and filled into a die of required shape and hot pressed at 500°C to get the preform composite. To obtain the carbonized and graphitic structure, the specimen was heat treated at 2500°C followed by soaking for 10 to 12 hrs. Further, two cycles pitch impregnation was done by hot isostatic pressing, to eliminate the voids and to increase the density hence to obtain good mechanical properties. The characteristics such as hardness, flexural strength, and impact strengths were studied. It is observed that, as the carbon fiber percentage increases, the properties also get improved, provided sintering is done at fairly higher temperatures such as 2700°C. The superiority of the new class of C/C composites made by the proposed PY technique over those obtained by the conventional methods is also demonstrated. Copyright © 2012 Society of Plastics Engineers.Item Titanium foam with coarser cell size and wide range of porosity using different types of evaporative space holders through powder metallurgy route(Elsevier Ltd, 2014) Mondal, D.P.; Patel, M.; Das, S.; Jha, A.K.; Jain, H.; Gupta, G.; Arya, S.B.Ti-foams were made using different evaporative types of space holders such as acrowax and ammonium bicarbonate with a wide range of porosities (55-89%) through powder metallurgy technique. Cold compaction pressure was varied from 100 to 200. MPa in order to examine the effect of cold compaction pressures on the absolute porosities of the foams. The cell size, cell wall thickness and porosities of the foams were characterised as a function of cold compaction pressures and type of space holders. Empirical correlation has been established to predict foam porosities from compaction pressures and volume fraction of space holder. The sintered foams were found to be free from residue of the space holder. However, approximate 8-10% of titanium oxidized during sintering. The foam made with acrowax, as space holder attains slightly higher strength, modulus and energy absorption. © 2014 Elsevier Ltd.Item Record-low sintering-temperature (600 °c) of solid-oxide fuel cell electrolyte(Elsevier Ltd, 2016) Prasad Dasari, H.P.; Ahn, K.; Park, S.-Y.; Hong, J.; Kim, H.; Yoon, K.J.; Son, J.-W.; Kim, B.-K.; Lee, H.-W.; Lee, J.-H.One of the major problems arising with Solid-Oxide Fuel Cell (SOFC) electrolyte is conventional sintering which requires a very high temperature (>1300 °C) to fully densify the electrolyte material. In the present study, the sintering temperature of SOFC electrolyte is drastically decreased down to 600 °C. Combinational effects of particle size reduction, liquid-phase sintering mechanism and microwave sintering resulted in achieving full density in such a record-low sintering temperature. Gadolinium doped Ceria (GDC) nano-particles are synthesized by co-precipitation method, Lithium (Li), as an additional dopant, is used as liquid-phase sintering aid. Microwave sintering of this electrolyte material resulted in decreasing the sintering temperature to 600 °C. Micrographs obtained from Scanning/Transmission Electron Microscopy (SEM/TEM) clearly pointed a drastic growth in grain-size of Li-GDC sample (?150 nm) than compared to GDC sample (<30 nm) showing the significance of Li addition. The sintered Li-GDC samples displayed an ionic conductivity of ?1.00 × 10-2 S cm-1 at 600 °C in air and from the conductivity plots the activation energy is found to be 0.53 eV. © 2016 Elsevier B.V. All rights reserved.Item Enhanced Bulk Thermoelectric Performance of Pb0.6Sn0.4Te: Effect of Magnesium Doping(American Chemical Society service@acs.org, 2017) Shenoy, U.S.; Bhat, D.K.Thermoelectric (TE) materials are promising in the context of renewable power generation as they can directly convert waste heat into electricity. Although PbTe is the best known TE material, its use is not encouraged due to concerns of environmental toxicity of lead. A combination of modified self-propagating high-temperature synthesis (SHS) and field-assisted sintering technique (FAST) is employed for the very first time to synthesize a solid solution of PbTe and SnTe. We show that doping of Pb0.6Sn0.4Te with Mg breaks crystal mirror symmetry and opens up band gap. This results in suppression of bipolar diffusion. Also the increase in degeneracy of valence sub-bands improves Seebeck coefficient. Both these synergistically leads to remarkable enhancement in figure of merit ZT (?2 at 840 K) and ZTavg (?1.2 between 500 and 840 K) rendering it into high-performance thermoelectric material by successfully engineering electronic structure. Most importantly, the ZT here is comparable to that of Mg-doped PbTe but has lesser lead content and hence is more environment friendly. The most probable configuration of Pb0.6Sn0.4Te was also determined for the very first time using site occupancy disorder (SOD) technique. © 2017 American Chemical Society.Item Effect of alkali earth oxides on hydroxy-carbonated apatite nano layer formation for sio2 –bao–cao–na2 o–p2o5 glass system(Springer Science and Business Media Deutschland GmbH, 2017) Kiran, P.; Ramakrishna, V.; Shashikala, H.D.; Udayashankar, N.K.Barium soda lime phosphosilicate [(58SiO2– (32-x)BaO–xCao–6Na2 O–4P2O5 (where x = 15, 20, 25 and 30 mol%)] samples were synthesised using conventional sol–gel method at 700 °C sintering temperature. Thermal, structural properties were studied using thermo gravimetric analysis and differential thermal analysis, X-ray diffraction, scanning electron microscopy, fourier transform infrared and Raman spectroscopy. Using Raman spectra non-bridging oxygen concentrations were estimated. The hydroxy-carbonated apatite (HCA) layer formation on samples was analysed for 7 days using simulated body fluid (SBF) soaked samples. The growth of HCA layers self-assembled on the sample surface was discussed as a function of NBO/BO ratio. Results indicated that the number of Ca2? ions released into SBF solution in dissolution process and weight loss of SB-treated samples vary with NBO/BO ratio. The changes in NBO/BO ratios were observed to be proportional to HCA forming ability of barium soda lime phosphosilicate glasses. © Springer. All rights reserved.Item Evaluation of mechanical properties for nickel based steel produced by metal injection moulding and sintered through conventional and microwave method(Italian Association of Chemical Engineering - AIDIC aidic@aidic.it, 2018) Veeresh Nayak, C.; Ramesh, M.R.; Desai, V.; Kumar Samanta, S.K.Metal injection moulding is a near net shape manufacturing technique. It developed from traditional plastic injection moulding and powder metallurgy process. The process involved mixing of metal powder and binder, injection moulding, debinding and sintering of moulded samples. Microwave process indicated critical consideration towards exceptional highlights, regards to, heating and sintering the various grouping of metals with the huge preferred perspective, control rate, and similarity, low ecological dangers. The samples consist of SS316L+WC-CrC-Ni metal powder and binders, low-density polyethylene (LDPE), paraffin wax (PW), stearic acid (SA) and polyethylene glycol (PEG 600). In the present study, the injection moulded green parts are exposed to high-intensity microwave fields operates at a frequency of 2.45 GHz. for sintering of MIM samples. The whole process time of the microwave-assisted sintering was remarkably less than conventional sintering. The sintering of SS316L+WC-CrC-Ni compact showed better results than those produced by sintering with conventional heating. The current study evaluates the effect of the conventional and microwave sintering on mechanical properties. © © 2018, AIDIC Servizi S.r.l.Item Praseodymium doped ceria as electrolyte material for IT-SOFC applications(Elsevier Ltd, 2018) Shajahan, I.; Ahn, J.; Nair, P.; Medisetti, S.; Patil, S.; Niveditha, V.; Uday Bhaskar Babu, G.; Prasad Dasari, H.P.; Lee, J.-H.Praseodymium-doped ceria (PDC, Ce0.9Pr0.1O2) electrolyte material for intermediate temperature solid oxide fuel cells (IT-SOFCs) has been successfully synthesised by EDTA-citrate method. From X-Ray diffraction (XRD), fluorite structure along with a crystallite size of 5.4 nm is obtained for PDC nanopowder calcined at 350 °C/24 h. Raman spectroscopy confirmed the structure, presence of oxygen vacancies with the manifestation of the main peak at 457 cm?1 and with a secondary peak at 550 cm?1. From Transmission Electron Microscopy (TEM) analysis, the average particle size is around 7–10 nm and selected area electron diffraction (SAED) patterns further confirmed the fluorite structure of PDC nanopowder. The PDC nanopowder displayed a BET surface area of 65 m2/g with a primary particle size of ?13 nm (calculated from BET surface area). Dilatometer studies revealed a multi-step shrinkage behaviour with the multiple peaks at 522, 1171 and 1461 °C which may be originated due to the presence of multiple size hard agglomerates. The PDC electrolyte pellet sintered at 1500 °C displayed an ionic conductivity of 1.213E-03 S cm?1 along with an activation energy of 1.28eV. Instead of a single fluorite structure, XRD of sintered PDC pellet showed multiple structures (Fluorite structure (CeO2) and cubic structure (PrO2). © 2018 Elsevier B.V.Item Investigation of sintering kinetics and morphological evolution of silver films from nano-dispersion(Springer Verlag service@springer.de, 2018) Pujar, P.; Anusha, P.; Gupta, D.; Mandal, S.The present study aimed at investigating the sintering kinetics and the mechanism of achieving uniform film morphology from silver nano-dispersion through evaporation of the solvent. A tuned time elapse between drop casting of silver dispersion and the annealing (dwell-time) acted as the decision maker in engineering the morphology: ring stain (infinite dwell-time), uniform deposit (variable dwell-time) and dot formation (zero dwell-time). Three distinct dwell-times (10, 20 and 30 min) are chosen for the study at different temperatures (120 to 250 °C) and the conclusion is derived based on the profile of the deposit. The frozen morphology that resulted from the evaporation goes through the debonding of surfactant with simultaneous sintering to minimize the surface energy. A linear isothermal sintering model comprising initial grain size, grain growth parameter, annealing time and fractional porosity helps to predict the grain size post-annealing. Theoretical predictions of grain sizes are well matched with experimental ones. The grain growth parameter which shows an upward trend with the annealing temperature is mainly due to a reduction in the porosity and the increase in the fraction of solid–solid interface which shows betterment in the percolation paths available for the movement of carriers. © 2018, Springer-Verlag GmbH Germany, part of Springer Nature.Item Evaluation of Wear Behaviour of Metal Injection Moulded Nickel Based Metal Matrix Composite(Springer Netherlands rbk@louisiana.edu, 2019) Veeresh Nayak, V.N.; Ramesh, M.R.; Desai, V.; Kumar Samanta, S.K.Metal injection moulding (MIM) is a near-net shape manufacturing technology for producing intricate parts, cost-effectively. MIM comprises combined techniques of plastic injection moulding and powder metallurgy. The present study focused on the development of the binder and fabrication of defect free MIM component. A wax-based binder system consisting of paraffin wax (PW), low density polyethylene (LDPE), polyethylene glycol (PEG-600) and stearic acid was established for MIM of NiCrSiB (70% Wt.) + Cr3C2-NiCr (30% Wt.) nickel based metal matrix composite (NMMC) powder. The feedstock was characterised through rheological properties at different temperatures. Injection temperature was determined from the rheological investigation of the feedstock having the 56% powder loading and 44% binder by volume. Sintering process was carried out with the temperature cycle in the range of 1250–1300 ?C under hydrogen purged atmosphere. The MIM components showed good and acceptable shrinkage in linear dimensions. The mechanical properties and wear behaviour of NMMC was studied using a pin-on-disc apparatus with alumina disc.Tests were performed under dry sliding conditions at room temperature and elevated temperatures of 200 and 400 ?C. Results shows that wear rate is maximum at 400 ?C for 40 N and lowest at room temperature for 10 N. Further wear mechanism was analysed using scanning electron microscope (SEM). © 2018, Springer Science+Business Media B.V., part of Springer Nature.